Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Spectrochimica Acta Part A Molecular Spectroscopy

Signal line shapes in four-level double resonance spectroscopy with closely spaced levels

Swapan Kumar Mandal, Pradip Narayan Ghosh

Published Nov 1, 1992• 9 citations
Publisher
DOI
10.1016/0584-8539(92)80230-t

Related papers

Disorder and spectral line shapes in two-level systems

Prathamesh Mahesh Shenai, Wu-Jun Shi, Vladimir Chernyak +1 more

Chemical Physics Letters•Jul 20, 2013•1 citation

Line shape, frequency shift, Rabi splitting, and two-photon resonances in four-level double-resonance spectroscopy with closely spaced intermediate levels

Swapan Kumar Mandal, Pradip Narayan Ghosh

The interaction of a four-level atomic system with two electromagnetic radiations has been studied. The two intermediate levels are closely spaced such that a single radiation frequency can induce transitions from the ground state to both of them. In a cascade-type double resonance, the pump electric-field amplitude is much stronger than the amplitude of the signal field, which can induce transitions from both of the intermediate levels to the upper state. The 15 optical Bloch equations obtained from the Liouville equations are solved analytically to obtain the Doppler-free signal line shape. The computed signals, exhibiting two Lorentzian line profiles, are presented for different pump frequencies. In addition to these one-photon transitions, we obtain a weak two-photon resonance peak. The two-photon resonance becomes weaker when the detuning of the pump frequency from a resonance frequency is increased. When the pump frequency ${\mathrm{\ensuremath{\Omega}}}_{\mathit{p}}$ is intermediate between the pump resonance frequencies ${\mathrm{\ensuremath{\omega}}}_{1}$ and ${\mathrm{\ensuremath{\omega}}}_{2}$, the two-photon resonance is very weak and almost vanishes when ${\mathrm{\ensuremath{\Omega}}}_{\mathit{p}}$=(${\mathrm{\ensuremath{\omega}}}_{1}$+${\mathrm{\ensuremath{\omega}}}_{2}$)/2. When the pump frequency is on resonance with one of the transition frequencies, the Rabi splitting of the signal shows asymmetry because of the presence of a close-lying transition which is pumped off resonance. The intensity-dependent shifts of the transitions are such that they repel each other more and more as the intensity of the pump field is increased. These shifts arise from the nonresonant interaction between the atom and the field.

Physical Review A•Jun 1, 1993•18 citations

Observation of high-power resonance line-shapes in an unstable two-level system

David R. Cok, S. R. Lundeen

Physics Letters A•Sep 1, 1981•1 citation

Theory of pump-probe and four-wave mixing spectroscopy

P. R. Berman, G. Khitrova

In this paper we present theoretical calculations relating to pump-probe and four-wave mixing spectroscopy. In pump-probe spectroscopy, one measures the absorption profile for the situation when an arbitrary strong pump field drives a given transition and a probe (weak) field drives the same transition. We have studied the influence of level degeneracy and field polarization on pump-probe and four-wave mixing signals. Our results indicate that for some closed systems (no population loss to the reservoir) it is possible to observe resonances that are characterized by the ground state width. Previous calculations indicate that for a nondegenerate system this resonance can appear only for an open system, the so-called "pressure induced resonances.”1 Our result, which contradicts this conclusion, can be understood by noting the fact that there are in general three irreducible tensor2 (in general) contributions to the line shape (K = 0 population, K = 1 orientation, and K = 2 alignment). Thus, even if the system is closed for the population it may still remain open for orientation or alignment; this effect is responsible for the narrow resonance. Specific calculations are presented for J = 1/2 → 1/2 and J = 1→2 transitions.

Conference on Lasers and Electro-Optics•Jan 1, 1986•0 citations

Effects of field-induced quantum coherence on the absorptive line shape of a four-level system with three closely spaced upper levels

Saswata Ghosh, Swapan Mandal

The optical Bloch equations of a four-level atomic system with three closely spaced upper levels irradiated by a single mode of the electromagnetic radiation field are constructed. Under the rotating wave approximation and by using the slowly varying envelope approximation, we obtain the analytical solution to these optical Bloch equations. These solutions, which are obtained perturbatively, are used to calculate the polarization and hence the absorptive line shape. In particular, we examine the effects of the field-induced coherence arising from the interference between the probability amplitudes of the levels participating in dipole-allowed transitions. We obtain the shifts of the resonance peak positions due to two different reasons. The first is due to the nonlinear effects arising from the closely spaced nature of the peaks. The second is attributed to the field-induced coherence alone. It is found that the shifts of the positions of the resonance peaks due to field-induced coherence may be in the blue or in the red region.

Physical Review A•Aug 19, 2004•16 citations

Line shapes in nonlinear spectroscopy

Lewis S. Klein

Foundations of Physics•May 1, 1992•0 citations
The interaction of a four-level atomic system with two electromagnetic radiations has been studied. The two intermediate levels are closely spaced such that a single radiation frequency can induce transitions from the ground state to both of them. In a cascade-type double resonance, the pump electric-field amplitude is much stronger than the amplitude of the signal field, which can induce transitions from both of the intermediate levels to the upper state. The 15 optical Bloch equations obtained from the Liouville equations are solved analytically to obtain the Doppler-free signal line shape. The computed signals, exhibiting two Lorentzian line profiles, are presented for different pump frequencies. In addition to these one-photon transitions, we obtain a weak two-photon resonance peak. The two-photon resonance becomes weaker when the detuning of the pump frequency from a resonance frequency is increased. When the pump frequency ${\mathrm{\ensuremath{\Omega}}}_{\mathit{p}}$ is intermediate between the pump resonance frequencies ${\mathrm{\ensuremath{\omega}}}_{1}$ and ${\mathrm{\ensuremath{\omega}}}_{2}$, the two-photon resonance is very weak and almost vanishes when ${\mathrm{\ensuremath{\Omega}}}_{\mathit{p}}$=(${\mathrm{\ensuremath{\omega}}}_{1}$+${\mathrm{\ensuremath{\omega}}}_{2}$)/2. When the pump frequency is on resonance with one of the transition frequencies, the Rabi splitting of the signal shows asymmetry because of the presence of a close-lying transition which is pumped off resonance. The intensity-dependent shifts of the transitions are such that they repel each other more and more as the intensity of the pump field is increased. These shifts arise from the nonresonant interaction between the atom and the field.
In this paper we present theoretical calculations relating to pump-probe and four-wave mixing spectroscopy. In pump-probe spectroscopy, one measures the absorption profile for the situation when an arbitrary strong pump field drives a given transition and a probe (weak) field drives the same transition. We have studied the influence of level degeneracy and field polarization on pump-probe and four-wave mixing signals. Our results indicate that for some closed systems (no population loss to the reservoir) it is possible to observe resonances that are characterized by the ground state width. Previous calculations indicate that for a nondegenerate system this resonance can appear only for an open system, the so-called "pressure induced resonances.”1 Our result, which contradicts this conclusion, can be understood by noting the fact that there are in general three irreducible tensor2 (in general) contributions to the line shape (K = 0 population, K = 1 orientation, and K = 2 alignment). Thus, even if the system is closed for the population it may still remain open for orientation or alignment; this effect is responsible for the narrow resonance. Specific calculations are presented for J = 1/2 → 1/2 and J = 1→2 transitions.
The optical Bloch equations of a four-level atomic system with three closely spaced upper levels irradiated by a single mode of the electromagnetic radiation field are constructed. Under the rotating wave approximation and by using the slowly varying envelope approximation, we obtain the analytical solution to these optical Bloch equations. These solutions, which are obtained perturbatively, are used to calculate the polarization and hence the absorptive line shape. In particular, we examine the effects of the field-induced coherence arising from the interference between the probability amplitudes of the levels participating in dipole-allowed transitions. We obtain the shifts of the resonance peak positions due to two different reasons. The first is due to the nonlinear effects arising from the closely spaced nature of the peaks. The second is attributed to the field-induced coherence alone. It is found that the shifts of the positions of the resonance peaks due to field-induced coherence may be in the blue or in the red region.