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Journal of the Physical Society of Japan

Transport in Gapped Quantum Antiferromagnets

Tôru Sakai, Shoji Yamamoto

Published Jan 1, 2005• 2 citations
Publisher

Abstract

The transport properties of quantum systems are one of the most interesting current topics in statistical physics. Heat transport can directly be observed through thermal conductivity measurements, while spin transport can be extracted from nuclear spin–lattice relaxation-time measurements. Numerous experiments have indeed been performed in an attempt to settle the argument about whether finite-temperature energy transport should be diffusive or ballistic. From the theoretical point of view, there is an argument that integrable Hamiltonians exhibit ballistic transport, whereas nonintegrable ones are diffusive or insulators. Since nonintegrable systems have much less been studied in this context so far, we investigate spin-½ ferromagnetic-antiferromagnetic bond-alternating chains, which exhibit common features of Haldane-gap antiferromagnets. Employing the Jordan–Wigner spinless-fermion representation, their level statistics is investigated by the exact-diagonalization method. We argue a possibility of the diffusive transport occurring in the system.

DOI
10.1143/jpsjs.74s.191

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The transport properties of quantum systems are one of the most interesting current topics in statistical physics. Heat transport can directly be observed through thermal conductivity measurements, while spin transport can be extracted from nuclear spin–lattice relaxation-time measurements. Numerous experiments have indeed been performed in an attempt to settle the argument about whether finite-temperature energy transport should be diffusive or ballistic. From the theoretical point of view, there is an argument that integrable Hamiltonians exhibit ballistic transport, whereas nonintegrable ones are diffusive or insulators. Since nonintegrable systems have much less been studied in this context so far, we investigate spin-½ ferromagnetic-antiferromagnetic bond-alternating chains, which exhibit common features of Haldane-gap antiferromagnets. Employing the Jordan–Wigner spinless-fermion representation, their level statistics is investigated by the exact-diagonalization method. We argue a possibility of the diffusive transport occurring in the system.
In terms of spinless fermions and spin waves, we describe magnetic properties of a spin-1/2 ferromagnetic– antiferromagnetic bond-alternating chain which behaves as a Haldane-gap antiferromagnet. On one hand, we employ the Jordan–Wigner transformation and treat the fermionic Hamiltonian within the Hartree–Fock approximation. On the other hand, we employ the Holstein– Primakoff transformation and modify the conventional spin-wave theory so as to restore the sublattice symmetry. We calculate the excitation gap, the specific heat, the magnetic susceptibility, magnetization curves, and the nuclear spin-lattice relaxation rate with varying bond alternation. These schemes are further applied to a bond-alternating tetramerized chain which behaves as a ferrimagnet. The fermionic language is particularly stressed as a useful tool to investigate one-dimensional spin-gapped antiferromagnets, while the bosonic one works better for ferrimagnets.
In terms of spinless fermions and spin waves, we describe the magnetic properties of a spin-1/2 ferromagnetic-antiferromagnetic bond-alternating chain which behaves as a Haldane-gap antiferromagnet. On the one hand, we employ the Jordan–Wigner transformation and treat the fermionic Hamiltonian within the Hartree–Fock approximation. On the other hand, we employ the Holstein–Primakoff transformation and modify the conventional spin-wave theory so as to restore the sublattice symmetry. We calculate the excitation gap, the specific heat, the magnetic susceptibility, magnetization curves, and the nuclear spin-lattice relaxation rate with varying bond alternation. These schemes are further applied to a bond-alternating tetramerized chain which behaves as a ferrimagnet. The fermionic language is particularly stressed as a useful tool for investigating one-dimensional spin-gapped antiferromagnets, while the bosonic one works better for ferrimagnets.
We study both the static and dynamic properties of gapped, one-dimensional, Heisenberg, antiferromagnetic, spin chains at finite temperature through an analysis of the O(3) nonlinear sigma model. Exploiting the integrability of this theory, we are able to compute an exact low-temperature expansion of the finite temperature correlators. We do so using a truncated ``form-factor'' expansion and so provide evidence that this technique can be successfully extended to finite temperature. As a direct test, we compute the static zero-field susceptibility and obtain an exact match to the susceptibility derived from the low-temperature expansion of the exact free energy. We also study transport properties, computing both the spin conductance and the NMR-relaxation rate, 1/T1.{1/T}_{1}.1/T1​. We find these quantities to show ballistic behavior. In particular, the computed spin conductance exhibits a nonzero Drude weight at finite temperature and zero applied field. The physics thus described differs from the spin diffusion reported by Takigawa et al. [Phys. Rev. Lett. 76, 2173 (1996)] from experiments on the Haldane gap material, AgVP2S6.{\mathrm{AgVP}}_{2}{S}_{6}.AgVP2​S6​.
It is well established that at zero magnetic field h=0h=0h=0, the spin diffusion constant of the spin-12\frac{1}{2}21​ XXZ chain is for anisotropy $\mathrm{\ensuremath{\Delta}}>1$ finite for both low and high temperatures, implying that the type of spin transport is normal diffusive. Although it is expected that this holds for all finite temperatures T>0T>0T>0, the calculation of the spin diffusion constant for all TTT is typically intractable. Here we consider a class of energy eigenstates that exist both for anisotropies $\mathrm{\ensuremath{\Delta}}=1$ and $\mathrm{\ensuremath{\Delta}}>1$. We show that at the isotropic point their contributions are behind the diffusion constant being infinite, spin transport being anomalous superdiffusive for T>0T>0T>0. That for $\mathrm{\ensuremath{\Delta}}>1$ such states do not contribute to the diffusion constant is shown to imply it is finite, spin transport being normal diffusive for T>0T>0T>0. By combining the connection through a Jordan-Wigner transformation of the spin-12\frac{1}{2}21​ XXZ chain to the one-dimensional (1D) lattice spinless fermion model at zero chemical potential $\ensuremath{\mu}=0$, for $V/J\ensuremath{\ge}1$ with its Bethe-ansatz solution, where VVV is the nearest-neighbor Coulomb repulsion and J=2tJ=2tJ=2t is twice the hopping integral ttt, in this paper we also address the issue of the T>0T>0T>0 charge transport of that model at $\ensuremath{\mu}=0$. It is found to be anomalous superdiffusive for V/J=1V/J=1V/J=1 and normal diffusive for V/J>1V/J>1V/J>1. Our results thus open the door to a key advance in the understanding for all finite temperatures T>0T>0T>0 of the spin transport in the spin-12\frac{1}{2}21​ XXZ chain at h=0h=0h=0 for anisotropy $\mathrm{\ensuremath{\Delta}}\ensuremath{\ge}1$ and of the charge transport in the 1D lattice spinless fermion model at $\ensuremath{\mu}=0$ for $V/J\ensuremath{\ge}1$.
This thesis studies transport properties of low-dimensional quantum spin systems with a particular focus on the transport of heat and spin. While the integrable anisotropic spin-1/2 chain exhibits ballistic transport (finite Drude weights), the numerical results of this work show that heat and spin transport of non-integrable models (spin ladder, frustrated and dimerized chain) is not ballistic, characterized by vanishing Drude weights in the thermodynamic limit. The results for the thermal conductivity of spin ladders are compared to experimental data. For the case of the spin-1/2 Heisenberg chain, this work contains detailed results for the temperature and magnetic field dependence of the Drude weights. Finally, bond-disordered spin systems are considered, namely the spin-1/2 chain and the spin ladder. In the first case, the transport coefficients are computed by means of exact diagonalization and discussed as a function of frequency, temperature, and magnetic field. In the second case, spectral properties of the elementary excitation of disordered spin ladders are analyzed using diagrammatic perturbation theory and numerical techniques.
Spin transport properties of the quantum one-dimensional non-linear sigma model are studied based upon the Bethe ansatz exact solution for the O(3) sigma model and the 1/N-expansion approach for the O(N) sigma model. It is shown that the spin transport at finite temperatures is ballistic and there is no spin diffusion in this system. A possible mechanism for the spin diffusion observed in the NMR experiment of the Haldane gap system AgVP_2S_6 by Takigawa et al. [Phys. Rev. Lett.{\bf 76}, 2173 (1996)] is also discussed. The inclusion of the spin-phonon interaction accounts for the experimental results qualitatively.