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Measurement-based Formulation of Quantum Heat Engine and Optimal Efficiency with Finite-Size Effect

Hiroyasu Tajima, Masahito Hayashi

Published Apr 23, 2015• 0 citations
OpenAlex

Abstract

There exist two formulations for quantum heat engine. One is semi-classical scenario, and the other is full quantum scenario. The former is formulated as a unitary evolution for the internal system (working body and heat baths), and is adopted by the community of statistical mechanics. The latter is formulated as a unitary for the work storage and the internal system. It is adopted by the community of quantum information. However, these formulations do not consider measurement process. In this paper, we formulate the quantum heat engine based on the quantum measurement theory, because the amount of extracted work should be observed in a practical situation. With using our formulation, we derive two trade-off relations that show the semi-classical scenario does not work when the amount of extracted work is observed, i.e., we can hardly know the amount of the extracted work when the time evolution of the internal system is close to unitary. Next, based on our formulation, we derive the optimal efficiency of quantum heat engines with the finite-size heat baths, without assuming the existence of quasi-static processes. Using the strong large deviation theory, we asymptotically expand the optimal efficiency up to the third order. The first term is shown to be Carnot efficiency, and the higher order terms are shown to be the finite-size effects of the heat baths. We can construct the optimal work extraction as an energy-preserving unitary evolution among the internal system and the work storage. During the optimal work extraction, the entropy gain of the work storage is so negligibly small as compared with the energy gain of the work storage.

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•Jan 1, 2017•0 citations
There exist two formulations for quantum heat engine. One is semi-classical scenario, and the other is full quantum scenario. The former is formulated as a unitary evolution for the internal system (working body and heat baths), and is adopted by the community of statistical mechanics. The latter is formulated as a unitary for the work storage and the internal system. It is adopted by the community of quantum information. However, these formulations do not consider measurement process. In this paper, we formulate the quantum heat engine based on the quantum measurement theory, because the amount of extracted work should be observed in a practical situation. With using our formulation, we derive two trade-off relations that show the semi-classical scenario does not work when the amount of extracted work is observed, i.e., we can hardly know the amount of the extracted work when the time evolution of the internal system is close to unitary. Next, based on our formulation, we derive the optimal efficiency of quantum heat engines with the finite-size heat baths, without assuming the existence of quasi-static processes. Using the strong large deviation theory, we asymptotically expand the optimal efficiency up to the third order. The first term is shown to be Carnot efficiency, and the higher order terms are shown to be the finite-size effects of the heat baths. We can construct the optimal work extraction as an energy-preserving unitary evolution among the internal system and the work storage. During the optimal work extraction, the entropy gain of the work storage is so negligibly small as compared with the energy gain of the work storage.
There exist two formulations for quantum heat engines that model energy transfer between two microscopic systems. One is the semiclassical scenario and the other is the full quantum scenario. The former is formulated as unitary evolution for the internal system and is adopted by the statistical mechanics community. In the latter, the whole process is formulated as unitary and is adopted by the quantum information community. This paper proposes a model for quantum heat engines that transfer energy from a collection of microscopic systems to a macroscopic system like a fuel cell. In such a situation, the amount of extracted work is visible for a human. For this purpose, we formulate a quantum heat engine as the measurement process whose measurement outcome is the amount of extracted work. Under this model, we derive a suitable energy-conservation law and propose a more concrete submodel. Then we derive a trade-off relation between the measurability of the amount of work extraction and the coherence of the internal system, which limits the applicability of the semiclassical scenario to a heat engine transferring energy from a collection of microscopic systems to a macroscopic system.
The optimal efficiency of quantum (or classical) heat engines whose heat baths are n-particle systems is given by the strong large deviation. We give the optimal work extraction process as a concrete energy-preserving unitary time evolution among the heat baths and the work storage. We show that our optimal work extraction turns the disordered energy of the heat baths to the ordered energy of the work storage, by evaluating the ratio of the entropy difference to the energy difference in the heat baths and the work storage, respectively. By comparing the statistical mechanical optimal efficiency with the macroscopic thermodynamic bound, we evaluate the accuracy of the macroscopic thermodynamics with finite-size heat baths from the statistical mechanical viewpoint. We also evaluate the quantum coherence effect on the optimal efficiency of the cycle processes without restricting their cycle time by comparing the classical and quantum optimal efficiencies.
Many studies of quantum-size heat engines assume that the dynamics of an internal system is unitary and that the extracted work is equal to the energy loss of the internal system. Both assumptions, however, should be under scrutiny. In the present paper, we analyze quantum-scale heat engines, employing the measurement-based formulation of the work extraction recently introduced by Hayashi and Tajima [M. Hayashi and H. Tajima, arXiv:1504.06150]. We first demonstrate the inappropriateness of the unitary time evolution of the internal system (namely, the first assumption above) using a simple two-level system; we show that the variance of the energy transferred to an external system diverges when the dynamics of the internal system is approximated to a unitary time evolution. Second, we derive the quantum Jarzynski equality based on the formulation of Hayashi and Tajima as a relation for the work measured by an external macroscopic apparatus. The right-hand side of the equality reduces to unity for "natural" cyclic processes but fluctuates wildly for noncyclic ones, exceeding unity often. This fluctuation should be detectable in experiments and provide evidence for the present formulation.
Abstract A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-local thermal operations and reversibly operate in a one-step cycle. These engines are superior to the ones considered earlier in work extraction efficiency, and, even, are capable of converting heat into work by exclusively utilizing inter-system correlations. We formulate a resource theory for quantum heat engines to prove the results.
Heat engines constitute the major building blocks of modern technologies. However, conventional heat engines with higher power yield lesser efficiency and vice versa and respect various power-efficiency trade-off relations. This is also assumed to be true for the engines operating in the quantum regime. Here we show that these relations are not fundamental. We introduce quantum heat engines that deliver maximum power with Carnot efficiency in the one-shot finite-size regime. These engines are composed of working systems with a finite number of quantum particles and are restricted to one-shot measurements. The engines operate in a one-step cycle by letting the working system simultaneously interact with hot and cold baths via semilocal thermal operations. By allowing quantum entanglement between its constituents and, thereby, a coherent transfer of heat from hot to cold baths, the engine implements the fastest possible reversible state transformation in each cycle, resulting in maximum power and Carnot efficiency. Finally, we propose a physically realizable engine using quantum optical systems.
Thermodynamics is one of the main pillars of theoretical physics, and it has a special appeal of having wide applicability to a large variety of different physical systems. However, many assumptions in thermodynamics apply only to systems which are bulk material, i.e. consisting a large number of microscopic classical particles. Due to the advancement of designing nanoscale engines, especially in the light of devices that are used today in the processing of quantum information, is thermodynamics still applicable? Can we refine the core principles of thermodynamics to suit such nanoscale quantum systems as well? The central aim of this thesis is to construct a theory of thermodynamics that holds for nanoscale quantum systems, even those as small and simple as a single qubit. We do this by starting out from the core basics of quantum theory: unitary dynamics on closed quantum systems. We adapt a resource theoretic approach inspired by quantum information theory, which defines the quantum states and operations allowed to be used in a thermodynamic evolution. With this framework that naturally adopts the first law as an energy preserving condition, we show the refinement of both the zeroeth and second law of thermodynamics. The zeroeth law explains the physical significance of the Gibbs thermal state. On the other hand, we show that the second law sees refinement in the quantum nanoregime: instead of having the free energy as the sole quantity dictating the possibility of a thermodynamic state transition, we derive a family of generalized free energies that also constitute necessary conditions for a transition to occur. Moreover, these conditions become sufficient for states which are block-diagonal in the energy eigenbasis. In this thesis, we also brought our approach of thermodynamics to the next step: we apply our findings on the second laws, in order to analyze the maximum achievable efficiency for quantum heat engines. In classical thermodynamics, the Carnot efficiency has been long known as the theoretical maximum which does not depend on the specific structure of the thermal baths used, but only on its temperature. With the additional free energies we discover, we show that although quantum heat engines may achieve the Carnot efficiency, such an achievability is no longer independent of the Hamiltonians of the thermal baths. In other words, we find additional restrictions that surface in the study of quantum nanoscale heat engines, which are a direct consequence of the generalized second laws. This has provided us with a deeper understanding into the fundamental limitations of how efficient devices can be made in the realm of microscopic quantum systems.