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Physical Review E

Work statistics of charged noninteracting fermions in slowly changing magnetic fields

Juyeon Yi, Peter Talkner A

Published Apr 20, 2011• 11 citations
Publisher

Abstract

We consider N fermionic particles in a harmonic trap initially prepared in a thermal equilibrium state at temperature β^{-1} and examine the probability density function (pdf) of the work done by a magnetic field slowly varying in time. The behavior of the pdf crucially depends on the number of particles N but also on the temperature. At high temperatures (β≪1) the pdf is given by an asymmetric Laplace distribution for a single particle, and for many particles it approaches a Gaussian distribution with variance proportional to N/β(2). At low temperatures the pdf becomes strongly peaked at the center with a variance that still linearly increases with N but exponentially decreases with the temperature. We point out the consequences of these findings for the experimental confirmation of the Jarzynski equality such as the low probability issue at high temperatures and its solution at low temperatures, together with a discussion of the crossover behavior between the two temperature regimes.

DOI
10.1103/physreve.83.041119

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We consider N fermionic particles in a harmonic trap initially prepared in a thermal equilibrium state at temperature β^{-1} and examine the probability density function (pdf) of the work done by a magnetic field slowly varying in time. The behavior of the pdf crucially depends on the number of particles N but also on the temperature. At high temperatures (β≪1) the pdf is given by an asymmetric Laplace distribution for a single particle, and for many particles it approaches a Gaussian distribution with variance proportional to N/β(2). At low temperatures the pdf becomes strongly peaked at the center with a variance that still linearly increases with N but exponentially decreases with the temperature. We point out the consequences of these findings for the experimental confirmation of the Jarzynski equality such as the low probability issue at high temperatures and its solution at low temperatures, together with a discussion of the crossover behavior between the two temperature regimes.
We consider bosons in a harmonic trap and investigate the fluctuations of the work performed by an adiabatic change of the trap curvature. Depending on the reservoir conditions such as temperature and chemical potential that provide the initial equilibrium state, the exponentiated work average (EWA) defined in the context of the Crooks relation and the Jarzynski equality may diverge if the trap becomes wider. We investigate how the probability distribution function (PDF) of the work signals this divergence. It is shown that at low temperatures the PDF is highly asymmetric with a steep fall-off at one side and an exponential tail at the other side. For high temperatures it is closer to a symmetric distribution approaching a Gaussian form. These properties of the work PDF are discussed in relation to the convergence of the EWA and to the existence of the hypothetical equilibrium state to which those thermodynamic potential changes refer that enter both the Crooks relation and the Jarzynski equality.
We consider a quantum charged particle moving in the xyxyxy plane under the action of a uniform perpendicular constant magnetic field, in the presence of a parabolic binding potential. The magnetic-moment operator has a continuous spectrum, and its eigenfunctions in the momentum representation are expressed in terms of modified Bessel functions. The probability distribution of the magnetic moment in the thermodynamic equilibrium state is calculated. At zero temperature, it has a simple exponential form in the diamagnetic region, with a sharp jump to zero at the origin. With an increase of temperature, a paramagnetic wing of the distribution becomes more and more pronounced. In the high-temperature regime, the diamagnetic and paramagnetic wings of the distribution have almost identical forms, described with a high precision by simple exponential functions with very large extensions. Therefore, diamagnetic and paramagnetic contributions almost cancel each other. The remaining non-zero diamagnetic value is due to a small asymmetry of the distribution nearby the origin, where some nonexponential fine structure is observed. The total width of the distribution function strongly depends on the strength of the binding potential. Strong fluctuations of the magnetic moment (described in terms of the variance) are discovered in all temperature regimes.
One-particle properties of noninteracting fermions in a one-dimensional harmonic trap and at zero temperature are studied. Exact expressions and asymptotic results for a large fermion number N are given for the particle density distribution n0(z,N).{n}_{0}(z,N).n0​(z,N). For large N and near the classical boundary at the Fermi energy, the density displays increasing fluctuations. A simple scaling of these tails of the density distribution with respect to N is established. The Fourier transform of the density distribution is calculated exactly. It displays a small but characteristic hump near 2kF,{2k}_{F},2kF​, with kF{k}_{F}kF​ being a properly defined Fermi wave number. This is due to Friedel oscillations, which are identified and discussed. These quantum effects are missing in the semiclassical approximation. Momentum distributions are also evaluated and discussed. As an example of a time-dependent one-particle problem, we calculate exactly the evolution of the particle density when the trap is suddenly switched off, and find a simple scaling behavior, in agreement with recent general results.
In the context of nonequilibrium quantum thermodynamics, variables like work behave stochastically. A particular definition of the work probability density function (pdf) for coherent quantum processes allows the verification of the quantum version of the celebrated fluctuation theorems, due to Jarzynski and Crooks, that apply when the system is driven away from an initial equilibrium thermal state. Such a particular pdf depends basically on the details of the initial and final Hamiltonians, on the temperature of the initial thermal state, and on how some external parameter is changed during the coherent process. Using random matrix theory we derive a simple analytic expression that describes the general behavior of the work characteristic function G(u), associated with this particular work pdf for sudden quenches, valid for all the traditional Gaussian ensembles of Hamiltonians matrices. This formula well describes the general behavior of G(u) calculated from single draws of the initial and final Hamiltonians in all ranges of temperatures.
Abstract I consider a quantum spinless charged particle moving in the xy plane under the action of a time-dependent magnetic field described by means of the linear vector potential in the ‘circular’ gauge A = B ( t )(− y , x )/2 and in the presence of the confining potential m g 2 x 2 + y 2 / 2 . This potential guarantees finite values of all second-order moments in the initial equilibrium (thermal) state. Time-dependent mean values of the energy and magnetic moment are expressed in terms of solutions to the classical equation of motion ε ̈ + Ω 2 ( t ) ε = 0 . Simple approximate results are found in the cases of the sudden jump of magnetic field, the parametric resonance, and the adiabatic evolution. They are compared with exact solutions in terms of the hypergeometric function for the specific function B ( t ) of the Epstein–Eckart type. A great amplification of the magnetic moment is discovered for the initial high-temperature states, both for the fast and slow monotonous variations of the magnetic field. Classical adiabatic invariants do not exist if the magnetic field slowly goes to zero or changes its sign.
A result of great theoretical and experimental interest, the Jarzynski equality predicts a free energy change $\mathrm{\ensuremath{\Delta}}F$ of a system at inverse temperature $\ensuremath{\beta}$ from an ensemble average of nonequilibrium exponential work, i.e., $\ensuremath{\langle}{e}^{\ensuremath{-}\ensuremath{\beta}W}\ensuremath{\rangle}={e}^{\ensuremath{-}\ensuremath{\beta}\mathrm{\ensuremath{\Delta}}F}$. The number of experimental work values needed to reach a given accuracy of $\mathrm{\ensuremath{\Delta}}F$ is determined by the variance of ${e}^{\ensuremath{-}\ensuremath{\beta}W}$, denoted $\mathrm{var}({e}^{\ensuremath{-}\ensuremath{\beta}W})$. We discover in this work that $\mathrm{var}({e}^{\ensuremath{-}\ensuremath{\beta}W})$ in both harmonic and anharmonic Hamiltonian systems can systematically diverge in nonadiabatic work protocols, even when the adiabatic protocols do not suffer from such divergence. This divergence may be regarded as a type of dynamically induced phase transition in work fluctuations. For a quantum harmonic oscillator with time-dependent trapping frequency as a working example, any nonadiabatic work protocol is found to yield a diverging $\mathrm{var}({e}^{\ensuremath{-}\ensuremath{\beta}W})$ at sufficiently low temperatures, markedly different from the classical behavior. The divergence of $\mathrm{var}({e}^{\ensuremath{-}\ensuremath{\beta}W})$ indicates the too-far-from-equilibrium nature of a nonadiabatic work protocol and makes it compulsory to apply designed control fields to suppress the quantum work fluctuations in order to test the Jarzynski equality.