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Annalen der Physik

Zur Deutung von Gibbs' „Canonical Ensembles”

J. D. van der Waals

Published Jan 1, 1911• 1 citation
Publisher
DOI
10.1002/andp.19113400613

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This paper considers the problem of data compression for dependent quantum systems. It is the second in a series under the same title. As in the previous paper, we are interested in Lempel--Ziv encoding for quantum Gibbs ensembles. Here, we consider the canonical ideal lattice Bose- and Fermi-ensembles. We prove that as in the case of the grand canonical ensemble, the (limiting) von Neumann entropy rate hhh can be assessed, via the classical Lempel--Ziv universal coding algorithm, from a single eigenvector of the density matrix.
In this work we generalize and combine Gibbs and von Neumann approaches to build, for the first time, a rigorous definition of entropy for hybrid quantum-classical systems. The resulting function coincides with the two cases above when the suitable limits are considered. Then, we apply the MaxEnt principle for this hybrid entropy function and obtain the natural candidate for the hybrid canonical ensemble (HCE). We prove that the suitable classical and quantum limits of the HCE coincide with the usual classical and quantum canonical ensembles since the whole scheme admits both limits, thus showing that the MaxEnt principle is applicable and consistent for hybrid systems.
In this and the subsequent paper under the same title a number of exactly sovlable models of quantum statistical mechanics are studied in a context of quantum information theory. The basic model in this paper is a lattice system of ideal (free) particles (bosons or fermions), in the infinite-volume lmit of the grand canonical Gibbs ensemble. We interpet the (limiting) von Neumann entropy rate h as the information rate and use the classical Lempel-Ziv universal coding algorithm to assess the value of h from a single eigenvector W of the Gibbs ensemble density matrix p. We also show how to apply this scheme to the Calogero model.