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arXiv:1610.06316 · Physical review. E

Quantum Jarzynski equality of measurement-based work extraction

Yohei Morikuni, Hiroyasu Tajima, Naomichi Hatano

Published Mar 31, 2017• 16 citations
arXivHTMLPDF

Abstract

Many studies of quantum-size heat engines assume that the dynamics of an internal system is unitary and that the extracted work is equal to the energy loss of the internal system. Both assumptions, however, should be under scrutiny. In the present paper, we analyze quantum-scale heat engines, employing the measurement-based formulation of the work extraction recently introduced by Hayashi and Tajima [M. Hayashi and H. Tajima, arXiv:1504.06150]. We first demonstrate the inappropriateness of the unitary time evolution of the internal system (namely, the first assumption above) using a simple two-level system; we show that the variance of the energy transferred to an external system diverges when the dynamics of the internal system is approximated to a unitary time evolution. Second, we derive the quantum Jarzynski equality based on the formulation of Hayashi and Tajima as a relation for the work measured by an external macroscopic apparatus. The right-hand side of the equality reduces to unity for "natural" cyclic processes but fluctuates wildly for noncyclic ones, exceeding unity often. This fluctuation should be detectable in experiments and provide evidence for the present formulation.

DOI
10.1103/physreve.95.032147

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Many studies of quantum-size heat engines assume that the dynamics of an internal system is unitary and that the extracted work is equal to the energy loss of the internal system. Both assumptions, however, should be under scrutiny. In the present paper, we analyze quantum-scale heat engines, employing the measurement-based formulation of the work extraction recently introduced by Hayashi and Tajima [M. Hayashi and H. Tajima, arXiv:1504.06150]. We first demonstrate the inappropriateness of the unitary time evolution of the internal system (namely, the first assumption above) using a simple two-level system; we show that the variance of the energy transferred to an external system diverges when the dynamics of the internal system is approximated to a unitary time evolution. Second, we derive the quantum Jarzynski equality based on the formulation of Hayashi and Tajima as a relation for the work measured by an external macroscopic apparatus. The right-hand side of the equality reduces to unity for "natural" cyclic processes but fluctuates wildly for noncyclic ones, exceeding unity often. This fluctuation should be detectable in experiments and provide evidence for the present formulation.
There exist two formulations for quantum heat engines that model energy transfer between two microscopic systems. One is the semiclassical scenario and the other is the full quantum scenario. The former is formulated as unitary evolution for the internal system and is adopted by the statistical mechanics community. In the latter, the whole process is formulated as unitary and is adopted by the quantum information community. This paper proposes a model for quantum heat engines that transfer energy from a collection of microscopic systems to a macroscopic system like a fuel cell. In such a situation, the amount of extracted work is visible for a human. For this purpose, we formulate a quantum heat engine as the measurement process whose measurement outcome is the amount of extracted work. Under this model, we derive a suitable energy-conservation law and propose a more concrete submodel. Then we derive a trade-off relation between the measurability of the amount of work extraction and the coherence of the internal system, which limits the applicability of the semiclassical scenario to a heat engine transferring energy from a collection of microscopic systems to a macroscopic system.
There exist two formulations for quantum heat engine. One is semi-classical scenario, and the other is full quantum scenario. The former is formulated as a unitary evolution for the internal system (working body and heat baths), and is adopted by the community of statistical mechanics. The latter is formulated as a unitary for the work storage and the internal system. It is adopted by the community of quantum information. However, these formulations do not consider measurement process. In this paper, we formulate the quantum heat engine based on the quantum measurement theory, because the amount of extracted work should be observed in a practical situation. With using our formulation, we derive two trade-off relations that show the semi-classical scenario does not work when the amount of extracted work is observed, i.e., we can hardly know the amount of the extracted work when the time evolution of the internal system is close to unitary. Next, based on our formulation, we derive the optimal efficiency of quantum heat engines with the finite-size heat baths, without assuming the existence of quasi-static processes. Using the strong large deviation theory, we asymptotically expand the optimal efficiency up to the third order. The first term is shown to be Carnot efficiency, and the higher order terms are shown to be the finite-size effects of the heat baths. We can construct the optimal work extraction as an energy-preserving unitary evolution among the internal system and the work storage. During the optimal work extraction, the entropy gain of the work storage is so negligibly small as compared with the energy gain of the work storage.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.
The optimal efficiency of quantum (or classical) heat engines whose heat baths are n-particle systems is given by the strong large deviation. We give the optimal work extraction process as a concrete energy-preserving unitary time evolution among the heat baths and the work storage. We show that our optimal work extraction turns the disordered energy of the heat baths to the ordered energy of the work storage, by evaluating the ratio of the entropy difference to the energy difference in the heat baths and the work storage, respectively. By comparing the statistical mechanical optimal efficiency with the macroscopic thermodynamic bound, we evaluate the accuracy of the macroscopic thermodynamics with finite-size heat baths from the statistical mechanical viewpoint. We also evaluate the quantum coherence effect on the optimal efficiency of the cycle processes without restricting their cycle time by comparing the classical and quantum optimal efficiencies.
We study the work fluctuations in ergotropic heat engines, namely two-stroke quantum Otto engines where the work stroke is designed to extract the ergotropy (the maximum amount of work by a cyclic unitary evolution) from a couple of quantum systems at canonical equilibrium at two different temperatures, whereas the heat stroke thermalizes back the systems to their respective reservoirs. We provide an exhaustive study for the case of two qutrits whose energy levels are equally spaced at two different frequencies by deriving the complete work statistics. By varying the values of temperatures and frequencies, only three kinds of optimal unitary strokes are found: the swap operator U1, an idle swap U2 (where one of the qutrits is regarded as an effective qubit), and a non-trivial permutation of energy eigenstates U3, which indeed corresponds to the composition of the two previous unitaries, namely U3=U2U1. While U1 and U2 are Hermitian (and hence involutions), U3 is not. This point has an impact on the thermodynamic uncertainty relations (TURs), which bound the signal-to-noise ratio of the extracted work in terms of the entropy production. In fact, we show that all TURs derived from a strong detailed fluctuation theorem are violated by the transformation U3.
Work is an important quantity in thermodynamics. In a closed quanutm system, the two-point energy measurements can be applied to measure the work but cannot be utilized in an open quantum system. With the two-point energy measurements, it has been shown that the work fluctuation satisfies the Jarzynski equality. We propose a scheme to measure the work in an open quantum system through the technique of reservoir engineering. Based on this scheme, we show that the work fluctuation in open quantum system may violate the Jarzynski equality. We apply our scheme to a two-level atom coupled to an engineered reservoir and numerically justify the general results, especially demonstrating that the second law of thermodynamics can be violated.