We report observation of laser excitation of a narrow, magnetic-dipole-allowed, infrared transition in a single trapped ion. Quantum jumps of a
Ba+ atom were observed using a diode laser tuned in resonance with the excited-state 5d
2D3/2--5d
2D5/2 transition at 12.48 \ensuremath{\mu}m. Single-ion resonance line shapes were obtained and a transition frequency of \ensuremath{\nu}=24 012 033\ifmmode\pm\else\textpm\fi{}11 MHz was determined. Calculated quantum jump rates of the D-D transition for the applied laser spectral brightness yield agreement with experimentally observed values.