An investigation was made of the dependences of the initial I(5 2 P 1/2 )→I(5 2 P 3/2 )+ hν ( λ = 1315nm) luminescence signal on the pressure and nature of the buffer gases. Atoms of I in the 5 2 P 1/2 state were formed, in initial concentrations of (0.5–3)×10 16 cm −3 , as a result of photolysis of CF 3 I (0.01 atm) by the fourth harmonic of a Q -switched neodymium laser ( E ∼0.6 J, τ ∼2×10 −3 sec). The I(5 2 P 1/2 ) luminescence was recorded by a germanium photodiode whose time constant was (3–4)×10 −7 sec. When CF 3 I was diluted with Ar, Xe, and SF 6 buffer gases, the intensity of the luminescence of the I(5 2 P 1/2 ) atoms increased because of an increase in the probability of the 5 2 P 1/2 →5 2 P 3/2 transition as a result of collisions of the iodine atoms with the atoms or molecules of the buffer gases. The dependence of the probability of the investigated transition on the nature and pressure of the buffer gases was determined in the pressure range ∼0–1 atm. Estimates were obtained of the oscillator strengths corresponding to the matrix elements of the induced electric dipole moment due to the deformation of the electron shells of the iodine atoms in collisions.
Frequency-modulated light was generated by the application of a magnetic field oscillating at frequencies in the range 1-10 MHz to mercury vapour undergoing resonance fluorescence. The characteristics of the fluorescent light have been studied. When the primary illumination in the plane perpendicular to the field is anisotropic the sigma components are coherently excited. The light emitted along the field is then polarization-modulated. It becomes intensity-modulated if it is passed through a linear analyser. The light emitted obliquely to the magnetic field is intensity-modulated without passing through an analyser. The amplitudes of these modulations show resonance behaviour under the application of an additional static field parallel to the oscillating field. The polarization-modulated light was used to excite resonance fluorescence in a second cell of mercury vapour. The fluorescent light is intensity-modulated. The amplitude of modulation shows resonance behaviour when harmonics of the driving frequency coincide with Zeeman intervals in the excited atoms. These resonances have been explored in detail. They are satisfactorily interpreted by a theory given in an accompanying paper.
We have calculated the excitation spectra of a single electron in the excited state of a four-level atom interacting with three laser fields at low intensities, where two of them are on two-photon resonance with the three levels of the atom, while the third laser is a weak one operating between the fourth and excited level of the atom. It is shown that light is switched off at certain frequency due to the coherent population trapping while light is turned on at another frequency, where stimulated emission occurs leading to light amplification without population inversion.
We have investigated the two basic types of Hanle fluorescence spectra, distinguished by the direction of observation, from a V-type atom with a
Jg =0\ensuremath{\leftrightarrows}
Je =1 transition excited by a linearly polarized laser. In the absence of a magnetic field to lift the Zeeman degeneracy of the sublevels, the incoherent fluorescence spectrum
GXinc(\ensuremath{\omega}) is dark for all Rabi frequencies, while the incoherent fluorescence spectrum
GYinc(\ensuremath{\omega}) exhibits a single peak for small Rabi frequencies and a Mollow-like triplet for large Rabi frequencies. However, if a magnetic field is applied, the incoherent spectra are composed, in general, of five peaks. When ${\mathrm{\ensuremath{\omega}}}_{\mathrm{B}}$ \ensuremath{\ll}\ensuremath{\Omega}, the incoherent spectrum
GXinc(\ensuremath{\omega}) has four peaks, while
GYinc(\ensuremath{\omega}) has a Mollow-like triplet, and the integrated area (i.e., the fluorescence intensity) under the spectrum
GXinc(\ensuremath{\omega}) is much less than that of
GYinc(\ensuremath{\omega}). When ${\mathrm{\ensuremath{\omega}}}_{\mathrm{B}}$ \ensuremath{\gg}:\ensuremath{\Omega}, both incoherent spectra have a two-peak structure similar to that of a two-level atom far off resonance, but the integrated area under the spectrum
GXinc(\ensuremath{\omega}) is much greater than that of
GYinc(\ensuremath{\omega}). When ${\mathrm{\ensuremath{\omega}}}_{\mathrm{B}}$ =\ensuremath{\Omega}\ensuremath{\gg}:\ensuremath{\gamma}, both spectra have a similar five-peak structure, and the same integrated area. The results obtained are interpreted in the dressed atomic state representation. In the strong-field limit, the secular approximation is invoked, and analytical expressions of the resonance fluorescence spectra are derived which demonstrate the dependence of the peak heights and widths of the resonance fluorescence spectra on the intensities of the magnetic and linear polarized laser fields in a more transparent way.