Abstract This chapter continues with a study of the time independent Schrödinger equation and seeks to contrast the quantum behavior of a free particle with that of a particle localized in a potential quantum well. A free particle can exist over all space or can be localized in a wave package. The wave packet is a coherent superposition of the plane waves that make up the wave function that localizes the particle because of constructive and destructive interference. The wave packet spreads out in time because the waves leading to constructive interference get out of phase. In Chapter 2, the particle was localized by a quadratic potential energy. Here, the potentials are described as piecewise constant. The approach is based on assuming a one-dimensional space, x, which is relevant to many problems in the laboratory. The solution is easily generalized to higher dimensions (x-y or x-y-z), but the physics remains the same. The objective is to understand the shape of the eigenfunctions in space and to be able to relate this to the probability density of locating the particle, as well as understanding the relevance of these systems to today’s technology.
Abstract This chapter continues with a study of the time independent Schrödinger equation and seeks to contrast the quantum behavior of a free particle with that of a particle localized in a potential quantum well. A free particle can exist over all space or can be localized in a wave package. The wave packet is a coherent superposition of the plane waves that make up the wave function that localizes the particle because of constructive and destructive interference. The wave packet spreads out in time because the waves leading to constructive interference get out of phase. In Chapter 2, the particle was localized by a quadratic potential energy. Here, the potentials are described as piecewise constant. The approach is based on assuming a one-dimensional space, x, which is relevant to many problems in the laboratory. The solution is easily generalized to higher dimensions (x-y or x-y-z), but the physics remains the same. The objective is to understand the shape of the eigenfunctions in space and to be able to relate this to the probability density of locating the particle, as well as understanding the relevance of these systems to today’s technology.
The Schrödinger equation assumes that a particle behaves as a wave and yields a solution in terms of wave function and the energy of the particle under consideration. Once the wave function is known, then everything about the particle can be deduced from the wave function. This chapter covers the development of the Schrödinger wave equation and its applications to one-dimensional systems. Time-dependent and time-independent Schrödinger equations, bound and scattering states, probability density, probability current and expectation values, the solution of the time-independent 1D-Schrödinger equation for a free particle, infinite as well as finite potential wells, potential steps, and the finite potential barrier are discussed in detail in the chapter. The phenomenon of tunneling, relevance and the importance of the free particle, potential wells and potential barriers to contemporary fields of physics and chemistry, periodic solids and their band structures, the Kronig-Penney model, confined states in quantum wells, and wires and dots are other topics presented in innovative manners in the chapter. The importance of the topics presented here is demonstrated through carefully chosen solved examples and unsolved exercises from contemporary fields of sciences.
The postulates of quantum mechanics associate the time-evolution of a system with its time-dependent Schrödinger equation. We start by examining different solutions to this equation for a particle, represented in terms of a Gaussian wave packet, in different scenarios: free, scattered from a potential energy barrier, or trapped in a potential energy well. In some cases, we encounter stationary solutions, in which the probability density does not change in time (a standing wave). These solutions are identified as eigenfunctions of a system Hamiltonian. The properties of the Hamiltonian as a Hermitian operator are introduced, and particularly, the fact that its proper eigenfunctions can compose an orthonormal set, and that the corresponding eigenvalues are real-valued. Learning that all operators that relate to measurables are Hermitian, and that their eigenvalues relate to the measured values, we conclude that the eigenvalues of the energy operator (Hamiltonian) are the energy levels of the quantum system.
This chapter discusses several applications of the formalism of theory of quantum mechanics. The time-independent Schrodinger equation is applied to understand simple quantum systems such as a free particle, a particle in an infinite square well, step potentials, potential barrier and finite square well. The chapter deals with the simplest case, a free particle. It is the most elementary application of the formalism. A free particle means that no forces are acting on the particle, and hence, there is no interaction between the particle and its environment. According to classical mechanics, a free particle moves with a constant velocity along a straight line. The energy of the wave associated with the free quantum particle is same as that of the classical free particle. The chapter describes a quantum free particle as a wave packet traveling in space and time. It discusses a quantum particle under the influence of a force.
The quantum mechanics is most easily started from the experimentally observed discrete energy states of bound particles. The free particle may take on any energy whatever, which makes the quantum description of a free particle more awkward conceptually and mathematically than the quantum description of a bound particle. The construction of moving quantum spatial probabilities will require a superposition of stationary state wave functions of different energies. Any coherent superposition of energy eigen states for a particle represents a possible quantum state of that particle. The most important property of the spatial probability function for superposed energy states is that it changes with time. A moving probability that is limited spatially is called a packet and the corresponding quantum-mechanical description is called a packet state. The free-particle packet states examples satisfy the position-momentum uncertainty relation. Probably the most important application of the energy time uncertainty relation concerns the lifetimes of the excited states of atoms and nuclei.
We discuss nonspreading wave packets in one dimensional Schrödinger equation. We derive general rules for constructing nonspreading wave packets from a general potential V(x,t). The essential ingredients of a nonspreading wave packet, the shape function f(x), the motion d(t), the phase function ϕ(x,t) are derived. Since the form of the shape of a nonspreading wave packet does not change in time, the shape equation should be time independent. We show that the shape function f(x) is the eigenfunction of the time independent Schrödinger equation with an effective potential Veff and an energy Eeff. We derive nonspreading wave packets found by Schrödinger, Senitzky, and Berry and Balazs as examples. We show that most stationary potentials can only support stationary nonspreading wave packets. We show how to construct moving nonspreading wave packets from time dependent potentials, which drive nonspreading wave packets into an arbitrary motion.
We show that one can obtain analytic solutions of the time-dependent Schrödinger equation that are more complex than the well-known oscillating coherent wave packet. Such Hermite-Gaussian or initially square wave packets exist for a free particle or for one subject to the harmonic oscillator potential. In either case, the Hermite-Gaussian packets retain their nodal structure even after long times. There is a single class of exact solutions for the system with oscillator constant K > 0, K = 0, or K < 0, leading to wave functions for the harmonic oscillator, the free particle, and the inverted oscillator, respectively.