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Journal of Applied Physics

Phase Behavior of Models with Competing Interactions

J. C. Bonner, John F. Nagle

Published Mar 15, 1971• 35 citations
Publisher

Abstract

Models with competing nearest-neighbor and very long-range interactions are solved exactly for several one-dimensional cases, including the usual Ising chain (ICCI), the XY model (XYCI), the transverse Ising model (TICCI), and the spherical model (SCCI). For certain ratios of the competing interaction strengths, ICCI and XYCI display triple points and two critical points in a field. In addition TICCI has an apparently enclosed phase in an H-T phase diagram; however, this phase is really paramagnetic as can be seen when an extended phase diagram is used. The extended phase diagrams for ICCI, XYCI, and TICCI display tricritical points and the tricritical exponents have different values from the usual classical values. In contrast to the rich phase behavior of the preceding models, SCCI shows very simple phase behavior, which is directly related to the ground state. Finally, the introduction of a staggered field to ICCI and a simple transformation allows reinterpretation as a metamagnetic model. Using ICCI as a guide the observability of the tricritical exponents is discussed.

DOI
10.1063/1.1660214

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Models with competing nearest-neighbor and very long-range interactions are solved exactly for several one-dimensional cases, including the usual Ising chain (ICCI), the XY model (XYCI), the transverse Ising model (TICCI), and the spherical model (SCCI). For certain ratios of the competing interaction strengths, ICCI and XYCI display triple points and two critical points in a field. In addition TICCI has an apparently enclosed phase in an H-T phase diagram; however, this phase is really paramagnetic as can be seen when an extended phase diagram is used. The extended phase diagrams for ICCI, XYCI, and TICCI display tricritical points and the tricritical exponents have different values from the usual classical values. In contrast to the rich phase behavior of the preceding models, SCCI shows very simple phase behavior, which is directly related to the ground state. Finally, the introduction of a staggered field to ICCI and a simple transformation allows reinterpretation as a metamagnetic model. Using ICCI as a guide the observability of the tricritical exponents is discussed.
The one-dimensional spin-\textonehalf{} Ising model is solved exactly with very long-range, equivalent-neighbor ferromagnetic interactions of strength JLR{J}_{\mathrm{LR}}JLR​ superimposed on nearest-neighbor anti-ferromagnetic interactions of strength $\ensuremath{-}{J}_{\mathrm{sr}}$. For $\ensuremath{-}\frac{{J}_{\mathrm{lr}}}{{J}_{\mathrm{sr}}} >R=3.1532$... there is a critical point of classical type in zero field. For $2\ensuremath{-}\frac{{J}_{\mathrm{lr}}}{{J}_{\mathrm{sr}}}=R$ the critical exponents take the values $\ensuremath{\beta}=\frac{1}{4}$, $\ensuremath{\gamma}=1={\ensuremath{\gamma}}^{\ensuremath{'}}$, $\ensuremath{\delta}=5$, and $0=\ensuremath{\alpha}\ensuremath{\ne}{\ensuremath{\alpha}}^{\ensuremath{'}}=\frac{1}{2}$. For $2<\ensuremath{-}\frac{{J}_{\mathrm{lr}}}{{J}_{\mathrm{sr}}}<R$ the transition in zero field is of first order, and the critical points which occur in finite field are of classical type. For $0<\ensuremath{-}\frac{{J}_{\mathrm{lr}}}{{J}_{\mathrm{sr}}}<2$ there is no phase transition in zero field, although there are classical critical points in a field.
The one-dimensional spin-½ Ising model with very long-range ferromagnetic interaction and first and second neighbor antiferromagnetic interactions is solved exactly in a direct magnetic field. A study of the finite temperature behavior confirms the existence of up to four first-order phase transitions ending in classical critical points. We find a confluence of three critical lines at a ``tricritical'' point with exponents β=14 , δ=5, γ=γ′=1,α=0, and α′=12. We find also a confluence of four critical lines at a ``tetracritical'' point with exponents β=14, δ=7, γ=γ′=1, α=0, and α′=23. We show the existence of triple lines and ``quadruple'' lines, along which three or four phases are simultaneously in contact with each other, respectively. For some special values of the interaction strengths, five phases are in contact with each other at a ``quintuple'' point. We remark that our ``multiple'' lines and ``multicritical'' points are not ``true'' multiple lines and multicritical points but that they would be so in a somewhat extended model. This model satisfies a generalized form of the ordinary phase rule of Gibbs. In distinction to various models considered recently, our model does not exhibit a singular phase-boundary diameter.
Abstract We study the effect of competing interactions on ensemble inequivalence. We consider a one-dimensional Ising model with ferromagnetic mean-field interactions and short-range nearest-neighbor (NN) and next-NN couplings which can be either ferromagnetic or antiferromagnetic. Despite the relative simplicity of the model, our calculations in the microcanonical ensemble reveal a rich phase diagram. The comparison with the corresponding phase diagram in the canonical ensemble shows the presence of phase transition points and lines which are different in the two ensembles. As an example, in a region of the phase diagram where the canonical ensemble shows a critical point and a critical end point, the microcanonical ensemble has an additional critical point and also a triple point. The regions of ensemble inequivalence typically occur at lower temperatures and at larger absolute values of the competing couplings. The presence of two free parameters in the model allows us to obtain a fourth-order critical point, which can be fully characterized by deriving its Landau normal form.
We explore the phase diagram of Ising spins on one-dimensional chains which criss-cross in two perpendicular directions and are connected by interchain couplings. This system is of interest as a simpler, classical analog of a quantum Hamiltonian which has been proposed as a model of magnetic behavior in Nb12_{12}12​O29_{29}29​ and also, conceptually, as a geometry which is intermediate between one and two dimensions. Using mean field theory as well as Metropolis Monte Carlo and Wang-Landau simulations, we locate quantitatively the boundaries of four ordered phases. Each becomes an effective Ising model with unique effective couplings at large interchain coupling. Away from this limit we demonstrate non-trivial critical behavior, including tricritical points which separate first and second order phase transitions. Finally, we find that the crossover of the magnetization critical exponent from the Ising to tricritical Ising value shows an unusual non-monotonic behavior.
We studied a layered metamagnetic Ising model with competing ferromagnetic and antiferromagnetic interactions on a square lattice. The model is formed of ferromagnetic chains coupled by an antiferromagnetic interaction. Using Monte Carlo simulations we have determined the phase diagram of the model, which exhibits a tricritical point. By exploring the short-time scaling dynamics, we have found the dynamic and static critical exponents along the continuous transition line between the antiferromagnetic and paramagnetic phases.
The phase diagrams of Ising antiferromagnets in a magnetic field HHH are investigated for various values of the ratio RRR between nearest- and next-nearest-neighbor interaction. While meanfield approximations and the existing real-space renormalization-group treatments yield phase diagrams which are sometimes even qualitatively incorrect, accurate results are obtained from Monte Carlo calculations. For R<0R<0R<0 only an antiferromagnetically ordered phase exists. Its transition to the disordered phase is first order for temperatures below the tricritical point (Tt{T}_{t}Tt​,Ht{H}_{t}Ht​). For $R\ensuremath{\rightarrow}0$ also ${T}_{t}\ensuremath{\rightarrow}0$. For R=0R=0R=0 we find very good agreement with the results of M\"uller-Hartmann and Zittartz. For R>0R>0R>0 and H1<H<H2{H}_{1}<H<{H}_{2}H1​<H<H2​ a new phase with anomalous high ground-state degeneracy is found (two sublattices have only one-dimensional order). These sublattices undergo order-disorder transitions at T=0T=0T=0, such that for T>0T>0T>0 one is left with a "superantiferromagnetic" phase. At low temperatures in this phase a pronounced tendency is observed to form a simpler (2 \ifmmode\times\else\texttimes\fi{} 2) superstructure but with many antiphase domain boundaries. For $R\ensuremath{\rightarrow}\frac{1}{2}$ and H<H1H<{H}_{1}H<H1​ the regime of the antiferromagnetic phases goes to zero temperature, while for R>12R>\frac{1}{2}R>21​ the superantiferromagnetic phase exists also for H<H1H<{H}_{1}H<H1​. The order-disorder transition associated with this phase seems to have non-Ising critical exponents which vary as a function of RRR and HHH. Estimates for the exponents lead us to suggest that Suzuki's "weak universality" is valid. The behavior of the model at T=0T=0T=0 is related to known results on hard-core lattice gases. It is shown that it is useful to interpret the transitions at T=0T=0T=0 as generalized percolation transitions. Since the model may have applications to adsorbate phases in registered structures at (100) surfaces of cubic crystals, the transcription of our results to temperature-coverage phase diagrams and adsorption isotherms is discussed in detail, and possible experimental applications are mentioned.