Abstract We compare and contrast classical and quantum dynamics of a free particle initially prepared in an s‐wave. Due to the wave nature of quantum theory the particle experiences an acceleration which depends on the number of space dimensions.
Abstract This chapter continues with a study of the time independent Schrödinger equation and seeks to contrast the quantum behavior of a free particle with that of a particle localized in a potential quantum well. A free particle can exist over all space or can be localized in a wave package. The wave packet is a coherent superposition of the plane waves that make up the wave function that localizes the particle because of constructive and destructive interference. The wave packet spreads out in time because the waves leading to constructive interference get out of phase. In Chapter 2, the particle was localized by a quadratic potential energy. Here, the potentials are described as piecewise constant. The approach is based on assuming a one-dimensional space, x, which is relevant to many problems in the laboratory. The solution is easily generalized to higher dimensions (x-y or x-y-z), but the physics remains the same. The objective is to understand the shape of the eigenfunctions in space and to be able to relate this to the probability density of locating the particle, as well as understanding the relevance of these systems to today’s technology.
We use a Markovian master equation to solve for the dynamics of a free particle damped by the coupling of its coordinate to a bath of harmonic oscillators. In the coordinate basis the reduced density matrix for the free particle tends to be diagonalized. Considering the evolution of an initial superposition of two plane waves, we find that the interference-pattern fringe contrast is decreased by the damping. However, for fixed times and sufficiently large damping, the fringe contrast increases with increasing damping. Considering an initial coordinate-space Gaussian wave function, we find that for sufficiently large damping the coupling to the environment models a quantum measurement of the particle's coordinate.
In this Brief Report we discuss a solution of the free-particle Schr\"odinger equation in which the time and space dependence are not separable. The wave function is written as a product of exponential terms, Hermite polynomials, and a phase. The peaks in the wave function decelerate and then accelerate around t=0. We analyze this behavior within both a quantum and a semiclassical regime. We show that the acceleration does not represent true acceleration of the particle but can be related to the envelope function of the allowed classical paths. Comparison with other ``accelerating'' wave functions is also made. The analysis provides considerable insight into the meaning of the quantum wave function.