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AIP conference proceedings

Quantum Fluctuation Dissipation Relations and the Second Law

Yury Klimontovich

Published Jan 1, 2002• 0 citations
Publisher

Abstract

The fluctuation‐dissipation relations (FDR) are studied at all levels of the statistical description. The most general FDR are the relations for the fluctuations of many‐body distribution functions. In all cases it is in agreement with the second law of thermodynamics.
DOI
10.1063/1.1523773

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The fluctuation-dissipation relations (FDR) in physical systems are studied at all levels of the statistical description. The most general FDR are the relations for the fluctuations of many-body distribution functions. It is pointed out the problem of formulation of FDR is related to the problem of deriving irreversible equations based on the reversible equations of classical and quantum mechanics. The FDR are divided into two classes: 1) FDR for fluctuations with infinite correlation times (collisionless approximation), which correspond to infinitely narrow resonances, and 2) FDR for fluctuations with finite correlation times (collisional approximation). The corresponding spectral densities have finite widths, determined by the collision integrals. The fundamental questions about which different viewpoints have been published in the literature are critically analyzed: 1) the limits of applicability of the Callen-Welton formula and 2) the quantum generalization of Nyquist's formula for the intensity of a Langevin source of oscillatory systems. It is shown that the traditional form of the quantum Nyquist formula, is not well-founded and leads to unphysical consequences. A different expression, used in the literature, for the quantum Nyquist formula is examined. It is not universal, but holds in many important cases. Its region of applicability is determined by the corresponding quantum kinetic equations. The consequences of the two forms of the quantum Nyquist formula, which can be checked experimentally, are studied. The question of the formulation of the quantum Nyquist formula is studied as a part of the general problem of determining the intensity of a Langevin source and the corresponding diffusion coefficient in quantum systems. It arises, in particular, also in quantum electrodynamics in the calculation of the Lamb shift (Sec. 12). In this connection two derivations of Bethe's formula for the Lamb shift are analyzed. It is established that the subtraction formalism of quantum electrodynamics corresponds to the nontraditional form of the quantum Nyquist formula. The exposition is illustrated with many specific examples.
The generalized Langevin equation and its attendant fluctuation–dissipation relation (FDR) for both classical and quantum systems is explictly derived for a large class of system-bath interaction potentials. We demonstrate for this class of potentials that the classical FDR involving only the temperature of the bath is satisfied, and that in general the decay times of the dissipative processes and of the system are temperature dependent. We also demonstrate that the quantum FDR depends in detail on the nature of the bath and on the specific system-bath interaction. Thus we conclude that while the classical Langevin equation is phenomenologically useful, its quantum counterpart is much more limited.
An important result in classical stochastic thermodynamics is the work fluctuation-dissipation relation (FDR), which states that the dissipated work done along a slow process is proportional to the resulting work fluctuations. We show that slowly driven quantum systems violate this FDR whenever quantum coherence is generated along the protocol, and we derive a quantum generalization of the work FDR. The additional quantum terms in the FDR are found to lead to a non-Gaussian work distribution. Fundamentally, our result shows that quantum fluctuations prohibit finding slow protocols that minimize both dissipation and fluctuations simultaneously, in contrast to classical slow processes. Instead, we develop a quantum geometric framework to find processes with an optimal trade-off between the two quantities.
Continuing our work on the nature and existence of fluctuation-dissipation relations (FDR) in linear and nonlinear open quantum systems [J.-T. Hsiang, B. L. Hu, and S.-Y. Lin, Phys. Rev. D 100, 025019 (2019); J.-T. Hsiang, B. L. Hu, S.-Y. Lin, and K. Yamamoto, Phys. Lett. B 795, 694 (2019); J.-T. Hsiang and B. L. Hu, Physics (Utrecht) 1, 430 (2019); J.-T. Hsiang and B. L. Hu, Phys. Rev. D 101, 125003 (2020)], here we consider such relations when a linear system is in a nonequilibrium steady state (NESS). With the model of two-oscillators (considered as a short harmonic chain with the two ends) each connected to a thermal bath of different temperatures we find that when the chain is fully relaxed due to interaction with the baths, the relation that connects the noise kernel and the imaginary part of the dissipation kernel of the chain in one bath does not assume the conventional form for the FDR in equilibrium cases. There exists an additional term we call the ``bias current'' that depends on the difference of the bath's initial temperatures and the interoscillator coupling strength. We further show that this term is related to the steady heat flow between the two baths when the system is in an NESS. The ability to know the real-time development of the interheat exchange (between the baths and the end-oscillators) and the intraheat transfer (within the chain) and their dependence on the parameters in the system offers possibilities for quantifiable control, and in the design of quantum heat engines, or thermal devices.