Abstract Applying the (infinite) density-matrix renormalisation group technique, we explore the effect of an explicit dimerisation on the ground-state phase diagram of the spin-1 XXZ chain with single-ion anisotropy D. We demonstrate that the Haldane phase between large-D and antiferromagnetic phases survives up to a critical dimerisation only. As a further new characteristic the dimerisation induces a direct continuous Ising quantum phase transition between the large-D and antiferromagnetic phases with central charge
c=1/2 c = 1 / 2 , which terminates at a critical end-point where
c=7/10 c = 7 / 10 . Calculating the critical exponents of the order parameter, neutral gap and spin–spin-correlation function, we find
β=1/8 β = 1 / 8 (1/24),
ν=1 ν = 1 (5/9), and
η=1/4 η = 1 / 4 (3/20), respectively, which proves the Ising (tricritical Ising) universality class in accordance with field-theoretical predictions.
We show that the higher Berry curvature (HBC) can be used to count the gapless edge modes created by an entanglement cut, and thus defines an integer-valued topological order parameter for quantum spin chains. Given an individual spin-chain Hamiltonian, we construct an extending family by interpolating to a reference product Néel state, and show that the integral of the HBC over this extension is equal to the ordinary Berry phase of half of the chain swept out in response to an \textit{infinitesimal} field. It thus counts the spin of the gapless edge modes exposed by the cut, and a change in its integer value signals a phase transition. We illustrate this with several examples:
S=1/2,
S=1, and
S=3/2 spin-Peierls chains, which undergo `singlet flop' transitions between different patterns of dimerisation; the bilinear-biquadratic chain, which clarifies the connection to the strict symmetry-protected topological phases classification; and the staggered
J1--
J2 chain, which has both nearest-neighbour and third-neighbour patterns of singlets depending on the signs of the interactions.
The author shows that SU(n) antiferromagnetic chains (or equivalently SU(2) spin-s-chains with Hamiltonians which project out singlet states) are exactly equivalent to the n 2 -state quantum Potts chain (obtained from the transfer matrix for the 2D classical Potts model), for arbitrary n (or s with n=2s+1). This implies that the models are spontaneously dimerised with a finite gap for n<2 but have a unique ground state and vanishing gap for n<or=2. The n to 0 limit may have some bearing on the quantum-Hall-effect localisation transition.