The absorption of helium excited at low voltages for its own lines, the $2^{3}S\ensuremath{-}2^{3}P$ at 10830A and the $2^{1}S\ensuremath{-}2^{1}P$ at 20582A, is determined. The percentage absorption of the $2^{3}S\ensuremath{-}2^{3}P$ line increases when either the exciting current or the pressure in the absorbing tube is increased, and also when either the current or the pressure in the source tube is decreased. When the light to be absorbed is taken end on from a Geissler tube source, the percentage absorption is much less than when the light is taken off at right angles to the capillary. The changes with source tube conditions are ascribed to the corresponding variations of the shape and width of the emission line. Observable absorption begins when the exciting voltage is 25 volts. No absorption is detected at 19.8 volts, the excitation potential of the $2^{3}S$ state. The 10830A line shows strong resonance which is directly proportional to the percentage absorption. The absorption for the 20582A line is very small. It shows no detectable resonance.The absorption of helium excited at low voltages for its own lines, the $2^{3}S\ensuremath{-}2^{3}P$ at 10830A and the $2^{1}S\ensuremath{-}2^{1}P$ at 20582A, is determined. The percentage absorption of the $2^{3}S\ensuremath{-}2^{3}P$ line increases when either the exciting current or the pressure in the absorbing tube is increased, and also when either the current or the pressure in the source tube is decreased. When the light to be absorbed is taken end on from a Geissler tube source, the percentage absorption is much less than when the light is taken off at right angles to the capillary. The changes with source tube conditions are ascribed to the corresponding variations of the shape and width of the emission line. Observable absorption begins when the exciting voltage is 25 volts. No absorption is detected at 19.8 volts, the excitation potential of the $2^{3}S$ state. The 10830A line shows strong resonance which is directly proportional to the percentage absorption. The absorption for the 20582A line is very small. It shows no detectable resonance.

Physical ReviewMar 1, 19321 citation

Absorption of powerful resonance radiation accompanying collisional line broadening

Sergei I Yakovlenko

Uspekhi Fizicheskih NaukJan 1, 198227 citations

Measurement of the Life of the Metastable Mercury Atom

M. L. Pool

Half value time for the ${2}^{3}$ ${\mathrm{P}}_{0}$ state of Hg for various pressures of admixed ${\mathrm{N}}_{2}$ --- A high speed rotating disk has been used to interrupt the total radiation from a water-cooled and magnetically controlled quartz mercury arc before optically exciting mercury vapor in a quartz resonance tube at room temperature. In the neighborhood of ${10}^{\ensuremath{-}4}$ sec. after the optical excitation a flash of visible radiation from another water-cooled and magnetically controlled mercury arc was passed through the resonance tube and the absorption spectrum photographed. The line 4047 ($2^{3}P_{0}\ensuremath{-}2^{3}S_{1}$) showed strong absorption when a few millimeters of nitrogen were introduced into the resonance tube. The lines 4077, 4358, 5461, 5770 and 5790 showed no measurable absorption under similar conditions. The rate of decay of the amount of 4047 absorbed with respect to the time-wait after excitation of the mercury vapor was taken as the rate of decay of the metastable $2^{3}P_{0}$ state. The life or half-value time of the state was found to vary markedly with the pressure of admixed nitrogen. The maximum life 4.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}4}$ sec. occurred for 6.8 mm of nitrogen. No absorption of 4047 was observed upon the introduction of hydrogen, argon, neon, or helium into the resonance tube.Half value time for the ${2}^{3}$${\mathrm{P}}_{0}$ state of Hg for various pressures of admixed ${\mathrm{N}}_{2}$--- A high speed rotating disk has been used to interrupt the total radiation from a water-cooled and magnetically controlled quartz mercury arc before optically exciting mercury vapor in a quartz resonance tube at room temperature. In the neighborhood of ${10}^{\ensuremath{-}4}$ sec. after the optical excitation a flash of visible radiation from another water-cooled and magnetically controlled mercury arc was passed through the resonance tube and the absorption spectrum photographed. The line 4047 ($2^{3}P_{0}\ensuremath{-}2^{3}S_{1}$) showed strong absorption when a few millimeters of nitrogen were introduced into the resonance tube. The lines 4077, 4358, 5461, 5770 and 5790 showed no measurable absorption under similar conditions. The rate of decay of the amount of 4047 absorbed with respect to the time-wait after excitation of the mercury vapor was taken as the rate of decay of the metastable $2^{3}P_{0}$ state. The life or half-value time of the state was found to vary markedly with the pressure of admixed nitrogen. The maximum life 4.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}4}$ sec. occurred for 6.8 mm of nitrogen. No absorption of 4047 was observed upon the introduction of hydrogen, argon, neon, or helium into the resonance tube.

Physical ReviewJan 1, 192914 citations

Distribution of Excitation Transfer in Helium

John D. Jobe, Robert M. St. John

Physical Review AMay 1, 19720 citations

Excitation-Transfer Collisions between Rubidium and Helium Atoms

T. J. Beahn, W. J. Condell, Hirsch I. Mandelberg

An experiment is described which measures the collision cross section for transfer of excitation in rubidium by helium. Rubidium atoms are pumped to either the $^{2}P_{\frac{1}{2}}$ or $^{2}P_{\frac{3}{2}}$ state by irradiation with one of the resonance lines. Some excited rubidium atoms are transferred to the other $P$ state by collisions with helium atoms. The rubidium atoms then radiate both resonance lines. Measurements of the intensities of both resonance lines as a function of helium pressure are used to calculate the collision cross section. The cross section for $^{2}P_{\frac{1}{2}}$ to $^{2}P_{\frac{3}{2}}$ is 1.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$ ${\mathrm{cm}}^{2}$ \ifmmode\pm\else\textpm\fi{}10% and for $^{2}P_{\frac{3}{2}}$ to $^{2}P_{\frac{1}{2}}$ is 1.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$ ${\mathrm{cm}}^{2}$ \ifmmode\pm\else\textpm\fi{}10%.An experiment is described which measures the collision cross section for transfer of excitation in rubidium by helium. Rubidium atoms are pumped to either the $^{2}P_{\frac{1}{2}}$ or $^{2}P_{\frac{3}{2}}$ state by irradiation with one of the resonance lines. Some excited rubidium atoms are transferred to the other $P$ state by collisions with helium atoms. The rubidium atoms then radiate both resonance lines. Measurements of the intensities of both resonance lines as a function of helium pressure are used to calculate the collision cross section. The cross section for $^{2}P_{\frac{1}{2}}$ to $^{2}P_{\frac{3}{2}}$ is 1.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$ ${\mathrm{cm}}^{2}$\ifmmode\pm\else\textpm\fi{}10% and for $^{2}P_{\frac{3}{2}}$ to $^{2}P_{\frac{1}{2}}$ is 1.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$ ${\mathrm{cm}}^{2}$\ifmmode\pm\else\textpm\fi{}10%.

Physical ReviewJan 7, 196628 citations

2^{3}S

state. The 10830A line shows strong resonance which is directly proportional to the percentage absorption. The absorption for the 20582A line is very small. It shows no detectable resonance.

Half value time for the

{2}^{3}

{\mathrm{P}}_{0}

state of Hg for various pressures of admixed

{\mathrm{N}}_{2}

--- A high speed rotating disk has been used to interrupt the total radiation from a water-cooled and magnetically controlled quartz mercury arc before optically exciting mercury vapor in a quartz resonance tube at room temperature. In the neighborhood of ${10}^{\ensuremath{-}4}$ sec. after the optical excitation a flash of visible radiation from another water-cooled and magnetically controlled mercury arc was passed through the resonance tube and the absorption spectrum photographed. The line 4047 ($2^{3}P_{0}\ensuremath{-}2^{3}S_{1}$) showed strong absorption when a few millimeters of nitrogen were introduced into the resonance tube. The lines 4077, 4358, 5461, 5770 and 5790 showed no measurable absorption under similar conditions. The rate of decay of the amount of 4047 absorbed with respect to the time-wait after excitation of the mercury vapor was taken as the rate of decay of the metastable

2^{3}P_{0}

state. The life or half-value time of the state was found to vary markedly with the pressure of admixed nitrogen. The maximum life 4.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}4}$ sec. occurred for 6.8 mm of nitrogen. No absorption of 4047 was observed upon the introduction of hydrogen, argon, neon, or helium into the resonance tube.

An experiment is described which measures the collision cross section for transfer of excitation in rubidium by helium. Rubidium atoms are pumped to either the

^{2}P_{\frac{1}{2}}

^{2}P_{\frac{3}{2}}

state by irradiation with one of the resonance lines. Some excited rubidium atoms are transferred to the other

P

state by collisions with helium atoms. The rubidium atoms then radiate both resonance lines. Measurements of the intensities of both resonance lines as a function of helium pressure are used to calculate the collision cross section. The cross section for

^{2}P_{\frac{1}{2}}

^{2}P_{\frac{3}{2}}

is 1.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$

{\mathrm{cm}}^{2}

\ifmmode\pm\else\textpm\fi{}10% and for

^{2}P_{\frac{3}{2}}

^{2}P_{\frac{1}{2}}

is 1.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}17}$

{\mathrm{cm}}^{2}

\ifmmode\pm\else\textpm\fi{}10%.