The rapid progress of the field of ultracold atoms during the past two decades has set new milestones in our control over matter. By cooling dilute atomic gases and molecules to nano-Kelvin temperatures, novel quantum mechanical states of matter can be realized and studied on a table-top experimental setup while bulk matter can be tailored to faithfully simulate abstract theoretical models. Two of such models which have witnessed significant experimental and theoretical attention are (1) the two-component Fermi gas with resonant $s$-wave interactions, and (2) the single-component Fermi gas with dipole-dipole interactions. This thesis is devoted to studying the non-equilibrium collective dynamics of these systems using the general framework of quantum kinetic theory.
The rapid progress of the field of ultracold atoms during the past two decades has set new milestones in our control over matter. By cooling dilute atomic gases and molecules to nano-Kelvin temperatures, novel quantum mechanical states of matter can be realized and studied on a table-top experimental setup while bulk matter can be tailored to faithfully simulate abstract theoretical models. Two of such models which have witnessed significant experimental and theoretical attention are (1) the two-component Fermi gas with resonant s-wave interactions, and (2) the single-component Fermi gas with dipole-dipole interactions. This thesis is devoted to studying the non-equilibrium collective dynamics of these systems using the general framework of quantum kinetic theory.
Motivated by rapid experimental progress in the fields of ultracold atoms and quantum optics, I present a series of theoretical studies which explore collective phenomena in quantum gases of atoms and photons. In Chapter 1, I highlight the major developments in the research field and identify the overarching themes and motivations. I also provide a roadmap for the rest of the thesis and summarize the main results. The remaining eight chapters contain original studies, organized along three broad motifs. In Chapters 2 through 5, I investigate how the nature of collective excitations and quasiparticles can be explored in modern experiments. More specifically, I model the dynamics of a spin impurity in a Bose lattice gas, develop a protocol for observing fractionalized excitations or anyons in an optical cavity, and characterize the collective dynamics of Bogoliubov quasiparticles and domain walls in a Fermi superfluid. In Chapters 6 and 7, I examine unconventional superfluid phases in spin-imbalanced Fermi gases. In particular, I propose a novel technique for engineering the long-sought-after Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) phase and study the relative stability of exotic phases across a dimensional crossover. Finally, Chapters 8 and 9 are devoted to studies of kinetics in out-of-equilibrium systems. I model the formation of a Bose-Einstein condensate in a dimple trap and characterize the approach to thermal equilibrium in quasi-one-dimensional geometries.
The interplay between spin and motional degrees of freedom in interacting electron systems has been a long-standing research topic in condensed matter physics. Interactions can modify the behavior of individual electrons and give rise to emergent collective phenomena such as superconductivity and colossal magnetoresistance. Theoretical understanding of non-equilibrium dynamics in interacting fermionic matter is limited, however, and many open questions remain. Ultracold atomic Fermi gases, with precisely controllable parameters, offer an outstanding opportunity to investigate the emergence of collective behavior in out-of-equilibrium settings. In this thesis we will describe how an optical lattice clock operated with neutral Fermionic atoms can be turned into a quantum simulator of charged particles in a strong magnetic field. We will then discuss the counterintuitive notion that weak interactions in a Fermi gas can lead to large scale collective behavior and global correlations. These ideas are being tested experimentally at JILA and the University of Toronto. We also investigate in detail the so-called spin model approximation which is used extensively throughout this thesis.
Rydberg atoms, characterized by their strong and long-range dipole-dipole interactions, provide a versatile platform for exploring intriguing collective and many-body effects. Recently, the experimental realization of these effects in dense ensembles and reconfigurable atomic arrays has attracted significant interest, particularly for applications in quantum simulations and non-equilibrium physics. This review focuses on such recent development, discussing the theoretical foundations of the interactions between Rydberg atoms and the ensuing many-body physics, while providing a critical survey of experimental techniques for their precise manipulation and observation. We further discuss recent breakthroughs in leveraging Rydberg collective effects to probe novel many-body phases and non-equilibrium dynamics of these systems. By synthesizing theoretical insights with experimental milestones, we provide a comprehensive perspective on this rapidly evolving field and its transformative potential for future quantum technologies.
The study of out-of-equilibrium dynamics in ultra-cold gases is a new and exciting field, driven largely by the recent experimental advances in controlling and imaging cold clouds. The experimental and theoretical work thus far has been somewhat exploratory and largely numerical in nature, as the very paradigms for thinking about these systems are not well established. In this thesis I consider several different scenarios of ultra-cold bosonic and fermionic gases driven out of equilibrium and study their properties. In Chapter 1, I provide an overview of the phenomenology of ultra-cold gases, highlighting the timescales governing these systems and how the experimentalist can tune them. I discuss how cold gases can be cooled and trapped and discuss the basic physics behind optical lattices. I also discuss experimental probes of these gases, in particular the new high resolution imaging techniques developed recently at Chicago, Munich and Harvard. In Chapter 2, I discuss an early experiment (circa. 2008) which observed long lived spin dynamics in a thermal spin-1/2 Fermi gas. This experiment is an nice illustration of interesting physics resulting from the separation of timescales between spin and collisional dynamics. In my opinion, it is an excellent example of why cold gases are naturally suited to studying non-equilibrium dynamics. I simulate the experiment numerically using a collisionless Boltzmann equation and explain the observed spin dynamics both qualitatively and quantitively. In Chapter 3, I continue the discussion of spin waves in thermal gases by extending previous works on spin-1/2 gases to spin-1 Bose gases. In contrast to Chapter 2, the bulk of the work in this Chapter is analytic in nature. In particular, I find a spin wave instability in the thermal spin-1 Bose gas, which is the high temperature analog of the polar to ferromagnetic transition in a spin-1 Bose Einstein condensate. In Chapter 3, I turn my attention to bosonic systems and briefly review the the Bogoliubov mean-field theory. I calculate the momentum distribution and density-density correlation function of an interacting Bose gas within the Bogoliubov framework. Then I consider bosons in an optical lattice, and introduce the Bose Hubbard model. I calculate the mean-field phase diagram of the Bose Hubbard model and then consider fluctuations about the mean field, and derive the excitation spectrum of the lattice gas in the superfluid and insulating regimes. In Chapter 4, I ask what we learn by studying the dynamics of correlation functions following a sudden change in the interactions in a superfluid. Using the Bogoliubov theory developed in Chapter 3, I will show how the underlying excitation spectrum influences the long and short time behavior of the correlation functions. By considering a lattice dispersion, I study the analogous problem in a weak optical lattice and discuss how the lattice dispersion leads to additional features in the correlation functions. I will also discuss the timescale governing the revival of the condensate fraction in a quantum depleted gas. In Chapter 5, I derive equations of motion governing the dynamics of one and two body correlation functions in the single-band Bose Hubbard model, applicable to bosons in deep lattices. I then consider a simple quench from a Mott insulating initial state to a weakly interacting final state and produce analytic expressions describing the dynamics of correlations following such a quench. I discuss the timescale for the development of long range order following such a quench. I study the problem of chapter 4 using an equations of motion approach. This approach complements the Bogoliubov approach of Chapter 4. First, I derive exact expressions for a quench to a non-interacting state. I then consider how interactions redistribute quasi-momentum to first order in perturbation theory in different dimensions. In Chapter 6, I calculate the relevant timescales for local and global dynamics in trapped lattice Bose gases, a work done in collaboration with Dr. Kaden R. A Hazzard. Using a time-dependent Gutzwiller mean-field theory, I show that the timescale for local equilibration in these systems is fast in experimental terms. I then show that due to the spatial inhomogeneities inherent to cold gases, achieving global equilibrium can be quite complicated, sometimes taking longer than the lifetime of the experiment, an issue of practical importance to current day experiments. I continue this discussion in Chapter 7 which is a collaborative work with experimentalists David McKay and Prof. Brian DeMarco from the University of Toronto and the University of Illinois, Urbana Champaign. Using experimental and numerical methods, we show that the rapid timescales for local dynamics in interacting systems invalidates a frequently used cold atom technique for mapping out the momentum distribution of atoms in an optical lattice.
Strongly correlated quantum systems display a myriad of complex, fascinating behaviour. The competition between charge, spin, orbital, or lattice degrees of freedom and their respective energy scales gives rise to rich and complex emergent phases. More recently, the non-equilibrium properties of correlated quantum many-body systems have come into the focus of active research, with remarkable advances. While the advent of tensor network based simulations on the theoretical side has allowed access to the full time-evolution of the quantum state as it traverses the Hilbert space, the experimental progress in the ultracold atom community has allowed physicists to enter the paradigm of analog quantum simulation. Their tunability and isolation from the environment makes them ideal platforms to emulate and study open problems in condensed matter physics and go beyond the simulational capabilities of state of the art classical simulations. In this thesis, we explore the dynamics of correlated Fermi gases. We develop and present different facets of applicability of radiofrequency modulation techniques to drive the system out of equilibrium. We begin by considering a homogeneous, three-dimensional Fermi gas in the BCS-BEC crossover and develop an off-resonant radiofrequency transfer scheme to excite the Higgs mode of the superfluid. In a subsequent study we investigate the tunability of the coherence between Cooper pairs by tuning the duration of interaction ramps of the internal interaction strength. These works highlight the possibility to externally tune and stabilise complex quantum many-body states away from equilibrium. Using quasi-exact matrix product state simulations, we study the response of an attractively interacting, one-dimensional Fermi-Hubbard model to weak radiofrequency perturbations. We reveal the emergence of two distinct dynamical regimes in the time evolution and are able to relate it back to the underlying excitation spectrum of the system. Finally, we explore the possibility to perform quantum quenches through radiofrequency π-pulses, achieving nearly complete population transfer between different interacting fermionic states. We reveal non-trivial dynamical effects in the pair correlation of the final state, as well as the excitation of a collective trap mode of the system.
Recent advances in theoretical physics have increasingly focused on the dynamics of quantum systems with many interacting degrees of freedom, while ultracold atom platforms now enable the realization of diverse theoretical models with precise control over system parameters and advanced monitoring techniques. A prominent example is cavity quantum electrodynamics (CQED), where large atomic or molecular ensembles are coupled to high-finesse optical cavities, enabling strong interaction with confined electromagnetic modes and leading to phenomena such as the superradiant phase transition, in which atoms and photons form a coherent state. Most theoretical studies of CQED have concentrated on regimes of spatially uniform atom–cavity coupling, where collective behavior allows a description in terms of the classical dynamics of a few macroscopic variables. However, experimental capabilities now permit exploration beyond this limit, though theoretical progress is hindered by the exponential computational complexity of simulating large quantum systems, particularly when environmental coupling is included. This thesis addresses such challenges by developing efficient approaches, within the Keldysh formalism of non-equilibrium quantum field theory, to study systems with strongly disordered interactions coupled to external reservoirs. Two representative models are considered: a disordered spin–boson model describing light–matter interactions with quenched disorder, relevant to recent CQED experiments in confocal cavities, and a fermion–phonon system governed by the Yukawa–Sachdev–Ye–Kitaev (Yukawa-SYK) model. Both systems are quantum critical, exhibiting a continuum of low-energy modes above their stationary states, yet disorder produces qualitatively distinct dynamical behaviors: in the spin–boson system it induces slow, glassy relaxation, whereas in the Yukawa-SYK model it leads to rapid thermalization. These contrasting outcomes reveal the non-trivial role of disorder in quantum many-body systems and motivate further investigation into its effects on non-equilibrium quantum dynamics.