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Proceedings of the Royal Society of London Series A Containing Papers of a Mathematical and Physical Character

The physical principles of the quantum theory

George Frederick James Temple

Published Dec 1, 1932• 380 citations
Publisher

Abstract

Abstract The object of this paper is to reformulate the principles of the quantum theory as a sequence of propositions which shall be either summary statements of standard experimental procedure or hypotheses concerning the results of experiment and having an immediate physical interpretation. It is shown that the standard process in micro-physics is a generalised spectral analysis, whose properties are simply expressible in symbolic form by means of projective or “idempotent” operators (Einzeloperatoren). It appears that only two hypotheses need be made and that these relate to the existence and properties of transition probabilities. From these fundamental principles, which have a direct physical significance, it is possible to deduce the subsidiary principles which form the accepted basis of the mathematical analysis of the quantum theory and which deal with the representation of quantum states and physical quantities by vectors and linear operators respectively. In this paper the emphasis is laid on the experimental process determining a state of a system and on the associated operators rather than on the state itself or the vector representing it in the system space. Projective operators, which represent actual processes of measurement, and unitary operators, which represent actual transformations of systems of measurement, are given priority over the (statistical) operators which represent physical variables. This method of representation makes the physical meaning of the theory fundamental, instead of leaving it to be extracted from a purely mathematical system of non-commutative algebra or differential equations.

DOI
10.1098/rspa.1932.0197

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Abstract The object of this paper is to reformulate the principles of the quantum theory as a sequence of propositions which shall be either summary statements of standard experimental procedure or hypotheses concerning the results of experiment and having an immediate physical interpretation. It is shown that the standard process in micro-physics is a generalised spectral analysis, whose properties are simply expressible in symbolic form by means of projective or “idempotent” operators (Einzeloperatoren). It appears that only two hypotheses need be made and that these relate to the existence and properties of transition probabilities. From these fundamental principles, which have a direct physical significance, it is possible to deduce the subsidiary principles which form the accepted basis of the mathematical analysis of the quantum theory and which deal with the representation of quantum states and physical quantities by vectors and linear operators respectively. In this paper the emphasis is laid on the experimental process determining a state of a system and on the associated operators rather than on the state itself or the vector representing it in the system space. Projective operators, which represent actual processes of measurement, and unitary operators, which represent actual transformations of systems of measurement, are given priority over the (statistical) operators which represent physical variables. This method of representation makes the physical meaning of the theory fundamental, instead of leaving it to be extracted from a purely mathematical system of non-commutative algebra or differential equations.
Quantum theory is the soul of contemporary physics. It was discovered in an adventurous way, under the urge to solve the puzzles posed by atomic spectra and blackbody radiation. But after its invention, it immediately became clear that it was not just a theory of specific physical systems: it was rather a new language of universal applicability. Already in 1928, the theory had received solid mathematical foundations by Hilbert, von Neumann, and Nordheim, and this work was brought to completion in the monumental work of von Neumann, in the form that we still study nowadays. The theory is extraordinarily successful, and its predictions have been confirmed to an astonishing level of precision in a large spectrum of experiments. However, almost 90 years after von Neumann's book, quantum theory remains mysterious. Its mathematical formulation – based on Hilbert spaces and self-adjoint operators – is far from having an intuitive interpretation. The association of physical systems to Hilbert spaces whose unit vectors represent pure states, the representation of transformations by unitary operators and of observables by self-adjoint operators – all such postulates look artificial and ad hoc . A slightly more operational approach is provided by the C * -algebraic formulation of quantum theory – still, this formulation relies on the assumption that observables form an algebra , where the physical meanings of the multiplication and the sum are far from clear. In short, the postulates of quantum theory impose mathematical structures without providing any simple reason for this choice: the mathematics of Hilbert spaces is adopted as a magic blackbox that “works well” at producing experimental predictions. However, in a satisfactory axiomatization of a physical theory the mathematical structures should emerge as a consequence of postulates that have a direct physical interpretation. By this we mean postulates referring, e.g., to primitive notions like physical system, measurement, or process, rather than notions like, e.g., Hilbert space, C * -algebra, unit vector, or selfadjoint operator. The crucial question thus remains unanswered: why quantum theory? Which are the principles at the basis of the theory? A case that is often invoked in contrast is that of Special Relativity theory, which directly follows from the simple understandable principle of relativity.
Abstract Mathematical formalism of quantum mechanics is closely connected with the theory of linear operators. A key quantum-mechanical principle is that physical quantities (observables) are represented by Hermitian linear operators that act on state vectors that belong to a Hilbert vector space. This chapter analyzes problems that deal with the basic concepts of the theory of linear operators; eigenfunctions, eigenvalues, mean values; the projection operators; quantum-mechanical representations of operators and wave-functions; and unitary operators.
We present in this paper a set of postulates for a physical system and deduce from these the main general features of the quantum theory of stationary states. Our theory is strictly operational in the sense that only the observables of the physical system are involved in the postulates. The collection of all bounded self-adj oint operators on a Hilbert space, which has previously been used as a mathematical model for the observables in quantum mechanics, satisfy the postulates, as do a variety of considerably more general mathematical structures. We show that for any two observables there exists a pure state of the system (this term being defined essentially as done by von Neumann and Weyl) in which they have different (expectation) values. Each observable has a spectral resolution, and a state of the system induces, in a natural way, a probability distribution on the range of spectral values of each observable. A number of observables are simultaneously observable if and only if they commute (although the product of two observables is not defined in general, a reasonable notion of commutativity can be introduced). Inasmuch as Hilbert space plays no role in our theory, our proofs are necessarily of a different character from the proofs of these results for the case of the system of all bounded selfadjoint operators. Actually, Hilbert space appears to be somewhat inadequate as a state space even for the latter system, in that there exist pure states of the system which cannot be represented in the usual way by rays of the Hilbert space. The postulates are partly algebraic and partly metric. The algebraic postulates require essentially that an observable can be multiplied by real numbers and raised to integral powers, and that any two observables can be added. It is assumed that the usual algebraic laws are satisfied so that (1) the observables can be treated like the elements of a linear space, and (2) the usual rules for dealing with polynomials in one variable with real coefficients remain valid when the variable is replaced by an observable. It is not assumed that two observables have a product. The metric postulates require that for each observable there be defined a kind of maximum numerical value, which plays the part of a norm, and has various properties in accord with its physical significance. While this norm is quite essential to the development of the theory, an interesting consequence of the theory is that the norm can be (uniquely) defined in a purely algebraic fashion. This shows that the objective features of a physical system,-the spectral values and probability distributions of the observables, and the pure states,-are completely determined by the algebra of observables, i.e., by the rules for addition, scalar multiplication, and powers, of observables.
Extracting information from a quantum system inevitably requires the performance of a measurement, and it is no surprise that the theory of measurement plays a central role in our subject. The physical nature of the measurement process remains one of the great philosophical problems in the formulation of quantum theory. Fortunately, however, it is sufficient for us to take a pragmatic view by asking what measurements are possible and how the theory describes them, without addressing the physical mechanism of the measurement process. This is the approach we shall adopt. We shall find that it leads us to a powerful and general description of both the probabilities associated with measurement outcomes and the manner in which the observation transforms the quantum state of the measured system. The simplest form of measurement was given a mathematical formulation by von Neumann, and we shall refer to measurements of this type as von Neumann measurements or projective measurements. It is this description of measurements that is usually introduced in elementary quantum theory courses. We start with an observable quantity A represented by a Hermitian operator Â, the eigenvalues of which are the possible results of the measurement of A. The relationship between the operator, its eigenstates {|λnñ}, and its (real) eigenvalues {λn} is expressed by the eigenvalue equation . . . Â |λn_ = λn|λn_. (4.1) . . .
This work develops a conceptual framework for the foundations of quantum physics, linking two main approaches: the algebraic formulation and quantum probability. Rather than proposing new axioms or theories, the text reorganizes and synthesizes existing models, highlighting their assumptions, conceptual structures, and operational significance. The analysis begins with von Neumann's measurement theory and its subsequent developments by Mackey, emphasizing the role of experimentally feasible procedures and the need for a statistical model grounded in laboratory practice. The work adopts an operational perspective, according to which physical quantities are defined solely through experimental measurement methods, and the corresponding probabilistic measures are derived from measurement outcomes. The introduction critically examines the limitations of purely mathematical formulations - such as the algebraic method - when separated from experimental interpretation. The text argues for a clear distinction between axioms, postulates, and presuppositions, and for a reconstruction of quantum theory that respects both empirical constraints and conceptual clarity. Overall, the goal is to provide a coherent path from operational principles to algebraic structures, offering a basis for an axiomatic reformulation of quantum mechanics that remains faithful to physical practice.
Abstract This chapter develops the fundamental notions and concepts of the probabilistic and statistical interpretation of quantum mechanics. It begins with a brief review of the mathematical structure given by a Hilbert space of state vectors and an algebra of observables represented by selfadjoint operators. Special emphasis is laid on the connection between the spectral representation of a selfadjoint operator and a corresponding random variable that describes the possible measurement outcomes. The chapter further introduces the concepts of a composite quantum system, of the reduced density matrix, and of entangled quantum states. A section on quantum entropies is included, as well as the mathematical formulation of the generalized theory of quantum measurements in terms of completely positive quantum operations and effects.