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Springer series in synergetics

Quantum and Classical Statistical Mechanics of the Non-Linear Schrödinger, Sinh-Gordon and Sine-Gordon Equations

R. Bullough, D. J. Pilling, JUSSI TIMONEN

Published Jan 1, 1985• 6 citations
Publisher
DOI
10.1007/978-3-662-02449-2_16

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arXiv:cond-mat/9707222•Physical Review Letters•Nov 17, 1997•44 citations
We give two fundamental methods for evaluation of classical free energies of all the integrable models admitting soliton solutions; the sine-Gordon equation is one example. Periodic boundary conditions impose integral equations for allowed phonon and soliton momenta. From these, generalized Bethe-Ansatz and functional-integration methods using action-angle variables follow. Results for free energies coincide, and coincide with those that we find by transfer-integral methods. Extension to the quantum case, and quantum Bethe Ansatz, on the lines to be reported elsewhere for the sinh-Gordon equation, is indicated.
The calculation of the equilibrium free energy of integrable models like the sine-Gordon and attractive nonlinear Schrödinger models is discussed in the context of biological molecules like DNA : the thermalisation process (approach to equilibrium) is also discussed. The sine-Gordon model has a "repulsive" form which is the sinh-Gordon model. The approach to equilibrium of the sinh-Gordon model is described in all completeness in terms of a quantum mechanical master equation at finite temperatures. Although the dynamical evolution of the master equation as written is a solved problem, only the equilibrium solution is examined in this paper. The equilibrium free energy is calculated exactly as an integral equation for certain excitation energies at finite temperatures. Bose-fermi equivalent forms of this integral equation are given. The bose form yields a similar integral equation in classical limit. The iteration of this yields a low temperature asymptotic series for the classical free energy which checks against the result of the transfer integral method (TIM). Results for the zero temperature quantum eigenenergies are found. A further discussion of the dynamics of the approach to thermal equilbrium is made.
We study the classical thermodynamics of a (1+1)(1+1)(1+1)-dimensional double-well sinh-Gordon theory. Remarkably, the Schr\"odinger-like equation resulting from the transfer integral method is quasi-exactly solvable at several temperatures. This allows exact calculation of the partition function and some correlation functions above and below the short-range order (``kink'') transition, in striking agreement with high resolution Langevin simulations. Interesting connections with the Landau-Ginzburg and double sine-Gordon models are also established.