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Reviews of Modern Physics

Phase and Angle Variables in Quantum Mechanics

Peter Carruthers, Michael Martin Nieto

Published Apr 1, 1968• 1,108 citations
Publisher

Abstract

The quantum-mechanical description of phase and angle variables is reviewed, with emphasis on the proper mathematical description of these coordinates. The relations among the operators and state vectors under consideration are clarified in the context of the Heisenberg uncertainty relations. The familiar case of the azimuthal angle variable $\ensuremath{\phi}$ and its "conjugate" angular momentum ${L}_{z}$ is discussed. Various pitfalls associated with the periodicity problem are avoided by employing periodic variables ($sin\ensuremath{\phi}$ and $cos\ensuremath{\phi}$ to describe the phase variable. Well-defined uncertainty relations are derived and discussed. A detailed analysis of the three-dimensional harmonic oscillator excited in coherent states is given. A detailed analysis of the simple harmonic oscillator is given. The usual assumption that a (Hermitian) phase operator $\ensuremath{\varphi}$ (conjugate to the number operator $N$) exists is shown to be erroneous. However, cosine and sine operators $C$ and $S$ exist and are the appr\'opriate phase variables. A Poisson bracket argument using action-angle (rather $J$, $cos\ensuremath{\varphi}$, $sin\ensuremath{\varphi}$) variables is used to deduce $C$ and $S$. The spectra and eigenfunctions of these operators are investigated, along with the important "phase-difference" periodic variables. The properties of the oscillator variables in the various types of states are analyzed with special attention to the uncertainty relations and the transition to the classical limit. The utility of coherent states as a basis for the description of the evolution of the density matrix is emphasized. In this basis it is easy to identify the classical Liouville equation in action-angle variables along with quantum-mechanical "corrections." Mention is made of possible physical applications to superfluid systems.

DOI
10.1103/revmodphys.40.411

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Physical Review A•May 1, 1994•70 citations
The quantum-mechanical description of phase and angle variables is reviewed, with emphasis on the proper mathematical description of these coordinates. The relations among the operators and state vectors under consideration are clarified in the context of the Heisenberg uncertainty relations. The familiar case of the azimuthal angle variable \ensuremathϕ\ensuremath{\phi}\ensuremathϕ and its "conjugate" angular momentum Lz{L}_{z}Lz​ is discussed. Various pitfalls associated with the periodicity problem are avoided by employing periodic variables (sin\ensuremathϕsin\ensuremath{\phi}sin\ensuremathϕ and cos\ensuremathϕcos\ensuremath{\phi}cos\ensuremathϕ to describe the phase variable. Well-defined uncertainty relations are derived and discussed. A detailed analysis of the three-dimensional harmonic oscillator excited in coherent states is given. A detailed analysis of the simple harmonic oscillator is given. The usual assumption that a (Hermitian) phase operator \ensuremathφ\ensuremath{\varphi}\ensuremathφ (conjugate to the number operator NNN) exists is shown to be erroneous. However, cosine and sine operators CCC and SSS exist and are the appr'opriate phase variables. A Poisson bracket argument using action-angle (rather JJJ, cos\ensuremathφcos\ensuremath{\varphi}cos\ensuremathφ, sin\ensuremathφsin\ensuremath{\varphi}sin\ensuremathφ) variables is used to deduce CCC and SSS. The spectra and eigenfunctions of these operators are investigated, along with the important "phase-difference" periodic variables. The properties of the oscillator variables in the various types of states are analyzed with special attention to the uncertainty relations and the transition to the classical limit. The utility of coherent states as a basis for the description of the evolution of the density matrix is emphasized. In this basis it is easy to identify the classical Liouville equation in action-angle variables along with quantum-mechanical "corrections." Mention is made of possible physical applications to superfluid systems.
The quantum mechanical description of the azimuthal rotation angle and the orbital angular momentum around the polar axis differs greatly from the description of position and momentum. This has led to a controversy over the existence of a self-adjoint angle operator in the literature. It is possible to circumvent the problems of defining a self-adjoint operator for a periodic variable by using trigonometric functions of operators as a basis for the quantum mechanical description. This approach, however, does not allow us to study the properties of the angle operator itself. By using a state space of an arbitrarily large yet finite number of dimensions, it is possible to introduce angle and orbital angular momentum as a conjugate pair of variables both represented by Hermitian matrices. After physical and measurable quantities have been calculated in this state space the number of dimensions is allowed to tend to infinity in a limiting procedure. The first part of this chapter reviews the difficulties associated with the quantum mechanical formulation of angle and orbital angular momentum and presents a way to overcome these problems using a finite-dimensional state space. In the second part this formulation is generalised to include the phenomenon of non-integer orbital angular momentum. This part is based on a chapter of the PhD thesis of Götte [1], where further details may be found. Introduction The correct description of a periodic variable such as a rotation angle or the optical phase has been a long standing problem in quantum mechanics. At the root of the problem is the question of whether the variable itself is restricted in a 2 π radian range or whether it evolves continuously without bound.
Requirements of a conjugate operator are emphasized, especially in its role in uncertainty relations.It is argued that in many contexts it is necessary to extend the Hilbert space in order to define a conjugate operator as in gauge theories. Example of a particle in a box is analysed. This is closely related to the quantum oscillator through cosine states of Susskind and Glogower.It is used to justify London's phase wave functions albeit as part of a larger Hilbert space. A new definition phase uncertainty neccessiated by periodicity is proposed.It is close to the usual r.m.s. definition.Corresponding number- phase uncertainty relation is obtained and its implications are discussed. Hilbert space of an oscillator is identified with the Hilbert space of a planar rotor with a Z2Z_2Z2​ gauge invariance.This is used to construct states analogous to the cosine and sine states and to illustrate unitary equivalence of Hilbert spaces.
A general approach to the description of an angle and phase is given on the basis of the kq\mathrm{kq}kq representation. It is shown that an angular coordinate in quantum mechanics has to be treated as a quasicoordinate in order to avoid inconsistencies. The kq\mathrm{kq}kq representation leads to a consistent definition of the angular-momentum-angle degree of freedom. Using the correspondence between classical and quantum mechanics for the phase of a harmonic oscillator, operators are defined that form a new quantum-mechanical representation. This representation clarifies the concept of the phase and sheds light on the general understanding of rotations in quantum mechanics.
We review some of the difficulties previously encountered in defining the phase operator for finite quantum systems. We then propose the Wigner–Weyl quantization of the angle function φ on phase space as the phase operator, and derive a closed expression for its matrix elements with respect to the Hermite functions. We also determine the quantization of e^{iφ} , which turns out to be a weighted shift operator, its spectrum and that of its adjoint. This is done in the framework of quantization of a certain symbol class of phase space distributions, specialized to those which depend on one variable only. After recalling some results for the position and momentum variables, we apply the scheme to functions of radius or angle. We give necessary and sufficient conditions for operators obtained by quantizing functions of the angle to be elements of \mathscr L^+ [\mathscr S(\mathbf R)] and \mathscr L^+ [\mathscr S (\mathbf R), L^2(\mathbf R)] , and a sufficient condition for boundedness. We then consider the associated questions of commutation relations and uncertainties for operators in \mathscr L^+ [\mathscr S(\mathbf R), L^2(\mathbf R)] , which we define as bilinear forms. As must be the case, the commutator between our phase operator and the number operator exhibits noncanonical terms. Not surprisingly, the Poisson bracket of their phase space symbols also exhibits a noncanonical term.
Calculates expectation values and uncertainties of the radial coordinate and momentum, and the azimuthal angle and angular momentum components for a three-dimensional harmonic oscillator in a coherent state. The operators corresponding to powers of the angular variable are defined by their Fourier expansions. For large distances of the particle from the origin, where the oscillator becomes classical, radial and angular uncertainty products approach the value h(cross)/ square root 2, except for the point of discontinuity, where the angular uncertainty becomes infinite. For small distances, where the oscillator tends to its quantum ground state, the radial uncertainty stays finite and the angular uncertainty product tends to zero. It is also shown that the concept of a polar momentum operator is meaningless.
A comprehensive study is presented on the Weyl-Wigner formalism for rotation-angle and angular-momentum variables: the elements of kinematics are extended, the elements of dynamics are established, and the implications of rotational perodicity and angular-momentum quantization are investigated. Particular attention is paid to discreteness, and two of its consequences are emphasized: the importance of evenness and oddness, and the need to use two difference operators in a discrete domain, whereas one differential operator suffices in a continuous domain. These consequences are shown to strongly distinguish the Weyl-Wigner formalism for rotation-angle and angular-momentum variables from the well-known Weyl-Wigner formalism for Cartesian-position and linear-momentum variables. The point is made clear that the first of these formalisms cannot be regarded as a trivial and straightforward extension of the second. The rotational Wigner function is derived as the only bilinear form of the state vector that is real, has the natural invariances for rotational motion, and yields the correct distributions for the rotation-angle and angular-momentum variables as well as the appropriate expression for the transition probability between states. The conditions for its uniqueness are thus established. Its properties are described in detail and, in particular, its uniform boundedness is demonstrated. The rotational Wigner function and the associated correspondence between quantum operators and classical-like functions, as well as the relations they obey, are explored and are written so as to clearly exhibit the distinct contributions of evenness and oddness in the discrete domain of the angular-momentum eigenvalues, thus providing a most natural way to account for periodicity.Using the derivative, which acts on the continuous rotation-angle variable, and the forward and backward differences, which act on the discrete angular-momentum variable, the equation of motion for the rotational Wigner function is established. This equation is detailed for the following Hamiltonian forms: those that depend only on the angular-momentum variable, including, in particular, the free rotator, and those that are in the cosine of the rotation-angle variable. It is verified that the Weyl-Wigner formalism for rotation-angle and angular-momentum variables has the correct nonperiodic limit and that it properly reduces to the Weyl-Wigner formalism for Cartesian-position and linear-momentum variables. In order to illustrate the formalism, a careful analysis is carried out for the rotational Wigner function representing the energy eigenstates of a hindered rotator whose Hamiltonian is the sum of a term in the absolute value of the angular-momentum variable with a term in the cosine of the rotation-angle variable. For this hindered rotator, and within the approximation of a large absolute value of the angular-momentum variable, the equation of motion for the rotational Wigner function is solved for its stationary solutions, and the time-independent Schr\"odinger equation is also solved.