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Cambridge University Press eBooks

Angular Momentum: General Properties

Rocco Schiavilla

Published Dec 5, 2024• 0 citations
Publisher

Abstract

General derivation of the eigenvalues and eigenstates of the square and z-component of the angular momentum; relationship between the angular momentum and the harmonic oscillator in two dimensions; transformation of states and operators under rotations; algebraic derivation of the hydrogen atom spectrum.
DOI
10.1017/9781009473637.012

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QUANTUM PRINCIPLES Perspective and Principles Prelude to Quantum Mechanics Stern-Gerlach Experiment Idealized Stern-Gerlach Results Classical Model Attempts Wave Functions for Two Physical-Outcome Case Process Diagrams, Operators, and Completeness Further Properties of Operators/Modulation Operator Reformulation Operator Rotation Bra-Ket Notation/Basis States Transition Amplitudes Three-Magnet Setup Example-Coherence Hermitian Conjugation Unitary Operators A Very Special Operator Matrix Representations Matrix Wave Function Recovery Expectation Values Wrap Up Problems Free Particles in One Dimension Photoelectric Effect Compton Effect Uncertainty Relation for Photons Stability of Ground States Bohr Model Fourier Transform and Uncertainty Relations Schrodinger Equation Schrodinger Equation Example Dirac Delta Functions Wave Functions and Probability Probability Current Time Separable Solutions Completeness for Particle States Particle Operator Properties Operator Rules Time Evolution and Expectation Values Wrap-Up Problems Some One-Dimensional Solutions to the Schrodinger Equation Introduction The Infinite Square Well: Differential Solution The Infinite Square Well: Operator Solution The Finite Potential Barrier Step Potential The Harmonic Oscillator The Attractive Kronig-Penny Model Bound State and Scattering Solutions Problems Hilbert Space and Unitary Transformations Introduction and Notation Inner and Outer Operator Products Operator-Matrix Relationship Hermitian Operators and Eigenkets Gram-Schmidt Orthogonalization Process Compatible Operators Uncertainty Relations and Incompatible Operators Simultaneously Measureable Operators Unitary Transformations and Change of Basis Coordinate Displacements and Unitary Transformations Schrodinger and Heisenburg Pictures of Time Evolution Free Gaussian Wave Packet in the Heisenberg Picture Potentials and the Ehrenfest Theorem Problems Three Static Approximation Methods Introduction Time-Independent Perturbation Theory Examples of Time-Independent Perturbation Theory Aspects of Degenerate Perturbation Theory WKB Semiclassical Approximation Use of the WKB Approximation in Barrier Penetration Use of the WKB Approximation in Bound States Variational Methods Problems Generalization to Three Dimensions Cartesian Basis States and Wave Functions in Three Dimensions Position/Momentum Eigenket Generalization Example: Three-Dimensional Infinite Square Well Spherical Basis States Orbital Angular Momentum Operator Effect of Angular Momentum on Basis States Energy Eigenvalue Equation and Angular Momentum Complete Set of Observables for the Radial Schrodinger Equation Specification of Angular Momentum Eigenstates Angular Momentum Eigenvectors and Spherical Harmonics Completeness and Other Properties of Spherical Harmonics Radial Eigenfunctions Problems QUANTUM PARTICLES The Three-Dimensional Radial Equation Recap of the Situation The Free Particle The Infinite Spherical Well Potential The Deuteron The Coulomb Potential: Initial Considerations The Coulomb Potential: 2-D Harmonic Oscillator Comparison The Confined Coulombic Model Problems Addition of Angular Momenta General Angular-Momentum Eigenstate Properties Combining Angular Momenta for Two Systems Explicit Example of Adding Two Spin 1/2 Systems Explicit Example of Adding Orbital Angular Momentum and Spin 1/2 Hydrogen Atom and the Choice of Basis States Hydrogen Atom and Perturbative Energy Shifts Problems Spin and Statistics The Connection between Spin and Statistics Building Wave Functions with Identical Particles Particle Occupation Basis More on Fermi-Dirac Statistics Interaction Operator and Feynman Diagrams Implications of Detailed Balance Cubical Enclosures and Particle States Maxwell-Boltzmann Statistics Bose-Einstein Statistics Fermi-Dirac Statistics The Hartree-Fock Equations Problems Quantum Particle Scattering Introduction The One-Dimensional Integral Schrodinger Equation Reflection and Transmission Amplitudes One-Dimensional Delta-Function Scattering Step-Function Potential Scattering The Born Series The Three-Dimensional Integral Schrodinger Equation The Helmholtz Equation and Plane Waves Cross Sections and the Scattering Amplitude Scattering Phase Shifts Finite-Range Potential Scattering The Three-Dimensional Born Series Identical Particle Scattering Proton-Proton Scattering Problems Connecting to the Standard Model Introduction Discrete Symmetries Parity Time Reversal Charge Conjugation Particle Primer Particle Interactions Quantum Electrodynamics Quantum Chromodynamics Weak Interactions Beyond the Standard Model Supersymmetry Superstrings Postlude Helpful Introductory Books on Particle and String Physics More Advanced Books on Particle and String Physics Problems Appendix: Notation Comments and Comparisons Appendix: Lattice Models Appendix: 2-D Harmonic Oscillator Wave Function Normalization Appendix: Allowed Standard Model Interactions Appendix: Weak Flavor Mixing Appendix: The Ising Model and More Index

•Aug 27, 2019•0 citations
The orbital angular momentum operator is defined and its commutation relations with the position and momentum operators, and generally with vector operators, are obtained; the relationship between the square of the momentum operator and the square of the orbital angular momentum is derived; the spectrum of the square and z-component of the orbital angular momentum is obtained by solving the Schröedinger equation near the origin; the radial equation is derived and the spherical harmonics are obtained as solutions of the associated Legendre equation.
Part 1: the need for the quantum mechanics quantization of radiation the special theory of relativity wave-particle duality the nature of matter waves the uncertainty principle the Bohr atom. Part 2 Schrodinger's equation: the postulates of quantum mechanics the wave equation the wave equation in three dimensions the time-independent Schrodinger equation stationary states normalisation probability flux physical constraints on the wave-function wave packets Gaussian wave-packets and the uncertainty principle. Part 3 One-dimensional potential wells: potential wells the one-dimensional infinite square well discussion of infinite square-well results eigenvalue equations the finite square well finite square well eigenfunctions the control of the wave-function by the wave equation numerical integration of Schrodinger's equation continuum solutions of the square-well potential interpretation of unbound-particle wave functions the double potential well the quantum bouncer electric fields and the tilted well the harmonic oscillator - introduction the quantum oscillator discussion of harmonic oscillator eigenvalues and eigenfunctions the classical probability density more potential wells. Part 4 Schrodinger's equation in three dimensions: particle in a three dimensional box degeneracy Schrodingers equation in spherical polar coordinates - the hydrogen atom normalisation. Part 5 Formal development of quantum mechanics: eigenvalues equations, operators and measurements the momentum operator, eigenvalues and eigenfunctions the position operator and its eigenfunctions Hermitian operators orthogonality of eigenfunctions the expansion postulate example - the b-decay of tritium expectation values compatibility of observables - commutators non-commuting operators time-dependence of expectation values - Ehrenfest's theorem abstract operators - the parity operator, matrix mechanics. Part 6 Angular momentum: angular momentum operators angular momentum commutators angular momentum eigenvalues and eigenfunctions interpretation of angular momentum eigenvalues interpretation of angular momentum eigenfunctions the Stern-Gerlach apparatus and electron spin spin operators - the Pauli Spin matrices the Zeeman effect measurements in quantum mechanics. Part 7 Spherically symmetric potential wells: the rigid rotator the radial equation the hydrogen atom and hydrogen like ions the isotropic harmonic oscillator molecular vibrations - the Morse potential the spherical square well general properties of spherically symmetric potential wells. (Part contents)
The addition theorem for spherical harmonics is just a special case of the law for the transformation of spherical harmonics under rotation of their arguments. Certain operators are scalars under rotation; this means that they commute with the total angular momentum and are unchanged by the transformation. The types of operators having simple transformation properties under rotation are known generally as tensor operators. The energy eigenstates of an atom, taking into account the spin-orbit interaction, are not usually eigenstates of the z component of the total orbital angular momentum, but are eigenstates of the total angular momentum, spin plus orbital. Sehwinger has looked at the theory of angular momentum from a point of view that enables one to carry out very elegant calculations of the various quantities occurring in the theory of angular momentum. The quanta of some different oscillators are simply the quarks that compose the strongly interacting particles.
QUANTUM PRINCIPLES Perspective and Principles Prelude to Quantum Mechanics Stern-Gerlach Experiment Idealized Stern-Gerlach Results Classical Model Attempts Wave Functions for Two Physical-Outcome Case Process Diagrams, Operators, and Completeness Further Properties of Operators/Modulation Operator Reformulation Operator Rotation Bra-Ket Notation/Basis States Transition Amplitudes Three-Magnet Setup Example-Coherence Hermitian Conjugation Unitary Operators A Very Special Operator Matrix Representations Matrix Wave Function Recovery Expectation Values Wrap Up Problems Free Particles in One Dimension Photoelectric Effect Compton Effect Uncertainty Relation for Photons Stability of Ground States Bohr Model Fourier Transform and Uncertainty Relations Schrodinger Equation Schrodinger Equation Example Dirac Delta Functions Wave Functions and Probability Probability Current Time Separable Solutions Completeness for Particle States Particle Operator Properties Operator Rules Time Evolution and Expectation Values Wrap-Up Problems Some One-Dimensional Solutions to the Schrodinger Equation Introduction The Infinite Square Well: Differential Solution The Infinite Square Well: Operator Solution The Finite Potential Barrier Step Potential The Harmonic Oscillator The Attractive Kronig-Penny Model Bound State and Scattering Solutions Problems Hilbert Space and Unitary Transformations Introduction and Notation Inner and Outer Operator Products Operator-Matrix Relationship Hermitian Operators and Eigenkets Gram-Schmidt Orthogonalization Process Compatible Operators Uncertainty Relations and Incompatible Operators Simultaneously Measureable Operators Unitary Transformations and Change of Basis Coordinate Displacements and Unitary Transformations Schrodinger and Heisenburg Pictures of Time Evolution Free Gaussian Wave Packet in the Heisenberg Picture Potentials and the Ehrenfest Theorem Problems Three Static Approximation Methods Introduction Time-Independent Perturbation Theory Examples of Time-Independent Perturbation Theory Aspects of Degenerate Perturbation Theory WKB Semiclassical Approximation Use of the WKB Approximation in Barrier Penetration Use of the WKB Approximation in Bound States Variational Methods Problems Generalization to Three Dimensions Cartesian Basis States and Wave Functions in Three Dimensions Position/Momentum Eigenket Generalization Example: Three-Dimensional Infinite Square Well Spherical Basis States Orbital Angular Momentum Operator Effect of Angular Momentum on Basis States Energy Eigenvalue Equation and Angular Momentum Complete Set of Observables for the Radial Schrodinger Equation Specification of Angular Momentum Eigenstates Angular Momentum Eigenvectors and Spherical Harmonics Completeness and Other Properties of Spherical Harmonics Radial Eigenfunctions Problems QUANTUM PARTICLES The Three-Dimensional Radial Equation Recap of the Situation The Free Particle The Infinite Spherical Well Potential The Deuteron The Coulomb Potential: Initial Considerations The Coulomb Potential: 2-D Harmonic Oscillator Comparison The Confined Coulombic Model Problems Addition of Angular Momenta General Angular-Momentum Eigenstate Properties Combining Angular Momenta for Two Systems Explicit Example of Adding Two Spin 1/2 Systems Explicit Example of Adding Orbital Angular Momentum and Spin 1/2 Hydrogen Atom and the Choice of Basis States Hydrogen Atom and Perturbative Energy Shifts Problems Spin and Statistics The Connection between Spin and Statistics Building Wave Functions with Identical Particles Particle Occupation Basis More on Fermi-Dirac Statistics Interaction Operator and Feynman Diagrams Implications of Detailed Balance Cubical Enclosures and Particle States Maxwell-Boltzmann Statistics Bose-Einstein Statistics Fermi-Dirac Statistics The Hartree-Fock Equations Problems Quantum Particle Scattering Introduction The One-Dimensional Integral Schrodinger Equation Reflection and Transmission Amplitudes One-Dimensional Delta-Function Scattering Step-Function Potential Scattering The Born Series The Three-Dimensional Integral Schrodinger Equation The Helmholtz Equation and Plane Waves Cross Sections and the Scattering Amplitude Scattering Phase Shifts Finite-Range Potential Scattering The Three-Dimensional Born Series Identical Particle Scattering Proton-Proton Scattering Problems Connecting to the Standard Model Introduction Discrete Symmetries Parity Time Reversal Charge Conjugation Particle Primer Particle Interactions Quantum Electrodynamics Quantum Chromodynamics Weak Interactions Beyond the Standard Model Supersymmetry Superstrings Postlude Helpful Introductory Books on Particle and String Physics More Advanced Books on Particle and String Physics Problems Appendix: Notation Comments and Comparisons Appendix: Lattice Models Appendix: 2-D Harmonic Oscillator Wave Function Normalization Appendix: Allowed Standard Model Interactions Appendix: Weak Flavor Mixing Appendix: The Ising Model and More Index