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International Journal of Modern Physics B

SUPERCONDUCTOR-INSULATOR TRANSITIONS

Allen M. Goldman

Published Aug 30, 2010• 137 citations
Publisher

Abstract

Superconductor-insulator transitions, especially in thin films, can provide the simplest examples of the continuous quantum phase transition paradigm. Quantum phase transitions differ from thermal phase transitions in that they occur at zero temperature when the ground state of a system is changed in response to a variation of an external parameter of the Hamiltonian. In the example of the superconductor-insulator transition, this control parameter could be the parallel or perpendicular magnetic field, disorder, or charge density. Quantum phase transitions are studied through measurements at nonzero temperature of physical behaviors influenced by the quantum fluctuations associated with the transition. This review will focus on experimental aspects of superconductor-insulator transition in disordered films that are effectively two-dimensional. In particular, the evidence for quantum critical behavior in the various types of transitions will be presented. The various theoretical scenarios for the transitions will also be discussed along with the extent to which they are supported by experiment. Open questions relating to the nature of the very puzzling insulating regime and whether there are many different types of superconductor-insulator transitions will be presented. Although this research area is more than 20 years old, rather central issues are not resolved.

DOI
10.1142/s0217979210056451

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Superconductor-insulator transitions, especially in thin films, can provide the simplest examples of the continuous quantum phase transition paradigm. Quantum phase transitions differ from thermal phase transitions in that they occur at zero temperature when the ground state of a system is changed in response to a variation of an external parameter of the Hamiltonian. In the example of the superconductor-insulator transition, this control parameter could be the parallel or perpendicular magnetic field, disorder, or charge density. Quantum phase transitions are studied through measurements at nonzero temperature of physical behaviors influenced by the quantum fluctuations associated with the transition. This review will focus on experimental aspects of superconductor-insulator transition in disordered films that are effectively two-dimensional. In particular, the evidence for quantum critical behavior in the various types of transitions will be presented. The various theoretical scenarios for the transitions will also be discussed along with the extent to which they are supported by experiment. Open questions relating to the nature of the very puzzling insulating regime and whether there are many different types of superconductor-insulator transitions will be presented. Although this research area is more than 20 years old, rather central issues are not resolved.
In recent years, quantum phase transitions have attracted the interest of both theorists and experimentalists in condensed matter physics. These transitions, which are accessed at zero temperature by variation of a non-thermal control parameter, can influence the behaviour of electronic systems over a wide range of the phase diagram. Quantum phase transitions occur as a result of competing ground state phases. The cuprate superconductors which can be tuned from a Mott insulating to a d -wave superconducting phase by carrier doping are a paradigmatic example. This review introduces important concepts of phase transitions and discusses the interplay of quantum and classical fluctuations near criticality. The main part of the article is devoted to bulk quantum phase transitions in condensed matter systems. Several classes of transitions will be briefly reviewed, pointing out, e.g., conceptual differences between ordering transitions in metallic and insulating systems. An interesting separate class of transitions is boundary phase transitions where only degrees of freedom of a subsystem become critical; this will be illustrated in a few examples. The article is aimed at bridging the gap between high-level theoretical presentations and research papers specialized in certain classes of materials. It will give an overview on a variety of different quantum transitions, critically discuss open theoretical questions, and frequently make contact with recent experiments in condensed matter physics.
In the previous chapter, we discussed both the insulator–superconductor and the insulator–metal transitions. As such transitions are disorder or magnetic-field tuned, thermal fluctuations play no role. Phase transitions of the insulator–superconductor or insulator–metal type are called quantum phase transitions. Such phase transitions are not controlled by changing the temperature, as in the melting of ice or the λ-point of liquid helium, but rather by changing some system parameter, such as the number of defects or the concentration of charge carriers. In all such instances, the tuning parameter transforms the system between quantum mechanical states that either look different topologically (as in the transition between localized and extended electronic states) or have distinctly different magnetic properties. As quantum mechanics underlies such phase transitions, all quantum phase transitions obtain at the absolute zero of temperature and thus are governed by a T = 0 quantum critical point. While initially surprising, this state of affairs is expected, because quantum mechanics is explicitly a zero-temperature theory of matter. Of course, this is of no surprise to chemists who have known for quite some time that numerous materials can exhibit vastly distinct properties simply by changing the chemical composition and, most importantly, that such transformations persist down to zero temperature. Common examples include turning insulators such as the layered cuprates into superconductors simply by chemical doping or semiconductors into metals once again by doping, or ferromagnets such as Li(Ho, Tb) x Y 1- x F 4 into a spin glass (AR1998) by altering x .
In this article we study superconductor-insulator transitions within the general framework of an attractive Hubbard model. This is a well-defined model of s-wave superconductivity which permits different tuning parameters (disorder and field). Furthermore, it allows a comparison of various analytical and computational approaches in order to gain a complete understanding of the various effects of amplitude and phase fluctuations. We present a systematic pedagogical approach, aiming to equip the lay reader with enough apparatus to be able to understand the numerical calculations, reproduce some of the simpler results, and be able to tackle future problems related to inhomogeneous phases. We go into considerable detail on mean-field theory (MFT) and the Bogoliubov-de Gennes (BdG) approach, as these are a first line of attack which can capture much of the physics, but we also outline cases where this fails to capture phase fluctuations and more sophisticated Quantum Monte Carlo (QMC) calculations are necessary. We discuss the behavior of many observables, including densities of states, superfluid stiffness, and dynamical conductivity, for the disorder-tuned superconductor-insulator transition. We also discuss SITs tuned by parallel magnetic field, which are quite different due to pairbreaking.
We develop an analytical theory for generic disorder-driven quantum phase transitions. We apply this formalism to the superconductor-insulator transition and we briefly discuss the applications to the order-disorder transition in quantum magnets. The effective spin-12\frac{1}{2}21​ models for these transitions are solved in the cavity approximation which becomes exact on a Bethe lattice with large branching number K⪢1K⪢1K⪢1 and weak dimensionless coupling g⪡1g⪡1g⪡1. The characteristic feature of the low-temperature phase is a large self-formed inhomogeneity of the order-parameter distribution near the critical point $K\ensuremath{\ge}{K}_{c}(g)$, where the critical temperature Tc{T}_{c}Tc​ of the ordering transition vanishes. We find that the local probability distribution P(B)P(B)P(B) of the order parameter BBB has a long power-law tail in the region where BBB is much larger than its typical value B0{B}_{0}B0​. Near the quantum-critical point, at $K\ensuremath{\rightarrow}{K}_{c}(g)$, the typical value of the order parameter vanishes exponentially, ${B}_{0}\ensuremath{\propto}{e}^{\ensuremath{-}C/[K\ensuremath{-}{K}_{c}(g)]}$ while the spatial scale Ninh{N}_{inh}Ninh​ of the order parameter inhomogeneities diverges as ${[K\ensuremath{-}{K}_{c}(g)]}^{\ensuremath{-}2}$. In the disordered regime, realized at K<Kc(g)K<{K}_{c}(g)K<Kc​(g) we find actually two distinct phases characterized by different behavior of relaxation rates. The first phase exists in an intermediate range of ${K}^{\ensuremath{\ast}}(g)<K<{K}_{c}(g)$. It has two regimes of energies: at low excitation energies, $\ensuremath{\omega}<{\ensuremath{\omega}}_{d}(K,g)$, the many-body spectrum of the model is discrete, with zero-level widths, while at $\ensuremath{\omega}>{\ensuremath{\omega}}_{d}$ the level acquire a nonzero width which is self-generated by the many-body interactions. In this phase the spin model provides by itself an intrinsic thermal bath. Another phase is obtained at smaller $K<{K}^{\ensuremath{\ast}}(g)$, where all the eigenstates are discrete, corresponding to full many-body localization. These results provide an explanation for the activated behavior of the resistivity in amorphous materials on the insulating side near the superconductor-insulator transition and a semiquantitative description of the scanning tunneling data on its superconductive side.
The past decade has seen a substantial rejuvenation of interest in the study of quantum phase transitions, driven by experiments on cuprate superconductors, heavy fermion materials, organic conductors, and related compounds. Although quantum phase transitions in simple spin systems, like the Ising model in a transverse field, were studied in the early 1970s, much of the subsequent theoretical work examined a particular example: the metal–insulator transition. While this is a subject of considerable experimental importance, the greatest theoretical progress was made for the case of the Anderson transition of non-interacting electrons, which is driven by localization of the electronic states in the presence of a random potential. The critical properties of this transition of noninteracting electrons constituted the primary basis upon which most condensed matter physicists have formed their intuition on the behavior of the systems near a quantum phase transition. However, it is clear that strong electronic interactions play a crucial role in the systems of current interest noted earlier, and simple paradigms for the behavior of such systems near quantum critical points are not widely known. It is the purpose of this book to move interactions to center stage by describing and classifying the physical properties of the simplest interacting systems undergoing a quantum phase transition. The effects of disorder will be neglected for the most part but will be considered in the concluding chapters. Our focus will be on the dynamical properties of such systems at nonzero temperature, and it will become apparent that these differ substantially from the noninteracting case.
We discuss some problems related to quantum critical phenomena in superfluids and superconductors. In Ch. 1, we apply generalizations of hyperuniversality to quantum phase transitions at zero temperature. We find new universal amplitude combinations involving the superfluid density in Bose systems, as well as confirm and extend previous proposals for universal transport coefficients in two-dimensional superconducting films and magnetic-field-induced metal-insulator transitions. In Ch. 2, we apply the double-dimensionality expansion of Dorogovstev to derive renormalization-group recursion relations for a Bose fluid in a random external potential. We find a nontrivial fixed point. The onset of mean-field behavior for dimensions d > d[subscript]c = 4 is unconventional, yielding discontinuous exponents. Including positive temperatures, we give a clear picture of various crossover regimes. In Ch. 3, We give a detailed derivation of the critical thermodynamics of O(n) spin models, correct to O([epsilon] = 4 - d), using a generalization of the renormalization-group trajectory integral and noncritical matching technique introduced by Rudnick and Nelson. We especially emphasize the coexistence-curve behavior for spins with a continuous symmetry (n [...] 2), deriving detailed expressions for the renormalized spin-wave stiffness and longitudinal susceptibility.