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arXiv:1802.10559 · Physical review. E

Quantum work for sudden quenches in Gaussian random Hamiltonians

Eric G. Arrais, Diego A. Wisniacki, Lucas C. Céleri, N. G. de Almeida, Augusto J. Roncaglia, Fabricio Toscano

Published Jul 5, 2018• 16 citations
arXivHTMLPDF

Abstract

In the context of nonequilibrium quantum thermodynamics, variables like work behave stochastically. A particular definition of the work probability density function (pdf) for coherent quantum processes allows the verification of the quantum version of the celebrated fluctuation theorems, due to Jarzynski and Crooks, that apply when the system is driven away from an initial equilibrium thermal state. Such a particular pdf depends basically on the details of the initial and final Hamiltonians, on the temperature of the initial thermal state, and on how some external parameter is changed during the coherent process. Using random matrix theory we derive a simple analytic expression that describes the general behavior of the work characteristic function G(u), associated with this particular work pdf for sudden quenches, valid for all the traditional Gaussian ensembles of Hamiltonians matrices. This formula well describes the general behavior of G(u) calculated from single draws of the initial and final Hamiltonians in all ranges of temperatures.

DOI
10.1103/physreve.98.012106

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We derive an exact analytical expression for the characteristic function of work in closed many-body bosonic systems governed by general time-dependent quadratic Hamiltonians. This is made possible by adopting a unified prescription in which all operators appearing in the characteristic function are treated as elements of the inhomogeneous Metaplectic group. The esulting expression involves a single symplectic matrix, a single phase-space displacement, and a single accumulated phase. It holds for any number of degrees of freedom, arbitrary time dependence of the quadratic Hamiltonian, and any initial thermal equilibrium state of the system. The formalism trades the explicit time-ordering problem associated with the unitary evolution for the determination of a symplectic path in phase space, from which the corresponding driving Hamiltonian can be reconstructed. We also discuss the generalization to arbitrary nonequilibrium initial states within the two-projective-measurement scheme for quantum work. The same construction yields Loschmidt echoes and mixed-state total phases. Using the derived characteristic function, we obtain formulas for the Helmholtz free energy, the Jarzynski equality, the mean work, the work variance, and the nonequilibrium lag. Undisplaced Hamiltonians, sudden quenches, constant-Hessian protocols, and the adiabatic limit follow as special cases of the general result. As an illustration, we analyze a one-dimensional system constructed from an unconventional symplectic path and exhibiting physically relevant limiting cases. We then show how affine and purely symplectic contributions affect work statistics and irreversibility.

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In the context of nonequilibrium quantum thermodynamics, variables like work behave stochastically. A particular definition of the work probability density function (pdf) for coherent quantum processes allows the verification of the quantum version of the celebrated fluctuation theorems, due to Jarzynski and Crooks, that apply when the system is driven away from an initial equilibrium thermal state. Such a particular pdf depends basically on the details of the initial and final Hamiltonians, on the temperature of the initial thermal state, and on how some external parameter is changed during the coherent process. Using random matrix theory we derive a simple analytic expression that describes the general behavior of the work characteristic function G(u), associated with this particular work pdf for sudden quenches, valid for all the traditional Gaussian ensembles of Hamiltonians matrices. This formula well describes the general behavior of G(u) calculated from single draws of the initial and final Hamiltonians in all ranges of temperatures.
Work in isolated quantum systems is a random variable and its probability distribution function obeys the celebrated fluctuation theorems of Crooks and Jarzynski. In this study, we provide a simple way to describe the work probability distribution function for sudden quench processes in quantum systems with large Hilbert spaces. This description can be constructed from two elements: the level density of the initial Hamiltonian, and a smoothed strength function that provides information about the influence of the perturbation over the eigenvectors in the quench process, and is especially suited to describe quantum many-body interacting systems. We also show how random models can be used to find such smoothed work probability distribution and apply this approach to different one-dimensional spin-1/2 chain models. Our findings provide an accurate description of the work distribution of such systems in the cases of intermediate and high temperatures in both chaotic and integrable regimes.
The statistics of work performed on a system by a sudden random quench is investigated. Considering systems with finite dimensional Hilbert spaces we model a sudden random quench by randomly choosing elements from a Gaussian unitary ensemble (GUE) consisting of Hermitian matrices with identically, Gaussian distributed matrix elements. A probability density function (pdf) of work in terms of initial and final energy distributions is derived and evaluated for a two-level system. Explicit results are obtained for quenches with a sharply given initial Hamiltonian, while the work pdfs for quenches between Hamiltonians from two independent GUEs can only be determined in explicit form in the limits of zero and infinite temperature. The same work distribution as for a sudden random quench is obtained for an adiabatic, i.e., infinitely slow, protocol connecting the same initial and final Hamiltonians.
Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate spectra. In the particular case of microcanonical initial states, explicit expressions for the characteristic function and the corresponding probability density of work are formulated. Their classical limit as well as their relations to the corresponding canonical expressions are discussed. A fluctuation theorem is derived that expresses the ratio of probabilities of work for a process and its time reversal to the ratio of densities of states of the microcanonical equilibrium systems with corresponding initial and final Hamiltonians. From this Crooks-type fluctuation theorem a relation between entropies of different systems can be derived which does not involve the time-reversed process. This entropy-from-work theorem provides an experimentally accessible way to measure entropies.
The concept of work is basic for statistical thermodynamics. To gain a fuller understanding of work and its (quantum) features, it needs to be represented as an average of a fluctuating quantity. Here I focus on the work done between two moments of time for a thermally isolated quantum system driven by a time-dependent Hamiltonian. I formulate two natural conditions needed for the fluctuating work to be physically meaningful for a system that starts its evolution from a nonequilibrium state. The existing definitions do not satisfy these conditions due to issues that are traced back to noncommutativity. I propose a definition of fluctuating work that is free of previous drawbacks and that applies for a wide class of nonequilibrium initial states. It allows the deduction of a generalized work-fluctuation theorem that applies for an arbitrary (out-of-equilibrium) initial state.
We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.
We derive an exact analytical expression for the characteristic function of work in closed many-body bosonic systems governed by general time-dependent quadratic Hamiltonians. This is made possible by adopting a unified prescription in which all operators appearing in the characteristic function are treated as elements of the inhomogeneous Metaplectic group. The esulting expression involves a single symplectic matrix, a single phase-space displacement, and a single accumulated phase. It holds for any number of degrees of freedom, arbitrary time dependence of the quadratic Hamiltonian, and any initial thermal equilibrium state of the system. The formalism trades the explicit time-ordering problem associated with the unitary evolution for the determination of a symplectic path in phase space, from which the corresponding driving Hamiltonian can be reconstructed. We also discuss the generalization to arbitrary nonequilibrium initial states within the two-projective-measurement scheme for quantum work. The same construction yields Loschmidt echoes and mixed-state total phases. Using the derived characteristic function, we obtain formulas for the Helmholtz free energy, the Jarzynski equality, the mean work, the work variance, and the nonequilibrium lag. Undisplaced Hamiltonians, sudden quenches, constant-Hessian protocols, and the adiabatic limit follow as special cases of the general result. As an illustration, we analyze a one-dimensional system constructed from an unconventional symplectic path and exhibiting physically relevant limiting cases. We then show how affine and purely symplectic contributions affect work statistics and irreversibility.