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arXiv:1911.04306 · Physical Review Research

Quantum work statistics close to equilibrium

Matteo Scandi, Harry J. D. Miller, Janet Anders, Martí Perarnau-Llobet

Published Jun 22, 2020• 83 citations
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Abstract

The authors identify quantum signatures in thermodynamic protocols in the linear response regime; these manifest in the form of non-Gaussian work distributions and modified fluctuation dissipation relations.
DOI
10.1103/physrevresearch.2.023377

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We consider a quantum system driven out of equilibrium via a small Hamiltonian perturbation. Building on the paradigmatic framework of linear response theory (LRT), we derive an expression for the full generating function of the dissipated work. Remarkably, we find that all information about the distribution can be encoded in a single quantity, the standard relaxation function in LRT, thus opening up new ways to use phenomenological models to study nonequilibrium fluctuations in complex quantum systems. Our results establish a number of refined quantum thermodynamic constraints on the work statistics that apply to regimes of perturbative but arbitrarily fast protocols, and do not rely on assumptions such as slow driving or weak coupling. Finally, our approach uncovers a distinctly quantum signature in the work statistics that originates from underlying zero-point energy fluctuations. This causes an increased dispersion of the probability distribution at short driving times, a feature that can be probed in efforts to witness nonclassical effects in quantum thermodynamics.
An important result in classical stochastic thermodynamics is the work fluctuation-dissipation relation (FDR), which states that the dissipated work done along a slow process is proportional to the resulting work fluctuations. We show that slowly driven quantum systems violate this FDR whenever quantum coherence is generated along the protocol, and we derive a quantum generalization of the work FDR. The additional quantum terms in the FDR are found to lead to a non-Gaussian work distribution. Fundamentally, our result shows that quantum fluctuations prohibit finding slow protocols that minimize both dissipation and fluctuations simultaneously, in contrast to classical slow processes. Instead, we develop a quantum geometric framework to find processes with an optimal trade-off between the two quantities.