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Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Probability current in presence of Spin-Orbit Interaction

Federico Bottegoni, H.-J. Drouhin, G. Fishman, Jean-Eric Wegrowe

Published Aug 21, 2011• 0 citations
Publisher

Abstract

We propose a procedure, based on momentum power series expansion Hamiltonian of nth general order, to obtain a coherent expression of the probability current operator that is valid also when Spin-Orbit Interaction (SOI) terms are included. We prove that we recover the standard definition when the free electron-like term is included in the Hamiltonian, but when taking into account higher order Spin-Orbit Interaction (SOI) terms, a more general definition of the probability current operator is mandatory, due to its different symmetrization, compared to the Hermitian velocity operator expression.

DOI
10.1117/12.893592

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We propose a procedure, based on momentum power series expansion Hamiltonian of nth general order, to obtain a coherent expression of the probability current operator that is valid also when Spin-Orbit Interaction (SOI) terms are included. We prove that we recover the standard definition when the free electron-like term is included in the Hamiltonian, but when taking into account higher order Spin-Orbit Interaction (SOI) terms, a more general definition of the probability current operator is mandatory, due to its different symmetrization, compared to the Hermitian velocity operator expression.
This paper analyzes how the existence of electron spin changes the equation for the probability current density in the quantum-mechanical continuity equation. A spinful electron moving in a potential energy field experiences the spin-orbit interaction, and that additional term in the time-dependent Schrödinger equation places an additional spin-dependent term in the probability current density. Further, making an analogy with classical magnetostatics hints that there may be an additional magnetization current contribution. This contribution seems not to be derivable from a non-relativistic time-dependent Schrödinger equation, but there is a procedure described in the quantum mechanics textbook by Landau and Lifschitz to obtain it. We utilize and extend their procedure to obtain this magnetization term, which also gives a second derivation of the spin-orbit term. We conclude with an evaluation of these terms for the ground state of the hydrogen atom with spin-orbit interaction. The magnetization contribution is generally the larger one, except very near an atomic nucleus.
In this work, we start from the problem of quantizing the relativistic Hamiltonian of a free massive particle (rest mass different from 0), a problem exceptionally difficult in the standard approaches to quantum mechanics. In fact, in tempered distribution state space, we find the natural way to define the relativistic Hamiltonian operator and its associated Schrödinger equation The existence of a linear continuous Hermitian operator associated with the Einstein's Hamiltonian of a free particle, defined on the entire tempered distribution space, automatically implies the conservation of Born probability flux (which doesn't mean the conservation of particles number, rather it implies the conservation of the total relativistic energy of the solution wave). We, then, deduce the continuity equation for the Born probability density and study some its different (but equivalent) expressions. We determine some possible forms of probability currents and flux velocity fields associated with the particle evolution. We provide the relativistic invariant expression for both Schrödinger equation and probability flux continuity equations.
The problem of the position and spin in relativistic quantum mechanics is analyzed in detail. It is definitively shown that the position and spin operators in the Foldy-Wouthuysen representation (but not in the Dirac one) are quantum-mechanical counterparts of the classical position and spin variables. The probabilistic interpretation is valid only for Foldy-Wouthuysen wave functions. The relativistic spin operators are discussed. The spin-orbit interaction does not exist for a free particle if the conventional operators of the orbital angular momentum and the rest-frame spin are used. Alternative definitions of the orbital angular momentum and the spin are based on noncommutative geometry, do not satisfy standard commutation relations, and can allow the spin-orbit interaction.
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We revisit the definition of the probability current for the Schrodinger equation. First, we prove that the Dirac probability currents of stationary wave functions of the hydrogen atom and of the isotrop harmonic oscillator are not nil and correspond to a circular rotation of the probability. Then, we recall how it is necessary to add to classical Pauli and Schrodinger currents, an additional spin-dependant current, the Gordan current. Consequently, we get a circular probability current in the Schrodinger approximation for the hydrogen atom and the isotrop harmonic oscillator.