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Physica

The three-body collision operator in quantum mechanics

Pierre M. V. Résibois

Published Sep 1, 1966• 13 citations
Publisher
DOI
10.1016/0031-8914(66)90031-0

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The relationship between the collision kernel of the three-body quantum mechanical kinetic equation (quantum version of the Choh-Uhlenbeck equation) and modern scattering theory is examined utilizing the work of Faddeev and Weinberg. Recognizing that the collision kernel is related to the M⊘ller scattering operator it is shown that the collision kernel is “well-defined” for suitable interaction potentials and contains only connected three particle collisions in the sense of Weinberg. The collision kernel is interpreted physically and is shown to contain a generalization of the ordinary Boltzmann collision term to three particle processes plus a distorted-wave-impulse approximation correction to the two particle Boltzmann collision term.
We study the collisional processes that can lead to thermalization in one-dimensional (1D) systems. For two-body collisions, excitations of transverse modes are the prerequisite for energy exchange and thermalization. At very low temperatures, excitations of transverse modes are exponentially suppressed, thermalization by two-body collisions stops and the system should become integrable. In quantum mechanics, virtual excitations of higher radial modes are possible. These virtually excited radial modes give rise to effective three-body velocity-changing collisions, which lead to thermalization. We show that these three-body elastic interactions are suppressed by pairwise quantum correlations when approaching the strongly correlated regime. If the relative momentum k is small compared with the two-body coupling constant c , the three-particle scattering state is suppressed by a factor of ( k / c ) 12 , which is proportional to γ −12 , that is, to the square of the three-body correlation function at zero distance in the limit of the Lieb–Liniger parameter γ≫1. This demonstrates that in 1D quantum systems, it is not the freeze-out of two-body collisions but the strong quantum correlations that ensure absence of thermalization on experimentally relevant time scales.