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Physics and Chemistry of Liquids

The Nature of Condensation in Momentum Space for an Interacting Bose Liquid

R. I. M. A. Rashid

Published Mar 1, 1990• 0 citations
Publisher

Abstract

Earlier it has been shown that the properties of superfluid helium four have an intimate connection with a non-vanishing coherent pairing as well as the generalized Bose-Einstein condensation. Here, the nature of condensation for an interacting Bose system is re-examined. It is shown that, under conditions of constant temperature and pressure, minimization of the Gibbs free energy leads to a generalized condensation of the type first proposed by Girardeau. Extrapolation of these ideas to quasiparticle models of interacting Bose systems such as helium-II leads to the conclusion that the condensation in momentum space should also be regarded as generalized in the same sense. A bonus of this approach is the disappearance of macroscopic fluctuations in the density encountered in the usual theory of the condensed ideal Bose system.

DOI
10.1080/00319109008028467

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Earlier it has been shown that the properties of superfluid helium four have an intimate connection with a non-vanishing coherent pairing as well as the generalized Bose-Einstein condensation. Here, the nature of condensation for an interacting Bose system is re-examined. It is shown that, under conditions of constant temperature and pressure, minimization of the Gibbs free energy leads to a generalized condensation of the type first proposed by Girardeau. Extrapolation of these ideas to quasiparticle models of interacting Bose systems such as helium-II leads to the conclusion that the condensation in momentum space should also be regarded as generalized in the same sense. A bonus of this approach is the disappearance of macroscopic fluctuations in the density encountered in the usual theory of the condensed ideal Bose system.
The basic assumption of this paper is that in the presence of Bose-Einstein condensation (BEC) in liquid 4He^{4}\mathrm{He}4He, the wave functions of occupied many particle states are the superposition of two components; a phase coherent component, proportional to the ground state wave function and a phase incoherent component. It is shown that this assumption satisfies necessary conditions imposed by the presence of BEC and that the wave functions of the ideal Bose gas and wave functions of the Bijl-Feynman type are of this form. It is shown that this single assumption provides simple microscopic explanations of essentially all the exotic properties of helium II; why BEC implies two fluid behavior, how the superfluid and condensate fractions are linked, how Landau theory is linked to the presence of BEC, why the superfluid exhibits flow without viscosity and macroscopic quantum effects while the normal fluid does not, how the anomalous expansion and loss of spatial order, observed in helium II as it is cooled, is linked to BEC, and how the presence of sharp peaks observed in the dynamic structure factor are linked with BEC. The theory provides predictions that are in quantitative agreement with a wide range of presently unexplained experimental data on helium II.
One considers the superfluid (SF) state of a Bose liquid with a strong repulsion between bosons, in which at T=0, along with a weak single-particle Bose-Einstein condensate (BEC), there exists an intensive pair coherent condensate (PCC), analogous to the Cooper condensate in a Fermi liquid with an attraction between the fermions. Such a PCC emerges in a system of bosons due to an oscillating sign-changing momentum dependence of the Fourier component of the pair interaction potential, which is characteristic of a certain family of repulsion potentials. In such cases, the Fourier component is negative in some domain of nonzero momentum transfer, which corresponds to an effective attraction. The collective effects of renormalization (``screening'') of the initial interaction lead to a suppression of the repulsion and an enhancement of the effective attraction. It is the ratio of the BEC density to the full density of the liquid n0/n≪1n_0/n\ll 1n0​/n≪1 that is used as a small parameter---unlike in the Bogolyubov theory for a quasi-ideal Bose gas, in which the small parameter is the ratio of the number of supracondensate excitations to the number of particles in an intensive BEC, (n−n0)/n0≪1(n-n_0)/n_0\ll 1(n−n0​)/n0​≪1. A closed system of nonlinear integral equations for the normal and anomalous self-energy parts is obtained, in the framework of a renormalized perturbation theory built on combined hydrodynamic and field variables. In the framework of the hard-spheres model, a spectrum of quasiparticles is obtained, which is in good accordance with the experimental spectrum of elementary excitations in superfluid 4^44He. The question of applicability of the Landau criterion in the absence of quantum vortices is discussed.
The Bose-Einstein condensation mechanism is shown to be capable of accounting for the existence of separate hydrodynamic velocity fields for the normal and the superfluid, provided suitable assumptions are made with regard to the single-particle energy spectrum. We consider the effect on the microcanonical gas distribution of imposing a nonzero value of the total momentum P. For an ordinary gas the effect is trivial, the whole distribution being merely shifted in momentum space. However, in the case of a degenerate Bose gas whose single-particle energy spectrum has a sharp minimum (gap or cusp), only the excited part of the gas (normal fluid) participates in the imposed motion, the condensate (superfluid) remaining "frozen" in momentum space. This rigidity of the condensate in momentum space plays the same role as the rigidity of the superelectrons on imposition of a magnetic field in the London theory of superconductivity. P acts as an additional thermodynamic variable, states with P \ensuremath{\ne} 0 being macroscopically metastable and corresponding to the existence of a relative velocity between normal and superfluid. The basic hydrodynamic assumption of the two-fluid model is thus reduced to an assumption concerning the form of an effective single-particle energy spectrum, and the parallelism between the theories of superconductivity and superfluidity is clearly exhibited. The present theory permits, in particular, the introduction of the mathematical form of Landau's phonon and "roton" spectra within the framework of the Bose-Einstein condensation picture. The statistical-thermodynamic formulas are derived and are shown to lead to characteristic two-fluid equations derived previously from a variational principle.
The paradoxes and disparities in the contemporary microscopic theory of superfluid helium (He–II) are discussed along with possible ways of resolving them by taking pair correlations of He4 atoms into consideration. It is shown that most paradoxes are associated with the commonly accepted initial assumption concerning the dominating role of single-particle Bose condensate (SPBC) in the quantum microstructure of the superfluid component ρs. The existence of intensive SPBC leads to a strong hybridization of the elementary excitation branches and to a common dispersion law for all boson branches, which is identified with the quasiparticle spectrum E(p) observed experimentally from slow neutron scattering in liquid helium. However, the stability of this spectrum during a transition through the λ-point and the large value of the gap in the vicinity of the “rotonic” minimum contradict both the Landau theoretical criterion of superfluidity and the small value of experimentally measured critical velocity. At the same time, a strong interaction between particles in the Bose liquid He4 strongly suppresses the SPBC which amounts to less than 1% of all He4 atoms and hence cannot be the main constituent of the superfluid component, unlike the case of a weakly nonideal Bose gas. Moreover, for a quite strong attraction between particles in a certain region of the momentum space, bound pairs of bosons can be formed in the superfluid Bose liquid, and a coherent pair condensate (CPC) analogous to the Cooper pair condensate in superconductors may appear. Such a strong CPC may completely suppress the weak SPBC. In this case, the one-particle spectrum ε(p) of elementary excitations does not hybridize with the collective (two-particle) spectrum and does not appear in the structure of the dynamic form factor S(p,ε), i.e., does not coincide with the spectrum measured from neutron scattering. The dispersion of one-particle spectrum is defined by the momentum dependence of the pair order parameter Ψ̃(p) and may have a minimum or a point of inflection at p≠0. This peculiarity in the one-particle spectrum of a Bose liquid with CPC but without SPBC vanishes together with Ψ̃(p) at the temperature Tc=Tλ of the phase transition from the superfluid to the normal state (unlike the rotonic minimum in the collective spectrum), while the corresponding critical velocity vc=min[ε(p)/p] vanishes at the λ-point in accordance with the Landau criterion and the experimental data. The assumption that the strong “Cooper-like” CPC is responsible for the quantum structure of the superfluid component ρs is confirmed indirectly by the successful application of the Justrow approximation (based on strong pair correlations) for describing the properties of liquid He4 and quantum liquid mixtures He3–4He on one hand, and by an anomalously large effective mass of He3 impurity atoms in He4, which is approximately equal to total mass of He3 and He4 atoms, thus pointing to the existence of helium atoms in superfluid liquid He–II. The value of the superfluid velocity circulation quantum in the Onsager–Feynman vortices in a Bose liquid with CPC but without SPBC is discussed as well as the critical velocities of superfluid He4 in ultrathin films and channels in which the creation and motion of quantum vortices are ruled out, and the quasiparticle spectrum undergoes dimensional quantization.
The condition which has to be fulfilled in order that the Bose-Einstein condensation be accompanied by a discontinuity of the heat capacity at the condensation temperature is discussed. The nature of the transition depends on the distribution of the energy levels of the individual particles forming the gas. The condensation is studied for several types of individual energy spectra. It is shown that all those Bose-Einstein (B.E.) assemblies which admit a non-ambiguous definition of the statistical distribution function present, beside interesting analogies, a qualitatively different behavior from that observed in liquid helium. It appears that as long as the transition in momentum space of non-ideal B.E. systems is not understood, the possibility of connection between B.E. condensation and the transition observed in liquid helium remains an open problem.
A self-consistent model of the superfluid (SF) state of a Bose liquid with strong interaction between bosons is considered, in which at T=0, along with a weak single-particle Bose-Einstein condensate (BEC), there exists an intensive pair coherent condensate (PCC) of bosons, analogous to the Cooper pair condensate of fermions. Such a PCC emerges due to an effective attraction between bosons in some regions of momentum space, which results from an oscillating sign-changing momentum dependence of the Fourier component V(p) of the interaction potential. The collective many-body effects of renormalization ("screening") of the initial interaction, which are described by the bosonic polarization operator Π(p,ω), lead to a suppression of the repulsion [V(p)>0] and an enhancement of the effective attraction [V(p)<0] in the respective domains of nonzero momentum transfer. The ratio of the BEC density n_0 to the total particle density n of the Bose liquid is used as a small parameter of the model. A closed system of nonlinear integral equations for the normal and anomalous self-energy parts is obtained with account for the terms of first order in the BEC density. In the framework of the ``soft spheres'' model with the single fitting parameter--the value of the repulsion potential at r=0, a theoretical quasiparticle spectrum E(p) is obtained, which is in good accordance with the experimental spectrum E_{exp}(p) of elementary excitations in superfluid 4^44He.