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American Journal of Physics

Eigenvalues of J2

Kenneth R. Brownstein

Published Sep 1, 1979• 0 citations
Publisher

Abstract

Most derivations of the possible eigenvalues of J2 [i.e., h/2j (j + 1), j = 0, 1/2, 1, 3/2,...] rely upon the eigenvalues, h/m, of a component of J, say Jz. A derivation of the J2 eigenvalues is presented in which the concept of Jz eigenvalues does not appear. The derivation is based upon addition of angular momenta and the algebraic properties of the Pauli spin matrices.

DOI
10.1119/1.11700

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Most derivations of the possible eigenvalues of J2 [i.e., h/2j (j + 1), j = 0, 1/2, 1, 3/2,...] rely upon the eigenvalues, h/m, of a component of J, say Jz. A derivation of the J2 eigenvalues is presented in which the concept of Jz eigenvalues does not appear. The derivation is based upon addition of angular momenta and the algebraic properties of the Pauli spin matrices.
We propose an algebraic diagonalization procedure for the angular momentum matrix Jx which is based on the introduction of a suitable generating function. The consideration of the analytic properties of the generating function leads to the eigenvalues of the problem. The coefficients of the power series expansion of this function generate the components of the eigenvectors of Jx. This procedure provides the beginning student of quantum mechanics with an alternative derivation of the eigenvalue spectrum of the angular momentum.
This chapter covers various aspects of orbital, total, and spin angular momenta and the Clebsch-Gordon coefficients. An approach that is not found in many books, is used to derive eigenvalues of orbital angular momentum. The Pauli theory of spin half systems, addition of angular momenta, eigenfunctions of orbital angular momentum, computation of Clebsch-Gordon coefficients, solved examples, and unsolved exercises are included in the chapter. The basic purpose of the chapter has been to bring out the quantum mechanical importance of the theory of angular momenta with the use of essential mathematical derivations, which are self-consistent, and to adopt an elegant modern approach. Special mention on why orbital angular momentum cannot have non-integer values is made. The concept of spin angular momentum, which is purely a quantum mechanical quantity, is introduced in a simple and most convincing manner.
We know that even a single electron in a hydrogen atom generally has orbital angular momentum L (with (2 l + 1) possible orientations where l is a integer) and spin angular momentum S (with two possible orientations commonly described as spin up and spin down or s = ± 1/2). In more complicated atoms there may be many components of angular momentum; for example, the helium atom has two electrons both of which have orbital and spin angular momenta. Also, in many atomic systems of physical interest we need to know how to combine angular momenta. This chapter explains how to do it.