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Progress in physics

Comments on the Statistical Nature and on the Irreversibility of the Wave Function Collapse

Armando V.D.B. Assis

Published Jun 1, 2011• 0 citations
OpenAlex

Abstract

In a previous preprint, [1], reproduced here within the appendix in its revised version, we were confronted, to reach the validity of the second law of thermodynamics for an unique collapse of an unique quantum object, to the necessity of an ensemble of measures to be accomplished within copies of identical isolated systems. The validity of the second law of thermodynamics within the context of the wave function collapse was sustained by the large number of microstates related to a given collapsed state. Now, we will consider just one pure initial state containing just one initial state of the quantum subsystem, not an ensemble of identically prepared initial quantum subsystems, e.g., just one photon from a very low intensity beam prepared with an equiprobable eigenset containing two elements, an unique observation raising two likelihood outcomes. Again, we will show the statistical interpretation must prevail, albeit the quantum subsystem being a singular, unique, pure state element within its unitary quantum subsystem ensemble set. This feature leads to an inherent probabilistic character, even for a pure one-element quantum subsystem object.

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In a previous preprint, [1], reproduced here within the appendix in its revised version, we were confronted, to reach the validity of the second law of thermodynamics for an unique collapse of an unique quantum object, to the necessity of an ensemble of measures to be accomplished within copies of identical isolated systems. The validity of the second law of thermodynamics within the context of the wave function collapse was sustained by the large number of microstates related to a given collapsed state. Now, we will consider just one pure initial state containing just one initial state of the quantum subsystem, not an ensemble of identically prepared initial quantum subsystems, e.g., just one photon from a very low intensity beam prepared with an equiprobable eigenset containing two elements, an unique observation raising two likelihood outcomes. Again, we will show the statistical interpretation must prevail, albeit the quantum subsystem being a singular, unique, pure state element within its unitary quantum subsystem ensemble set. This feature leads to an inherent probabilistic character, even for a pure one-element quantum subsystem object.
Academically, among students, an apparent paradox may arise when one tries to interpret the second law of thermodynamics within the context of the quantum mechanical wave function collapse. This is so because a quantum mechanical system suddenly seems to undergo, from a less restrictive state constructed from a superposition of eigenstates of a given operator, to a more restrictive state: the collapsed state. This paper is intended to show how this picture turns out to be a misconception and, albeit briefly, furtherly discuss the scope of Max Born’s probabilistic interpretation within the second law of thermodynamics.
Despite early developments on the foundations of quantum mechanics concern the wave function, quantum statistics has been developed with the density matrix formalism, leading to very important results in explaining molecular observations. Only recently, several authors argued a new interpretation by focusing on the wave function representing the quantum state of an isolated system, showing how a single wave function can exhibit statistical properties and generate the same results expected in the standard quantum statistical framework. Starting from these results, investigation on the foundations of quantum statistical mechanics has gained recently a renewed interest. As a matter of fact, the possibility of studying single molecule properties as well as the need of a better understanding of the effect of quantum dynamics, in order to develop new nanoscaled materials suitable to quantum computing tasks, have opened new intriguing questions leading to quantum statistical approaches far from being well understood and accepted. In this framework the behaviour of a single realization of quantum systems has gained a central role in the description of molecular systems. Furthermore, in recent years, an increasing number of studies has been presented on quantum dynamics through the numerical solution of the Schrödinger equation for systems of interacting components. These studies demonstrates that Quantum Dynamics Simulations could be a practicable route. In order to study phenomena such as dissipation, relaxation and thermalization, the focus has to be moved from isolated molecules to modular systems made of mutual interacting components, with model Hamiltonians possessing a sufficiently low dimensional representation. An important issue concerns the rules to be employed for the choice of the initial quantum state for the simulation of isolated systems. As long as one considers molecular degrees of freedom interacting with a (model) environment, there are no reasons to select a particular quantum state for the overall system and, therefore, a random choice has to be performed amongst a well defined statistical ensemble of pure states. Furthermore, one would like to operate a choice assuring that the simulation of the system is in a well defined thermal state with given temperature. This necessarily calls for a statistical description like for classical systems. A useful parametrization of the wave function will be presented in order to highlight the most appropriate variable for the statistical analysis. In particular some of them, called phases, retain all the dynamical information whereas the others, called populations, are the constants of motion. The latter, in particular are very important because they describe the equilibrium properties strictly related to the thermodynamic description. Since the dynamics of wave function does not supply any information about populations, the definition of a probability distribution on these variables is required. Different probability distributions on populations have been proposed, only on the bases of reasonable assumptions and they validation has been performed only with a posteriori considerations. In particular Fresch and Moro have demonstrated how the agreement with thermodynamics can be employed to discriminate different probability distributions on pure states. This had led the uniform ensembles to be, up to now, the most self-consistent models for quantum pure states. However, in this thesis I will highlight a drawback of the uniform distribution ensemble that can be described as follow: if we bring into contact two systems, even through a perturbative interaction, we are not able to describe the equilibrium properties after the interaction within the uniform distribution statistics, since the uniform character is lost. It represents a severe shortcoming of the statistical ensemble from a methodological point of view, since closed systems can be always considered as the result of interaction among previously isolated systems. On the other hand this drawback introduces a further requirement of a different nature that can be used for the definition of a new statistical ensemble. In this work I intend to find and characterize a statistical ensemble for populations that overcomes the drawbacks of the uniform distribution of pure states. The invariance of the thermal state in the coupling of identical systems will be used as a guideline in the definition af a new probability distribution on populations. Such an ensemble for pure states, called Thermalization Resilient Ensemble, provides a convenient framework for treating the interactions between quantum systems, as long as the structure of the statistical distribution is preserved and the identification of thermodynamic properties is assured. In perspective it should be the privileged statistical ensemble to implement Quantum Dynamics Simulations. Once the average properties of the Thermalization Resilient Ensemble have been introduced, I will obtain a probability distribution on pure states with the use of a geometrical analysis on the Hilbert space. The surface elements of an ellipsoidal manifold will be related to the probability density on populations. As a matter of fact the explicit form of the probability distribution is a prerequisite in order to perform Quantum Dynamical Simulations. However the results obtained through the geometrical analysis cannot be easily extended to systems with unbounded energy spectrum and an alternative strategy has been developed. A scaling algorithm on the basis of the uniform statistical ensemble will be described and this allows a well defined sampling of a probability distribution with desired averages. In this framework I demonstrate the emergence of thermodynamic behavior in the limit of macroscopic systems. In the last part of the thesis I consider the dynamical features of the thermalization experiment. Two identical systems, initially at different temperature, will be brought in interaction and the analysis of the final equilibrium state will be performed for two different generic forms of the interaction Hamiltonian, highlighting how the statistical approach can be very useful in the definition of the equilibrium in complex quantum systems.
Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum systems. In the present contribution a simple but effective theoretical framework is introduced to clarify the connections between a purely mechanical description and the thermodynamic characterization of the equilibrium state of an isolated quantum system. A salient feature of our approach is the very transparent distinction between the statistical aspects and the dynamical aspects in the description of isolated quantum systems. Like in the classical statistical mechanics, the equilibrium distribution of any property is identified on the basis of the time evolution of the considered system. As a consequence equilibrium properties of quantum system appear to depend on the details of the initial state due to the abundance of constants of the motion in the Schrodinger dynamics. On the other hand the study of the probability distributions of some functions, such as the entropy or the equilibrium state of a subsystem, in statistical ensembles of pure states reveals the crucial role of typicality as the bridge between macroscopic thermodynamics and microscopic quantum dynamics. We shall consider two particular ensembles: the random pure state ensemble and the fixed expectation energy ensemble. The relation between the introduced ensembles, the properties of a given isolated system, and the standard quantum statistical description are discussed throughout the presentation. Finally we point out the conditions which should be satisfied by an ensemble in order to get meaningful thermodynamical characterization of an isolated quantum system.
A persistent focus on the concept of emergence as a core element of the scientific method allows a clean separation, insofar as this is possible, of the physical and philosophical aspects of the problem of outcomes in quantum mechanics. The philosophical part of the problem is to explain why a closed system has definite experimental outcomes. The physical part is to show mathematically that there exists a limit in which the contradiction between unitary Schroedinger dynamics and a reduction process leading to distinct outcomes becomes negligible according to an explicitly stated criterion, and to make this criterion as objective as possible. The physical problem is solved here by redefining the notion of a quantum state and finding a suitable measure for the change of state upon reduction. The appropriate definition of the quantum state is not as a ray or density operator in Hilbert space, but rather as an equivalence class consisting of all density operators in a given subspace, the members of which all describe the same experimental outcome. For systems containing only subsystems that are integrated with their environments, these equivalence classes can be represented mathematically by projection operators, and the resulting formalism is closely related to that used by von Neumann to study the increase of entropy predicted by the second law of thermodynamics. However, nearly isolated subsystems are reduced only indirectly, as a consequence of their interaction with integrated subsystems. The reduced states of isolated subsystems are the same conditional states used in the definition of quantum discord. The key concepts of decoherence theory can all be adapted to fit this definition of a quantum state, resulting in a unified theory capable of resolving, in principle, all aspects of the quantum measurement problem. The theory thus obtained is weakly objective but not strongly objective.
The challenge of understanding quantum measurement persists as a fundamental issue in modern physics. Particularly, the abrupt and energy-nonconserving collapse of the wave function appears to contradict classical thermodynamic laws. The contradiction can be resolved by considering measurement itself to be an entropy-increasing process, driven by the second law of thermodynamics. One such resolution explains the apparently irreversible emergence of objective outcomes in an isolated, unitarily evolving quantum system via the theory of closed-system equilibration. Working within this framework, we construct the set of “” that best encode the measurement statistics of a system in an objective manner and establish a measurement error bound to quantify the probability an observer will obtain an incorrect measurement outcome. Using this error bound, we show that the objectifying observables readily equilibrate on average under the set of Hamiltonians which preserve the outcome statistics on the measured system. Using a random matrix model for this set, we numerically determine the measurement error bound, finding that the error only approaches zero with increasing environment size when the environment is coarse grained into so-called observer systems. This indicates the necessity of coarse graining an environment for the emergence of objective, classical measurement outcomes.