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Physics Letters A

Isotope shift and hyperfine structure in the 2537 Å line of Hg by line-crossing experiments in forward-scattering

G. Stanzel

Published Apr 1, 1974• 11 citations
Publisher
DOI
10.1016/0375-9601(74)90167-4

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We report on the measurement of the isotope shifts of the 3d74sa5F5–3d74pz5G6o3{d}^{7}4s\phantom{\rule{0.28em}{0ex}}a\phantom{\rule{0.28em}{0ex}}{}^{5}{F}_{5}\text{--}3{d}^{7}4p\phantom{\rule{0.28em}{0ex}}z\phantom{\rule{0.28em}{0ex}}{}^{5}{G}_{6}^{o}3d74sa5F5​–3d74pz5G6o​ Fe i line at 358 nm between all four stable isotopes 54Fe,56Fe,57Fe^{54}\text{Fe},\phantom{\rule{0.16em}{0ex}}^{56}\text{Fe},\phantom{\rule{0.16em}{0ex}}^{57}\text{Fe}54Fe,56Fe,57Fe, and 58Fe^{58}\text{Fe}58Fe, as well as the hyperfine structure of that line for 57Fe^{57}\text{Fe}57Fe, the only stable isotope having a nonzero nuclear spin. This line is of primary importance for laser-cooling applications. In addition, an experimental value of the field and specific mass shift coefficients of the transition is reported as well as the hyperfine structure magnetic dipole coupling constant AAA of the transition excited state in 57Fe^{57}\text{Fe}57Fe, namely A(3d74pz5G6o)=31.241(48)A(3{d}^{7}4p\phantom{\rule{0.28em}{0ex}}z\phantom{\rule{0.28em}{0ex}}{}^{5}{G}_{6}^{o})=31.241(48)A(3d74pz5G6o​)=31.241(48) MHz. The measurements were carried out by means of laser-induced fluorescence spectroscopy performed on an isotope-enriched iron atomic beam. All measured frequency shifts are reported with relative uncertainties below one third percent.