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Dissipation, mixing and two level system in quantum field theory

Angelo Bruno

Published Apr 30, 2012• 0 citations
OpenAlex

Abstract

In this dissertation we discuss several aspects of a two level system (qubit) in the context of quantum mechanics and quantum eld theory. The presence of geometrical phases in the evolution of a qubit state is shown. We study geometric structures, which are correlated to an unitary time evolution and its interesting gauge structure. They can be very useful in quantum computational processes. We illustrate the quantum eld theoretical formulation of boson mixed elds, and oscillation formulas for neutral and charged elds are found. We show that the space for the mixed elds is unitary inequivalent to the state space where the unmixed eld are de ned, and we also derive the structure of the currents and charges for the charged mixed elds. Phenomenological aspects of meson mixing in the presence of the decay are discussed. In particular, we show that the the e ective Hamiltonian is non-Hermitian and non-normal in the Wigner-Weisskopf approximation and we use the biorthonormal basis formalism to diagonalize such an Hamiltonian. Finally, the presence of CP and CPT violations in meson mixing is shown.

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Quantum dissipation theory and applications to quantum transport and quantum measurement in mesoscopic systems

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The thesis comprises two major themes of quantum statistical dynamics. One is the development of quantum dissipation theory (QDT). It covers the establishment of some basic relations of quantum statistical dynamics, the construction of several nonequivalent complete second-order formulations, and the development of exact QDT. Another is related to the applications of quantum statistical dynamics to a variety of research fields. In particular, unconventional but novel theories of the electron transfer in Debye solvents, quantum transport, and quantum measurement are developed on the basis of QDT formulations. The thesis is organized as follows. In Chapter 1, we present some background knowledge in relation to the afore-mentioned two themes of this thesis. The key quantity in QDT is the reduced density operator ρ(t) ≡ trBρT(t); i.e., the partial trace of the total system and bath composite ρT(t) over the bath degrees of freedom. 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•Jan 1, 2006•0 citations

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Geometry of mixed states and degeneracy structure of geometric phases for multi-level quantum systems. A unitary group approach

Elisa Ercolessi, Giuseppe Marmo, G. Mor +1 more

We analyze the geometric aspects of unitary evolution of general states for a multilevel quantum system by exploiting the structure of coadjoint orbits in the unitary group Lie algebra. Using the same method in the case of SU(3) we study the effect of degeneracies on geometric phases for three-level systems. This is shown to lead to a highly nontrivial generalization of the result for two-level systems in which degeneracy results in a "monopole" structure in parameter space. The rich structures that arise are related to the geometry of adjoint orbits in SU(3). The limiting case of a two-level degeneracy in a three-level system is shown to lead to the known monopole structure.

•May 3, 2001•22 citations
In this dissertation we discuss several aspects of a two level system (qubit) in the context of quantum mechanics and quantum eld theory. The presence of geometrical phases in the evolution of a qubit state is shown. We study geometric structures, which are correlated to an unitary time evolution and its interesting gauge structure. They can be very useful in quantum computational processes. We illustrate the quantum eld theoretical formulation of boson mixed elds, and oscillation formulas for neutral and charged elds are found. We show that the space for the mixed elds is unitary inequivalent to the state space where the unmixed eld are de ned, and we also derive the structure of the currents and charges for the charged mixed elds. Phenomenological aspects of meson mixing in the presence of the decay are discussed. In particular, we show that the the e ective Hamiltonian is non-Hermitian and non-normal in the Wigner-Weisskopf approximation and we use the biorthonormal basis formalism to diagonalize such an Hamiltonian. Finally, the presence of CP and CPT violations in meson mixing is shown.
We investigate the geometric structure of a Hermitian two-level mixing Hamiltonian motivated by neutral meson oscillations and its connections with qubit, fermionic, and topological descriptions. Mapping the Hamiltonian to an effective qubit representation, we analyze the geometric phase associated with cyclic parameter evolution on the Bloch sphere. Without identifying the complex mixing phase with a physical CP-violation observable, we interpret it as a CP-like geometric parameter controlling the azimuthal orientation of the Hamiltonian vector and its reversal under phase conjugation. Third-order Bargmann invariants constructed from the eigenstates yield an associated discrete phase whose dependence on the mixing parameters is examined alongside the continuous geometric construction. The cyclic evolution is also represented as a single-qubit RzR_zRz​ phase operation and expressed through Majorana bilinears. Extending the construction to the momentum-dependent Bogoliubov-de Gennes Hamiltonian of the Kitaev chain, we relate momentum-space winding to the topological regimes and the quantized Berry (Zak) phase in the real-parameter model, while the corresponding Bargmann construction approaches the global phase in the continuum limit. Together, these results provide a geometric perspective connecting phase structure, qubit operations, fermionic representations, and momentum-space topology within related two-level Hamiltonians.
This thesis consists of several studies performed over different few-dof quantum systems exposed to the effect of an uncontrolled environment. The primary focus of the work is to explore the relation between decoherence and environmentally-induced dissipative effects, and the concept known as geometric phases. The first mention of such an object in the context of quantum mechanics goes back to the seminal work by Berry. He demonstrated that the phase acquired by an eigenstate of a time-dependent Hamiltonian in an adiabatic cycle consists of two distinct contributions: one termed 'geometric' and the other known as the dynamical phase. Since Berry's work, the notion of geometric phase has been extended far beyond the original context, encompassing definitions applicable to arbitrary unitary evolutions. These geometric phases naturally arise in the geometric description of Hilbert space, where they manifest as holonomies and possess significance in the fundamental understanding of quantum mechanics and its mathematical framework, and in explaining various physical phenomena, including the Fractional Hall Effect. Moreover, from a modern perspective, geometric phases hold promise for practical applications, such as constructing geometric gates for quantum information processing and storage. However, in practice, a pure state of a quantum system is an idealized concept, and every experimental or real-world implementation must account for the presence of an environment that interacts with the observed system. This interaction necessitates a description in terms of mixed states and non-unitary evolutions. The definition of a geometric phase applicable in such scenarios remains an open problem, giving rise to multiple proposed solutions. Consequently, characterizing these geometric phases encompase motivations from fundamental aspects of quantum mechanics to technological applications.
This thesis, explores the quantum entanglement and evolution through both a geometric and dynamical perspective. The first part focuses on classical phase space and its central role in Hamiltonian mechanics, emphasizing the importance of symplectic structures in describing mechanical states. The study highlights the formal analogy between classical phase space and the Hilbert space used in quantum mechanics. The second part is devoted to the geometric description of quantum states through the projective structure of Hilbert space. Emphasis is placed on the geometric interpretation of quantum evolution, particularly via the Fubini-Study metric, associated symplectic structures, and the geometric phase acquired during unitary evolutions. The final two parts are dedicated to the study of spin systems (both two-body and many-body) under different interaction models (XXZ Heisenberg and all-range Ising). Both the dynamical aspects (evolution speed, entanglement, and the quantum brachistochrone problem) and the geometric and topological structures of the corresponding quantum states are analyzed.
The thesis comprises two major themes of quantum statistical dynamics. One is the development of quantum dissipation theory (QDT). It covers the establishment of some basic relations of quantum statistical dynamics, the construction of several nonequivalent complete second-order formulations, and the development of exact QDT. Another is related to the applications of quantum statistical dynamics to a variety of research fields. In particular, unconventional but novel theories of the electron transfer in Debye solvents, quantum transport, and quantum measurement are developed on the basis of QDT formulations. The thesis is organized as follows. In Chapter 1, we present some background knowledge in relation to the afore-mentioned two themes of this thesis. The key quantity in QDT is the reduced density operator ρ(t) ≡ trBρT(t); i.e., the partial trace of the total system and bath composite ρT(t) over the bath degrees of freedom. QDT governs the evolu-tion of reduced density operator, where the effects of bath are treated in a quantum statistical manner. In principle, the reduced density operator contains all dynam-ics information of interest. However, the conventional quantum transport theory is formulated in terms of nonequilibrium Green's function. The newly emerging field of quantum measurement in relation to quantum information and quantum computing does exploit a sort of QDT formalism. Besides the background of the relevant theoretical development, some representative experiments on molecular nanojunctions are also briefly discussed. In Chapter 2, we outline some basic (including new) relations that highlight several important issues on QDT. The content includes the background of nonequi-librium quantum statistical mechanics, the general description of the total compos-ite Hamiltonian with stochastic system-bath interaction, a novel parameterization scheme for bath correlation functions, a newly developed exact theory of driven Brownian oscillator (DBO) systems, and its closely related solvation mode trans-formation of system-bath coupling Hamiltonian in general. The exact QDT of DBO systems is also used to clarify the validity of conventional QDT formulations that involve Markovian approximation. In Chapter 3, we develop three nonequivalent but all complete second-order QDT (CS-QDT) formulations. Two of them are of the conventional prescriptions in terms of time-local dissipation and memory kernel, respectively. The third one is called the correlated driving-dissipation equations of motion (CODDE). This novel CS-QDT combines the merits of the former two for its advantages in both the application and numerical implementation aspects. Also highlighted is the importance of correlated driving-dissipation effects on the dynamics of the reduced system. In Chapter 4, we construct an exact QDT formalism via the calculus on path integrals. The new theory aims at the efficient evaluation of non-Markovian dis-sipation beyond the weak system-bath interaction regime in the presence of time-dependent external field. By adopting exponential-like expansions for bath corre-lation function, hierarchical equations of motion formalism and continued fraction Liouville-space Green's function formalism are established. The latter will soon be used together with the Dyson equation technique for an efficient evaluation of non-perturbative reduced density matrix dynamics. The interplay between system-bath interaction strength, non-Markovian property, and the required level of hierarchy is also studied with the aid of simple spin-boson systems, together with the three proposed schemes to truncate the infinite hierarchy. In Chapter 5, we develop a nonperturbative theory of electron transfer (ET) in Debye solvents. The resulting exact and analytical rate expression is constructed on the basis of the aforementioned continued fraction Liouville-space Green's func-tion formalism, together with the Dyson equation technique. Not only does it re-cover the celebrated Marcus' inversion and Kramers' turnover behaviors, the new theory also shows some distinct quantum solvation effects that can alter the ET mechanism. Moreover, the present theory predicts further for the ET reaction ther-modynamics, such as equilibrium Gibbs free-energy and entropy, some interesting solvent-dependent features that are calling for experimental verification. In Chapter 6, we discuss the constructed QDTs, in terms of their unified math-ematical structure that supports a linear dynamics space, and thus facilitates their applications to various physical problems. The involving details are exemplified with the CODDE form of QDT. As the linear space is concerned, we identify the Schrödinger versus Heisenberg picture and the forward versus backward propaga-tion of the reduced, dissipative Liouville dynamics. For applications we discuss the reduced linear response theory and the optimal control problems, in which the correlated effects of non-Markovian dissipation and field driving are shown to be important. In Chapter 7, we turn to quantum transport, i.e. electric current through molecular or mesoscopic systems under finite applied voltage. By viewing the nonequilibrium transport setup as a quantum open system, we develop a reduced-density-matrix approach to quantum transport. The resulting current is explicitly expressed in terms of the molecular reduced density matrix by tracing out the degrees of freedom of the electrodes at finite bias and temperature. We propose a conditional quantum master equation theory, which is an extension of the conven-tional (or unconditional) QDT by tracing out the well-defined bath subsets indi-vidually, instead of the entire bath degrees of freedom. Both the current and the noise spectrum can be conveniently analyzed in terms of the conditional reduced density matrix dynamics. By far, the QDT (including the conditional one) has only been exploited in a second-order form. A self-consistent Born approximation for the system-electrode coupling is further proposed to recover all existing nonlinear current-voltage behaviors including the nonequilibrium Kondo effect. Transport theory based on the exact QDT formalism will be developed in future. In Chapter 8, we study the quantum measurement of a qubit with a quantum-point-contact detector. On the basis of a unified quantum master equation (a form of QDT), we study the measurement-induced relaxation and dephasing of the qubit . Our treatment pays particular attention on the detailed-balance relation, which is a consequence of properly accounting for the energy exchange between the qubit and detector during the measurement process. We also derive a conditional quantum master equation for quantum measurement in general, and study the readout characteristics of the qubit measurement. Our theory is applicable to the quantum measurement at arbitrary voltage and temperature. A number of remarkable new features are found and highlighted in concern with their possible relevance to future experiments. In Chapter 9, we discuss the further development of QDT, aiming at an effi-cient evaluation of many-electron systems. This will be carried out by reducing the many-particle (Fermion or Boson) QDT to a single-particle one by exploring, e.g. the Wick's contraction theorem. It also results in a time-dependent density func-tional theory (TDDFT) for transport through complex large-scale (e.g. molecules) systems. Primary results of the TDDFT-QDT are reported. In Chapter 10, we summary the thesis, and comment and remark on the future work on both the theoretical and application aspects of QDT.
We analyze the geometric aspects of unitary evolution of general states for a multilevel quantum system by exploiting the structure of coadjoint orbits in the unitary group Lie algebra. Using the same method in the case of SU(3) we study the effect of degeneracies on geometric phases for three-level systems. This is shown to lead to a highly nontrivial generalization of the result for two-level systems in which degeneracy results in a "monopole" structure in parameter space. The rich structures that arise are related to the geometry of adjoint orbits in SU(3). The limiting case of a two-level degeneracy in a three-level system is shown to lead to the known monopole structure.