Emergence of thermodynamic properties in quantum pure states II. Analysis of a spin model system

Masanori Ohya, Dėnes Petz

Barbara Fresch, Giorgio J. Moro

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and of the equilibrium reduced density matrix of a subsystem for the two different statistics introduced in Part I. In order to analyze their consistency with thermodynamics, these quantities of interest are evaluated in the limit of large number of components of the isolated system. The main results can be summarized as follows: typical values of the entropy and of the equilibrium reduced density matrix as functions of the internal energy in the fixed expectation energy ensemble do not satisfy the requirement of thermodynamics. On the contrary, the thermodynamical description is recovered from the random pure state ensemble (RPSE), provided that one considers systems large enough. The thermodynamic limit of the considered properties for the spin system reveals a number of important features. First canonical statistics (and thus, canonical typicality as long as the fluctuations around the average value are small) emerges without the need of assuming the microcanonical space for the global pure state. Moreover, we rigorously prove (i) the equivalence of the "global temperature," derived from the entropy equation of state, with the "local temperature" determining the canonical state of the subsystems; and (ii) the equivalence between the RPSE typical entropy and the canonical entropy for the overall system.

Samuel Sitotaw, Rostislav A. Serota

Eduardo Carlo Mascarenhas Moraes

In this thesis we study collective, emergent and optical properties of interacting quantum systems both in equilibrium and nonequilibrium situations from a microscopic modelling. This orientation steams from both the fact there is a profound need to design, characterise and set up control strategies for realistic systems in which quantum technologies could be conceived and the interest to grasp and identify fundamental principles for the emergence of macroscopic behaviour. The thesis is divided into three parts: I Optical and Collective Phenomena; II Equilibrium many-body systems and III Nonequilibrium many-body systems. Part I includes four complementary contributions to the optics emerging from the collective behaviour of microscopic quantum systems. In part II (Equilibrium many-body systems) of the thesis I have addressed the physics of quantum phase transitions from the perspective of nonequilibrium thermodynamics. We have shown that such an approach captures the essential features of finite order transitions that have a strong connection to thermodynamical and energetic figures of merit, but does not capture infinite order transitions that are of a much more subtle nature. Motivated by these exotic infinite order transitions we have looked at quantum phases and phase transitions through an informational and operational perspective based on pure state conversions restricted by local operations. In the third and last part (Nonequilibrium many-body systems) of the thesis I have laid out a project on the closed evolution of quantum spin chains focussing on the emergent nonequilibrium laws that depart from equilibrium physics.

G. Waldherr, G. Mahler

Closed weakly bound bipartite quantum systems typically exhibit relaxation behavior with respect to the smaller subsystem. Here, we investigate a model composed of a finite spin network with one interfacing spin being coupled to a single electromagnetic field mode via the Jaynes-Cummings interaction. The initial pure state of the system can be chosen such that the resulting thermodynamical relaxation process is lasing/nonlasing relaxation or energy back flow from the field mode. We examine the properties of the field mode with quantum optical methods. During the lasing process, the field mode is in a phase-diffused Glauber state with no optical coherence. The thermodynamical analysis of our system is consistent with this finding: The total energy exchanged between both subsystems is found to be heat only. Yet the mapping of this function onto a thermodynamic heat engine appears to be of limited value.

Alessandro Cuccoli, V. Tognetti, Ruggero Vaia +1 more