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Bulletin of the American Physical Society

Long-range interactions between three P-state atoms in a magnetic field

Sergey Alyabyshev, Roman V. Krems

Published Jun 8, 2007• 0 citations
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Alkaline-earth-metal atoms in their lowest (nsnp)(\mathrm{nsnp})(nsnp) 3P2{}^{3}{P}_{2}3P2​ state are exceptionally long lived and can be trapped magnetically. The nonspherical atomic structure leads to anisotropic long-range interactions between two metastable alkaline-earth-metal atoms. The anisotropy affects the rotational motion of the diatomic system and couples states of different rotational quantum numbers. This paper develops a tensorial decomposition of the most important long-range interaction operators, and a systematic inclusion of molecular rotations, in the presence of an external magnetic field. This analysis illuminates the nature of the coupling between the various degrees of freedom. The consequences are illustrated by application to a system of practical interest: metastable 88Sr.{}^{88}\mathrm{Sr}.88Sr. Using atomic parameters determined in a nearly ab initio calculation, we compute adiabatic potential-energy curves. The anisotropic interatomic interaction, in combination with the applied magnetic field, is demonstrated to induce the formation of a long-range molecular potential well. This curve correlates to two fully polarized, low-field seeking atoms in a rotational s-wave state. The coupling among molecular rotational states controls the existence of the potential well, and its properties vary as a function of magnetic-field strength, thus allowing the scattering length in this state to be tuned. The scattering length of metastable 88Sr{}^{88}\mathrm{Sr}88Sr displays a resonance at a field of 339 G.
Ultracold collisions of spin-polarized 24Mg, 40Ca, and 88Sr in the metastable 3P2 excited state are investigated based on molecular potentials obtained from ab initio calculations. We calculate the long-range interaction potentials and estimate the scattering length and the collisional loss rate as a function of magnetic field. The scattering lengths show resonance behavior due to the appearance of a molecular bound state in a purely long-range interaction potential and are positive for magnetic fields below 50 mT. A loss-rate model shows that losses should be smallest near zero magnetic field and for fields slightly larger than the resonance field, where the scattering length is also positive.
We investigate long-range pairing interactions between ultracold fermionic atoms confined in an optical lattice which are mediated by the coupling to a cavity. In the absence of other perturbations, we find three degenerate pairing symmetries for a two-dimensional square lattice. By tuning a weak local atomic interaction via a Feshbach resonance or by tuning a weak magnetic field, the superfluid system can be driven from a topologically trivial s wave to topologically ordered, chiral superfluids containing Majorana edge states. Our work points out a novel path towards the creation of exotic superfluid states by exploiting the competition between long-range and short-range interactions.
We use superconducting qubit quantum annealing devices to determine the ground state of Ising models with algebraically decaying competing long-range interactions in the thermodynamic limit. This is enabled by a unit-cell-based optimization scheme, in which the finite optimizations on each unit cell are performed using commercial quantum annealing hardware. To demonstrate the capabilities of the approach, we choose three exemplary problems relevant for other quantum simulation platforms and material science: (i) the calculation of devil's staircases of magnetization plateaux of the long-range Ising model in a longitudinal field on the triangular lattice, motivated by atomic and molecular quantum simulators; (ii) the evaluation of the ground state of the same model on the Kagome lattice in the absence of a field, motivated by artificial spin ice metamaterials; (iii) the study of models with additional few-nearest-neighbor interactions relevant for frustrated Ising compounds with potential long-range interactions. The approach discussed in this work provides a useful and realistic application of existing quantum annealing technology, applicable across many research areas in which lattice problems with resummable long-range interactions are relevant.