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Springer series in optical sciences/SPringer series in optical sciences

Light-Assisted Collisional Energy Transfer

Ph. Cahuzac, P. E. Toschek

Published Jan 1, 1977• 3 citations
Publisher
DOI
10.1007/978-3-540-35968-5_56

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Microwave-assisted resonant collisional energy transfer process $\mathrm{Na}(\mathrm{ns})+\mathrm{Na}(\mathrm{ns})+h\ensuremath{\nu}\ensuremath{\rightarrow}\mathrm{Na}(\mathrm{np})+\mathrm{Na}((n\ensuremath{-}1)p)$ is observed between two colliding $\mathrm{Na}(\mathrm{ns})$ atoms. The collisional resonance occurs when the microwave frequency $\ensuremath{\nu}$ equals the collisional energy defect $\frac{\ensuremath{\Delta}W}{h}$. The observed cross sections are very large (\ensuremath{\sim}${10}^{8}$ ${\mathrm{\AA{}}}^{2}$) and require very low microwave power, \ensuremath{\sim}10 W/${\mathrm{cm}}^{2}$. These observations are in good agreement with an intuitive two-photon absorption model for these collisions.

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Generation of magnetic-state polarization in light-induced collisional energy transfer: Weak-field, quasistatic-wing limit

P. R. Berman, F. Schuller, Gerard Nienhuis

A reaction of the form Ai+Ai\ensuremath{'}\ensuremath{'}+\ensuremath{\Elzxh}\ensuremath{\Omega}\ensuremath{\rightarrow}Af+Af\ensuremath{'}\ensuremath{'} has been referred to as light-induced collisional energy transfer (LICET). In such a reaction, atoms A and A\ensuremath{'} collide in the presence of a radiation field and absorb a photon during the collision, taking them from initial states (Ai,Ai\ensuremath{'}\ensuremath{'}) to different final states (Af,Af\ensuremath{'}\ensuremath{'}). We calculate the final-state magnetic polarization produced in LICET for detunings \ensuremath{\Delta}=[(Ef+Ef\ensuremath{'})-(Ei+Ei\ensuremath{'}+\ensuremath{\Elzxh}\ensuremath{\Omega})]/\ensuremath{\Elzxh} in the quasistatic wing: that is, for |\ensuremath{\Delta}|\ensuremath{\tau}c\ensuremath{\gg}1, where \ensuremath{\tau}c is the collision duration. Our results are compared with analogous depolarization rates for so-called ``optical'' collisions (reactions of the form Ai+Ai\ensuremath{'}\ensuremath{'}+\ensuremath{\Elzxh}\ensuremath{\Omega}\ensuremath{\rightarrow}Ai+Af\ensuremath{'}\ensuremath{'}). Similarities and differences between the LICET and ``optical'' collision theories are noted. Final-state LICET magnetic-state polarization is evaluated for a number of different A-A\ensuremath{'} level schemes, assuming a dipole-dipole collisional interaction. Our results are shown to be in good agreement with experiment [A. D\'ebarre, J. Phys. B 15, 1693 (1982)].

Physical Review A•Jul 1, 1990•9 citations

High-resolution study of light-induced collisional energy transfer in Na-Ca mixture

Anne Débarre

The experimental study of a laser-induced energy transfer for a dipole-dipole collisional interaction in a Na-Ca mixture is reported. A specific excitation scheme is used in this experiment for which the virtual level is optically excited. A comparison with the case of a dipole-dipole interaction in the Eu-Sr mixture where the virtual level is excited by collisional energy transfer is presented.

Journal of Physics B Atomic and Molecular Physics•Feb 14, 1983•29 citations
Microwave-assisted resonant collisional energy transfer process $\mathrm{Na}(\mathrm{ns})+\mathrm{Na}(\mathrm{ns})+h\ensuremath{\nu}\ensuremath{\rightarrow}\mathrm{Na}(\mathrm{np})+\mathrm{Na}((n\ensuremath{-}1)p)$ is observed between two colliding Na(ns)\mathrm{Na}(\mathrm{ns})Na(ns) atoms. The collisional resonance occurs when the microwave frequency $\ensuremath{\nu}$ equals the collisional energy defect $\frac{\ensuremath{\Delta}W}{h}$. The observed cross sections are very large (\ensuremath{\sim}108{10}^{8}108 A˚2{\mathrm{\AA{}}}^{2}A˚2) and require very low microwave power, \ensuremath{\sim}10 W/cm2{\mathrm{cm}}^{2}cm2. These observations are in good agreement with an intuitive two-photon absorption model for these collisions.
A reaction of the form Ai+Ai\ensuremath{'}\ensuremath{'}+\ensuremath{\Elzxh}\ensuremath{\Omega}\ensuremath{\rightarrow}Af+Af\ensuremath{'}\ensuremath{'} has been referred to as light-induced collisional energy transfer (LICET). In such a reaction, atoms A and A\ensuremath{'} collide in the presence of a radiation field and absorb a photon during the collision, taking them from initial states (Ai,Ai\ensuremath{'}\ensuremath{'}) to different final states (Af,Af\ensuremath{'}\ensuremath{'}). We calculate the final-state magnetic polarization produced in LICET for detunings \ensuremath{\Delta}=[(Ef+Ef\ensuremath{'})-(Ei+Ei\ensuremath{'}+\ensuremath{\Elzxh}\ensuremath{\Omega})]/\ensuremath{\Elzxh} in the quasistatic wing: that is, for |\ensuremath{\Delta}|\ensuremath{\tau}c\ensuremath{\gg}1, where \ensuremath{\tau}c is the collision duration. Our results are compared with analogous depolarization rates for so-called ``optical'' collisions (reactions of the form Ai+Ai\ensuremath{'}\ensuremath{'}+\ensuremath{\Elzxh}\ensuremath{\Omega}\ensuremath{\rightarrow}Ai+Af\ensuremath{'}\ensuremath{'}). Similarities and differences between the LICET and ``optical'' collision theories are noted. Final-state LICET magnetic-state polarization is evaluated for a number of different A-A\ensuremath{'} level schemes, assuming a dipole-dipole collisional interaction. Our results are shown to be in good agreement with experiment [A. D\'ebarre, J. Phys. B 15, 1693 (1982)].