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Soviet Physics Uspekhi

GENERATION, AMPLIFICATION, AND DETECTION OF INFRARED AND OPTICAL RADIATION BY QUANTUM-MECHANICAL SYSTEMS

Nikolai G. Basov, Oleg N Krokhin, Yurii M Popov

Published May 31, 1961• 33 citations
Publisher

Abstract

CONTENTS Introduction 702 I. Methods of Obtaining Negative Temperature States 703 1. Negative Temperature 703 2. Selection of Molecules in Molecular Beams by Means of Inhomogeneous Electric or Magnetic Fields 705 3. Excitation of Gas Molecules by Means of a Gas Discharge 705 4. Pulse Method of Obtaining Negative Temperatures in Semiconductors 708 5. Obtaining Negative Temperatures in Semiconductors between Levels in a Single Band (Negative Mass Amplifiers) 713 6. Obtaining Negative Temperatures by Double-Resonance Techniques 715 II. Generation and Amplification of Electromagnetic Waves by Negative Temperature Systems 718 7. Interaction of Radiation with Negative Temperature Systems 718 8. Oscillation Conditions 719 9. Resonators 721 10. Amplifiers 723 11. Quantum-Mechanical Radiation Detectors 725 Conclusion 726 Cited Literature 726

DOI
10.1070/pu1961v003n05abeh003322

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CONTENTS Introduction 702 I. Methods of Obtaining Negative Temperature States 703 1. Negative Temperature 703 2. Selection of Molecules in Molecular Beams by Means of Inhomogeneous Electric or Magnetic Fields 705 3. Excitation of Gas Molecules by Means of a Gas Discharge 705 4. Pulse Method of Obtaining Negative Temperatures in Semiconductors 708 5. Obtaining Negative Temperatures in Semiconductors between Levels in a Single Band (Negative Mass Amplifiers) 713 6. Obtaining Negative Temperatures by Double-Resonance Techniques 715 II. Generation and Amplification of Electromagnetic Waves by Negative Temperature Systems 718 7. Interaction of Radiation with Negative Temperature Systems 718 8. Oscillation Conditions 719 9. Resonators 721 10. Amplifiers 723 11. Quantum-Mechanical Radiation Detectors 725 Conclusion 726 Cited Literature 726
Abstract : A method of amplifying electromagnetic radiation is proposed, based on the use of induced emission phenomena, theoretically developed by A. Einstein in 1917. At the given method of amplification there is no conversion of energy of amplified radiation into other forms of energy. The method is suitable for amplification of ultraviolet, visible, infrared radio range waves. To bring the described amplification method into realization, a medium is produced having a negative absorption factor for radiations. The intensity of the radiation stream, passed through such a medium, rises, which produces the amplification effect. The amplification factor equals e to the (K)L, where K is the absorption coefficient and L is the thickness of the layer.
1. Introduction 2. Review of Classical Electrodynamics 3. Review of Quantum Mechanics 4. The Spontaneous Emission of Radiation 5. Selection Rules for Electric Dipole Transitions 6. Measurement of Radiative Lifetimes of Atoms and Molecules 7. Forbidden Transitions and Metastable Atoms 8. The Width and Shape of Spectral Lines 9. The Absorption and Stimulated Emission of Radiation 10. Radiative Transfer and the Formation of Spectral Lines 11. Population Inversion Mechanisms in Gas Lasers 12. Resonant Modes of Optical Cavities 13. Saturation Characteristics and the Single-Frequency Operation of Gas Lasers 14. Turnable Dye Lasers and Atomic Spectroscopy 15. The Hanle Effect and the Theory of Resonance Flourescence Experiments 16. Optical Double Resonance Experiments 17. Optical Pumping Experiments 18. The Hyperfine Structure of Atoms and its Investigation by Magnetic Resonance Methods Appendix
Introduction The emission and absorption of radiation, as well as the conversion of radiation into other modes of energy such as heat or electricity, all involve interaction between electromagnetic waves and atoms, molecules, or free electrons. Such daily phenomena as the radiative emission by the sun, the shielding of earth from harmful UV radiation by the ozone layer, the blue color of the sky, and red sunsets are all – despite their celestial magnitude – generated by microscopic particles. Most lasers depend on emission by excited atoms (e.g. the He-Ne laser), ionized atoms (the Ar + laser), molecules (CO or CO 2 lasers), impurities trapped in crystal structures (Nd: YAG or Ti:sapphire lasers), or semiconductors (GaAs diode lasers). Similarly, many scattering processes of interest (e.g., Rayleigh or Mie scattering) result from the exchange of energy and momentum between incident radiation and atomic or molecular species. In the previous chapter we saw that the energy of microscopic particles is quantized: their energy can be acquired, stored, or released only in fixed lumps called quanta . The example of the “particle in the box” (eqn. 8.19) illustrated that these energy quanta are specific not only to the particle itself but to the system to which it belongs. Thus, in the box, the energy of the particle is specified by its own mass and by the dimension of the box; in a different box, the same particle will have an entirely different system of energy levels and the quanta will have different magnitudes.
The subject of masers is introduced by giving an historical account of events which led to the amplification of microwave radiation by an inverted population in a system of weakly interacting ammonia molecules. The introduction also outlines the development of masers up to the present. Sections 2 and 3 are concerned with maser fundamentals. Methods for obtaining inverted populations are discussed in § 2. Section 3 is devoted to the theory of maser gain and noise. This is followed by a discussion of microwave solid state masers. Microwave maser materials and the development of unidirectional travelling wave maser amplifiers are emphasized. Optical masers are treated in § 5. In this section the theory of optical amplifiers and oscillators is outlined. Also included in the theoretical discussion is a rather lengthy consideration of pump power requirements in optically pumped masers. This is followed by a survey of solid state, semiconductor and gaseous optical masers. The review ends with some comments on the extension of masers to new wavelength regions.
Summary Molecular beams are beams of molecules (which may be single atoms) travelling through vacuum at thermal velocities. They have been used to explore many properties of atoms and molecules, chiefly through their deflection in magnetic and electric inhomogeneous fields. Atomic beams first clearly established the phenomenon of space quantization, which means that the magnetic (or electric) energy of an atomic system in a given field can have only certain discrete values, and is not a continuum as classical physics supposed. Transitions between those energy states can be induced by radio-frequency fields; sharp resonances are observed and can be used to get accurate values of atomic and nuclear constants or to provide accurate frequency standards ('atomic clocks'). Molecular beams have also been used to test de Broglie's surmise that beams of particles should show wave properties (diffraction), to study collisions between molecules, and to supply spectroscopic sources in which the line broadening by Doppler effect is greatly reduced.