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Physical Review A

Quasicausal expansion of the quantum Liouville propagator

Gerhard Wilhelm Bund, Salomon Sylvain Mizrahi, M. C. Tijero

Published Feb 1, 1996• 8 citations
Publisher

Abstract

The quasicausal expansion of the quantum Liouville propagator is introduced into the Weyl-Wigner picture. The zeroth-order term is shown to lead to the statistical quasiclassical method of Lee and Scully [J. Chem. Phys. 73, 2238 (1980)]. \textcopyright{} 1996 The American Physical Society.
DOI
10.1103/physreva.53.1191

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The Gaussian wave-packet phase-space representation is used to show that the expansion in powers of \ensuremath{\Elzxh} of the quantum Liouville propagator leads, in the zeroth-order term, to results close to those obtained in the statistical quasiclassical method of Lee and Scully in the Weyl-Wigner picture. It is also verified that, propagating the Wigner distribution along the classical trajectories, the amount of error is less than that coming from propagating the Gaussian distribution along classical trajectories.
The Wigner-Weyl (WW) phase-space formulation of quantum mechanics is discussed within the Liouville-space formalism, where quantum operators A^ are viewed as vectors, represented by L kets \ensuremath{\Vert}A^>>, on which act ``superoperators''; the scalar product is A^\ensuremath{\Vert}B^>>=TrA${\mathrm{^}}^{\mathrm{\ifmmode^\circ\else\textdegree\fi{}}}$B^. With every operator A^, we associate commutation and anticommutation superoperators A${\mathrm{^}}^{\mathrm{\ensuremath{-}}}$ and A${\mathrm{^}}^{+}$, defined by their actions on any operator B^ as A${\mathrm{^}}^{\mathrm{\ensuremath{-}}}$B^=${\mathrm{\ensuremath{\Elzxh}}}^{\mathrm{\ensuremath{-}}1}$[A^,B^], A${\mathrm{^}}^{+}$B^=1/2(A^B^+B^A^). The WW representation corresponds to the choice of a special basis in Liouville space, namely, the eigenbasis of the position and momentum anticommutation superoperators q${\mathrm{^}}^{+}$ and p${\mathrm{^}}^{+}$ (where [q^,p^]=i\ensuremath{\Elzxh}). These, together with the commutation superoperators q${\mathrm{^}}^{\mathrm{\ensuremath{-}}}$ and p${\mathrm{^}}^{\mathrm{\ensuremath{-}}}$, form a canonical set of superoperators, [q${\mathrm{^}}^{+}$,p${\mathrm{^}}^{\mathrm{\ensuremath{-}}}$]=[q${\mathrm{^}}^{\mathrm{\ensuremath{-}}}$,p${\mathrm{^}}^{+}$]=i (the other commutators vanishing), as functions of which all other super- operators can be expressed. Weyl ordering is expressed as f(q^,p^)Weyl{)}_{\mathrm{Weyl}})Weyl​ ordering=f(q${\mathrm{^}}^{+}$,p${\mathrm{^}}^{+}$)1^. A generalization of Ehrenfest's theorem is obtained.
Abstract. We establish the difference between the propagation of semiclassical Wigner functions and classical Liouville propagation. First we re-discuss the semiclassical limit for the propagator of Wigner functions, which on its own leads to their classical propagation. Then, via stationary phase evaluation of the full integral evolution equation, using the semiclassical expressions of Wigner functions, we provide the correct geometrical prescription for their semiclassical propagation. This is determined by the classical trajectories of the tips of the chords defined by the initial semiclassical Wigner function and centered on their arguments, in contrast to the Liouville propagation which is determined by the classical trajectories of the arguments themselves. 1. introduction The Wigner [11] function W is a representation of the quantum density operator ˆρ as a real function on phase space, for a non-relativistic dynamical system with classical-quantum correspondence and n degrees of freedom. Here, all the underlying geometry is euclidean and we can include the Wigner function within the general framework of Weyl representation of operators: Â → A ∈ Ck IR (IR2n), so W(x) = (2π�) −n ρ(x) , where x ≡ (p1,...pn, q1,...qn) denotes a point in phase space. In this context, the quantum evolution of the density operator ˆρt effected by an autonomous external hamiltonian
We construct a representation of the coherent state path integral using the Weyl symbol of the Hamiltonian operator. This representation is very different from the usual path integral forms suggested by Klauder and Skagerstam (1985 Coherent States: Applications in Physics and Mathematical Physics (Singapore: World Scientific)), which involve the normal or the antinormal ordering of the Hamiltonian. These different representations, although equivalent quantum mechanically, lead to different semiclassical limits. We show that the semiclassical limit of the coherent state propagator in the Weyl representation involves classical trajectories that are independent of the width of coherent states. This propagator is also free from the phase corrections found in Baranger et al ( 2001 J. Phys. A: Math. Gen. 34 7227 ) for the two Klauder forms and provides an explicit connection between the Wigner and the Husimi representations of the evolution operator.
Using operators' Weyl ordering expansion formula (Hong-yi Fan,\emph{\}J. Phys. A 25 (1992) 3443) we find new two-fold integration transformation about the Wigner operator Δ(q′,p′)Δ(q',p')Δ(q′,p′) (qqq-number transform) in phase space quantum mechanics, ∬−∞∞dp′dq′/πΔ(q′,p′)e−2i(p−p′)(q−q′)=δ(p−P)δ(q−Q), \iint_{-\infty}^\infty dp' dq'/πΔ(q',p') e^{-2i(p-p') (q-q')} =δ(p-P) δ(q-Q), ∬−∞∞​dp′dq′/πΔ(q′,p′)e−2i(p−p′)(q−q′)=δ(p−P)δ(q−Q), and its inverse ∬−∞∞dqdpδ(p−P)δ(q−Q)e2i(p−p′)(q−q′)=Δ(q′,p′),\iint_{-\infty}^\infty dq dp δ(p-P) δ(q-Q) e^{2i(p-p') (q-q')}=Δ(q',p'), ∬−∞∞​dqdpδ(p−P)δ(q−Q)e2i(p−p′)(q−q′)=Δ(q′,p′), where Q,Q,Q, PPP are the coordinate and momentum operators, respectively. We apply it to studying mutual converting formulas among Q−PQ-PQ−P ordering, P−QP-QP−Q ordering and Weyl ordering of operators. In this way, the contents of phase space quantum mechanics can be enriched.