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Quantum interferometry with complex molecules

Markus Arndt, Klaus Hornberger

Published Mar 9, 2009• 10 citations
Publisher

Abstract

Summary. — This chapter reviews recent experiments on matter wave interferometry with large molecules. Starting from an elementary introduction to matter wave physics we discuss far-field diffraction and near-field interferometry with thermally excited many-body systems. We describe the constraints imposed by decoherence and dephasing effects, and present an outlook to the future challenges in macromolecule and cluster interferometry. PACS 03.75.-b – Matter waves. 1. – Historical introduction and overview The year 1923 is generally considered as the year of birth of matter wave physics. It is the year when Louis de Broglie proposed the idea that each material particle is accompanied by an oscillatory phenomenon [1]. De Broglie based his hypothesis on two discoveries: the energy-frequency equivalence for photons, E = ¯hω, and the energy-mass equivalence for matter, E = mc 2. While the first relation had already been central to Planck’s explanation of the black body spectrum [2] and to Einstein’s analysis of the photo effect [3], the latter was a consequence of Einstein’s theory of special relativity.

DOI
10.3254/978-1-60750-039-1-103

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Summary. — This chapter reviews recent experiments on matter wave interferometry with large molecules. Starting from an elementary introduction to matter wave physics we discuss far-field diffraction and near-field interferometry with thermally excited many-body systems. We describe the constraints imposed by decoherence and dephasing effects, and present an outlook to the future challenges in macromolecule and cluster interferometry. PACS 03.75.-b – Matter waves. 1. – Historical introduction and overview The year 1923 is generally considered as the year of birth of matter wave physics. It is the year when Louis de Broglie proposed the idea that each material particle is accompanied by an oscillatory phenomenon [1]. De Broglie based his hypothesis on two discoveries: the energy-frequency equivalence for photons, E = ¯hω, and the energy-mass equivalence for matter, E = mc 2. While the first relation had already been central to Planck’s explanation of the black body spectrum [2] and to Einstein’s analysis of the photo effect [3], the latter was a consequence of Einstein’s theory of special relativity.
Recent progress and future prospects of matter-wave interferometry with complex organic molecules and inorganic clusters are reviewed. Three variants of a near-field interference effect, based on diffraction by material nanostructures, at optical phase gratings, and at ionizing laser fields are considered. The theoretical concepts underlying these experiments and the experimental challenges are discussed. This includes optimizing interferometer designs as well as understanding the role of decoherence. The high sensitivity of matter-wave interference experiments to external perturbations is demonstrated to be useful for accurately measuring internal properties of delocalized nanoparticles. The prospects for probing the quantum superposition principle are investigated in the limit of high particle mass and complexity.
Louis de Broglie's discovery of the wave nature of matter 80 years ago and the subsequent development of quantum mechanics by Erwin Schrodinger, Werner Heisenberg and Paul Dirac solved many riddles of those days and determined physics of the whole 20th century. Yet, after this long time, matter wave interferometry is as up to date as it was in 1927 when Louis de Broglie's hypothesis was verified, e.g., by Davisson and Germer. Atom interferometry, ion interferometry and Bose-Einstein condensates are today's fascinating applications based on de Broglie's discovery. The focus of the present contribution are Hanbury Brown-Twiss anti-correlations (i.e. interferences between two fermions (electrons)) and the quantitative observation of decoherence by electron biprism interferometry.
We discuss new de Broglie coherence experiments in a near-field molecule interferometer with a variety of large organic molecules. While de Broglie coherence is to first order only associated with the center-of-mass motion of the diffracted particle, we here investigate the question as to which extent the internal molecular property is relevant for, compatible with or detrimental for maintaining coherence in the translational degree of freedom. External perturbations, such as inhomogeneous external electric fields, may influence the delocalized molecules inside the matter wave interferometer and they allow us to access the molecular polarizabilities, permanent or even fluctuating electric dipole moments. We extract information about the molecular states from the interference phase shifts as well as from the observed dephasing in a Kapitza-Dirac Talbot-Lau-Stark-deflectometer. We discuss the relevance of our experiments with regard to both molecule metrology and the foundations of quantum mechanics, i.e. the preservation of coherence for highly complex particles in external fields.
We describe the state of the art in preparing, manipulating and detecting coherent molecular matter. We focus on experimental methods for handling the quantum motion of compound systems from diatomic molecules to clusters or biomolecules.Molecular quantum optics offers many challenges and innovative prospects: already the combination of two atoms into one molecule takes several well-established methods from atomic physics, such as for instance laser cooling, to their limits. The enormous internal complexity that arises when hundreds or thousands of atoms are bound in a single organic molecule, cluster or nanocrystal provides a richness that can only be tackled by combining methods from atomic physics, chemistry, cluster physics, nanotechnology and the life sciences.We review various molecular beam sources and their suitability for matter-wave experiments. We discuss numerous molecular detection schemes and give an overview over diffraction and interference experiments that have already been performed with molecules or clusters.Applications of de Broglie studies with composite systems range from fundamental tests of physics up to quantum-enhanced metrology in physical chemistry, biophysics and the surface sciences.Nanoparticle quantum optics is a growing field, which will intrigue researchers still for many years to come. This review can, therefore, only be a snapshot of a very dynamical process.
The wave-particle duality is a key concept of quantum physics and extending quantum superpositions to bodies of increasing mass and complexity has become a key goal to numerous research groups. Such experiments are motivated by the desire to probe and better understand the quantum-classical interface in advanced tests of spontaneous or gravity-induced wave function collapse and in the search for non-linear modifications of quantum theory. High mass interferometry has been proposed to serve in the search for light dark matter via weak recoil decoherence as well as in tests of the weak equivalence principle by comparing a large variety of quantum systems with very distinct internal composition, excitation, mass, shape or angular momentum. Here we discuss the experimental state of the art in high-mass matter-wave interferometry, as well as new perspectives from cluster and nanoparticle physics to push quantum superpositions by 3 to 4 orders of magnitude in mass or up to 6 orders of magnitude in 'macroscopicity'. We discuss different near-field interferometer configurations that shall become useful in near-future demonstrations of quantum phenomena with objects as diverse as proteins, metal clusters and dielectric nanoparticles.