Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2004.01986 · Physical review. E

Entropy and canonical ensemble of hybrid quantum classical systems

José Luis Alonso, Carlos Bouthelier-Madre, Alberto Castro, Jesús Clemente-Gallardo, Jorge Alberto Jover-Galtier

Published Oct 14, 2020• 12 citations
arXivHTMLPDF

Abstract

In this work we generalize and combine Gibbs and von Neumann approaches to build, for the first time, a rigorous definition of entropy for hybrid quantum-classical systems. The resulting function coincides with the two cases above when the suitable limits are considered. Then, we apply the MaxEnt principle for this hybrid entropy function and obtain the natural candidate for the hybrid canonical ensemble (HCE). We prove that the suitable classical and quantum limits of the HCE coincide with the usual classical and quantum canonical ensembles since the whole scheme admits both limits, thus showing that the MaxEnt principle is applicable and consistent for hybrid systems.

DOI
10.1103/physreve.102.042118

Related papers

Generalized Wigner–von Neumann entropy and its typicality

Zhigang Hu, Zhenduo Wang, Biao Wu

We propose a generalization of the quantum entropy introduced by Wigner and von Neumann [Z. Phys. 57, 30 (1929)10.1007/BF01339852]. Our generalization is applicable to both quantum pure states and mixed states. When the dimension N of the Hilbert space is large, this generalized Wigner-von Neumann (GWvN) entropy becomes independent of the choices of basis and is asymptotically equal to lnN in the sense of typicality. The dynamic evolution of our entropy is also typical, and is reminiscent of quantum H theorem proved by von Neumann. For a composite system, the GWvN entropy is typically additive; for the microcanonical ensemble, it is equivalent to the Boltzmann entropy; and for a system entangled with environment, it is consistent with the familiar von Neumann entropy, which is zero for pure states. In addition, the GWvN entropy can be used to derive the Gibbs ensemble.

arXiv:1812.10020•Physical review. E•May 14, 2019•13 citations

Semiclassical limit of entropies and free energies

Zied Ammari, Michele Correggi, Marco Falconi +1 more

Entropy and free energy are central concepts in both statistical physics and information theory, with quantum and classical facets. In mathematics these concepts appear quite often in different contexts (dynamical systems, probability theory, von Neumann algebras, etc.). In this work, we study the von Neumann and Wehrl entropies from the point of view of semiclassical analysis. We first prove the semiclassical convergence of the von Neumann to the Wehrl entropy for quantum Gibbs states (thermal equilibrium), after a suitable renormalization has been taken into account. Then, we show that, in the same limit, the free energy functional defined with the Wehrl entropy $ Γ-$converges to its classical counterpart, so implying convergence of the minima and the associated minimizers.

arXiv:2510.15777•Oct 17, 2025•0 citations

Continuity of the entropy of macroscopic quantum systems

Robert H. Swendsen

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper, I analyze and calculate the thermodynamic entropy for large but finite quantum mechanical systems. A special feature of this analysis is that the thermodynamic energy of a quantum system is shown to be a continuous variable, rather than being associated with discrete energy eigenvalues. Calculations of the entropy as a function of energy can be carried out with a Legendre transform of thermodynamic potentials obtained from a canonical ensemble. The resultant expressions for the entropy are able to describe equilibrium between quantum systems having incommensurate energy-level spacings. This definition of entropy preserves all required thermodynamic properties, including satisfaction of all postulates and laws of thermodynamics. It demonstrates the consistency of the concept of negative temperature with the principles of thermodynamics.

arXiv:1508.01323•Physical Review E•Nov 9, 2015•18 citations

Hybrid quantum-classical dynamics with stationary thermal states

Adrián A. Budini

Quantum and classical systems can consistently be coupled via non-unitary time-irreversible mechanisms. In this paper we characterize which kind of corresponding dynamics converge in the stationary regime to a thermal hybrid state, that is, a density matrix that maximizes the hybrid arrangement entropy under the constraints of a canonical ensemble. Introducing a detailed balance condition, it is found that a specific subclass of hybrid Lindblad equations fulfill the demanded requirement. The main theoretical results are exemplified through a set of specific examples that in addition lighten how the thermal state of each subsystem in isolation is affected by their mutual coupling. In particular, a Gaussian thermal state could become a bimodal distribution when increasing the interaction strength of a classical subsystem with a quantum two-level subsystem.

quant-pharXiv:2604.02484•Physical review. E•Apr 6, 2026•1 citation

Aspects of entropy in classical and in quantum physics

Stefan Heusler, Wolfgang Dür, Malte S. Ubben +1 more

Abstract Entropy has played an essential role in the history of physics. Its mathematical definition and applications have changed over time till today. In this paper, we first review the historical evolution of these various points of view, from the thermodynamic definition to information entropy from Shannon in classical physics, up to the modern concept of Neumann’s quantum entropy. As a specific example, we consider entanglement entropy and compare the phase space approach in classical physics to the Hilbert space approach in quantum physics in simple model systems. We derive a general expression for the entanglement entropy of fermions and bosons in arbitrary partitions of Hilbert space, valid beyond the thermodynamic limit. Next, we compare thermodynamic heat engines with quantum heat engines. Finally, we proceed to the more general concept of quantum (computational) complexity and argue, using the concept of entanglement entropy, that the Heisenberg time in classically chaotic systems coincides with the time when maximal complexity is reached in the quantum case for systems with all–all interactions.

Journal of Physics A Mathematical and Theoretical•Sep 5, 2022•9 citations

Statistical entropy of quantum systems

Smitarani Mishra, Shaon Sahoo

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical mechanics remain an area of active debate and are yet to be fully understood. This work is motivated by the need to develop a comprehensive understanding of the statistical measures of thermodynamic entropy in quantum systems - a topic intimately connected to the phenomenon of quantum thermalization. In particular, we investigate the conditions under which the von Neumann entropy can be regarded as a valid statistical measure of thermodynamic entropy in quantum systems. This paper demonstrates that the equivalence between the von Neumann and thermodynamic entropies is not universal, but instead depends on several subtle and often overlooked assumptions. In this context, we also briefly revisit key criticisms of von Neumann entropy - particularly its time-invariance and subadditivity - and argue that these concerns can be meaningfully addressed in the setting of thermodynamic systems. To substantiate some arguments and to clarify some issues, we provide suitable numerical results from our analysis of a spin-1/2 system.

arXiv:2412.15316•Dec 19, 2024•0 citations
In this work we generalize and combine Gibbs and von Neumann approaches to build, for the first time, a rigorous definition of entropy for hybrid quantum-classical systems. The resulting function coincides with the two cases above when the suitable limits are considered. Then, we apply the MaxEnt principle for this hybrid entropy function and obtain the natural candidate for the hybrid canonical ensemble (HCE). We prove that the suitable classical and quantum limits of the HCE coincide with the usual classical and quantum canonical ensembles since the whole scheme admits both limits, thus showing that the MaxEnt principle is applicable and consistent for hybrid systems.
We propose a generalization of the quantum entropy introduced by Wigner and von Neumann [Z. Phys. 57, 30 (1929)10.1007/BF01339852]. Our generalization is applicable to both quantum pure states and mixed states. When the dimension N of the Hilbert space is large, this generalized Wigner-von Neumann (GWvN) entropy becomes independent of the choices of basis and is asymptotically equal to lnN in the sense of typicality. The dynamic evolution of our entropy is also typical, and is reminiscent of quantum H theorem proved by von Neumann. For a composite system, the GWvN entropy is typically additive; for the microcanonical ensemble, it is equivalent to the Boltzmann entropy; and for a system entangled with environment, it is consistent with the familiar von Neumann entropy, which is zero for pure states. In addition, the GWvN entropy can be used to derive the Gibbs ensemble.
Entropy and free energy are central concepts in both statistical physics and information theory, with quantum and classical facets. In mathematics these concepts appear quite often in different contexts (dynamical systems, probability theory, von Neumann algebras, etc.). In this work, we study the von Neumann and Wehrl entropies from the point of view of semiclassical analysis. We first prove the semiclassical convergence of the von Neumann to the Wehrl entropy for quantum Gibbs states (thermal equilibrium), after a suitable renormalization has been taken into account. Then, we show that, in the same limit, the free energy functional defined with the Wehrl entropy $ Γ-$converges to its classical counterpart, so implying convergence of the minima and the associated minimizers.
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper, I analyze and calculate the thermodynamic entropy for large but finite quantum mechanical systems. A special feature of this analysis is that the thermodynamic energy of a quantum system is shown to be a continuous variable, rather than being associated with discrete energy eigenvalues. Calculations of the entropy as a function of energy can be carried out with a Legendre transform of thermodynamic potentials obtained from a canonical ensemble. The resultant expressions for the entropy are able to describe equilibrium between quantum systems having incommensurate energy-level spacings. This definition of entropy preserves all required thermodynamic properties, including satisfaction of all postulates and laws of thermodynamics. It demonstrates the consistency of the concept of negative temperature with the principles of thermodynamics.
Quantum and classical systems can consistently be coupled via non-unitary time-irreversible mechanisms. In this paper we characterize which kind of corresponding dynamics converge in the stationary regime to a thermal hybrid state, that is, a density matrix that maximizes the hybrid arrangement entropy under the constraints of a canonical ensemble. Introducing a detailed balance condition, it is found that a specific subclass of hybrid Lindblad equations fulfill the demanded requirement. The main theoretical results are exemplified through a set of specific examples that in addition lighten how the thermal state of each subsystem in isolation is affected by their mutual coupling. In particular, a Gaussian thermal state could become a bimodal distribution when increasing the interaction strength of a classical subsystem with a quantum two-level subsystem.
Abstract Entropy has played an essential role in the history of physics. Its mathematical definition and applications have changed over time till today. In this paper, we first review the historical evolution of these various points of view, from the thermodynamic definition to information entropy from Shannon in classical physics, up to the modern concept of Neumann’s quantum entropy. As a specific example, we consider entanglement entropy and compare the phase space approach in classical physics to the Hilbert space approach in quantum physics in simple model systems. We derive a general expression for the entanglement entropy of fermions and bosons in arbitrary partitions of Hilbert space, valid beyond the thermodynamic limit. Next, we compare thermodynamic heat engines with quantum heat engines. Finally, we proceed to the more general concept of quantum (computational) complexity and argue, using the concept of entanglement entropy, that the Heisenberg time in classically chaotic systems coincides with the time when maximal complexity is reached in the quantum case for systems with all–all interactions.
Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical mechanics remain an area of active debate and are yet to be fully understood. This work is motivated by the need to develop a comprehensive understanding of the statistical measures of thermodynamic entropy in quantum systems - a topic intimately connected to the phenomenon of quantum thermalization. In particular, we investigate the conditions under which the von Neumann entropy can be regarded as a valid statistical measure of thermodynamic entropy in quantum systems. This paper demonstrates that the equivalence between the von Neumann and thermodynamic entropies is not universal, but instead depends on several subtle and often overlooked assumptions. In this context, we also briefly revisit key criticisms of von Neumann entropy - particularly its time-invariance and subadditivity - and argue that these concerns can be meaningfully addressed in the setting of thermodynamic systems. To substantiate some arguments and to clarify some issues, we provide suitable numerical results from our analysis of a spin-1/2 system.