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Modern Physics Letters A

QUANTIZATION CONDITION FOR HIGHLY EXCITED STATES

Francisco Marcelo Fernández, R. Guardiola

Published Jun 21, 1999• 1 citation
Publisher

Abstract

We develop a quantization condition for the excited states of simple quantum-mechanical models. The approach combines perturbation theory for the oscillatory part of the eigenfunction with a rational approximation to the logarithmic derivative of the nodeless part of it. We choose one-dimensional anharmonic oscillators as illustrative examples.

DOI
10.1142/s0217732399001334

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The solution of the quantum-mechanical eigenvalue problem is discussed for cases when a series of approximate eigenfunctions is known. If these ``unperturbed'' states are divided into two classes, a perturbation formula is derived giving the influence of one class of states on the other in the final solution. The formula contains as special cases: (i) the Schrödinger-Brillouin formula for the eigenvalue of a nondegenerate state, (ii) a new simple formula for treating a class of degenerate states, and (iii) the splitting of the secular equation in cases where the system naturally consists of two independent parts in mutual interaction.
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