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Physical Review Letters

Statistical Mechanics of the Sine-Gordon Equation

JUSSI TIMONEN, M. Stirland, D. J. Pilling, Yi Cheng, R. Bullough

Published May 26, 1986• 70 citations
Publisher

Abstract

We give two fundamental methods for evaluation of classical free energies of all the integrable models admitting soliton solutions; the sine-Gordon equation is one example. Periodic boundary conditions impose integral equations for allowed phonon and soliton momenta. From these, generalized Bethe-Ansatz and functional-integration methods using action-angle variables follow. Results for free energies coincide, and coincide with those that we find by transfer-integral methods. Extension to the quantum case, and quantum Bethe Ansatz, on the lines to be reported elsewhere for the sinh-Gordon equation, is indicated.

DOI
10.1103/physrevlett.56.2233

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We give two fundamental methods for evaluation of classical free energies of all the integrable models admitting soliton solutions; the sine-Gordon equation is one example. Periodic boundary conditions impose integral equations for allowed phonon and soliton momenta. From these, generalized Bethe-Ansatz and functional-integration methods using action-angle variables follow. Results for free energies coincide, and coincide with those that we find by transfer-integral methods. Extension to the quantum case, and quantum Bethe Ansatz, on the lines to be reported elsewhere for the sinh-Gordon equation, is indicated.
We use the quantum Bethe-Ansatz method to compute the free energy of the classical sine-Gordon system. Previous attempts to do this have failed because the number of coupled integral equations to be solved to find the free-energy diverges in the classical limit. We present a transformation, extending a method of Maki, which reduces this divergent set to only two coupled equations, for the densities of solitons and anharmonic phonons. These equations can be solved iteratively in the temperature ttt and the soliton density ${e}^{\frac{\ensuremath{-}1}{t}}$ to give a double series for the free energy. This series coincides to high order with classical transfer-matrix results.
We use the quantum Bethe ansatz method to compute the free energy of the sine-Gordon model in the classical limit. In this limit the number of breathers, and hence the number of coupled integral equations to be solved, diverges. By linearizing the breather mass spectrum and phase shifts, extending a method of Maki, we can reduce the breather ladder to anharmonic phonons. The divergent set of integral equations is reduced to only two, for interacting phonons and solitons. We solve these equations iteratively to give the free energy in a double series in the temperature t and the soliton density ${e}^{\mathrm{\ensuremath{-}}1/t}$ which agrees to high order with classical transfer integral results.
The calculation of the equilibrium free energy of integrable models like the sine-Gordon and attractive nonlinear Schrödinger models is discussed in the context of biological molecules like DNA : the thermalisation process (approach to equilibrium) is also discussed. The sine-Gordon model has a "repulsive" form which is the sinh-Gordon model. The approach to equilibrium of the sinh-Gordon model is described in all completeness in terms of a quantum mechanical master equation at finite temperatures. Although the dynamical evolution of the master equation as written is a solved problem, only the equilibrium solution is examined in this paper. The equilibrium free energy is calculated exactly as an integral equation for certain excitation energies at finite temperatures. Bose-fermi equivalent forms of this integral equation are given. The bose form yields a similar integral equation in classical limit. The iteration of this yields a low temperature asymptotic series for the classical free energy which checks against the result of the transfer integral method (TIM). Results for the zero temperature quantum eigenenergies are found. A further discussion of the dynamics of the approach to thermal equilbrium is made.
The generalized Bethe-ansatz method of thermodynamic analysis of integrable systems was employed to compute the free energy of a classical integrable model,i.e.the Landau-Lifshitz model.Using the action-angle variables of the model and by imposing a periodic boundary condition.we derive a phase-shifted density of states for the excitations of the system.The free energy,in the thermodynamic limit,can be expressed analytic in terms of two coupled nonlinear integral equations of the finie temperature excited energy for effective phonons and kinks (antikinks).we solve these equations iteratively for a special case that the model is in the limit of anisotropic strong yz coupling.