Chapter 18 Quantum Dynamics of States

Seogjoo Jang

Gennaro Auletta, Mauro Fortunato, Giorgio Parisi A

In this chapter we shall deal with the quantum dynamics of an open system. By open quantum system we mean here a system which interacts with an environment (see Sec. 9.4): since we are not interested in the dynamics of the environment, we shall have to describe the evolution of the system in some “effective” way. In particular, if we consider only the evolution of the system, it will be non-unitary, and this will represent the subject of this chapter. As we know, Hamiltonian quantum dynamics is unitary and changes pure states into pure states. On the other hand, non-unitary dynamics changes an initially pure state into a mixture, which must be described by a density matrix (see Ch. 5). In the case of macroscopic systems, the coupling with the environment may be arbitrarily reduced and therefore its influence can be made correspondingly small (see Sec. 1.1). Microscopic systems, however, always couple to the environment and this coupling cannot be considered negligible. This is the reason why the quantum theory of open systems is one of the most important and fundamental chapters of quantum mechanics that, though born in quantum optics, has many implications in almost all fields of physics. The present chapter can be seen as a further development of the measurement theory (see Ch. 9), as open systems manifest a decoherent dynamics (see in particular Sec. 9.4).

Jørgen Rammer

In the previous chapter we studied the kinematics of many-body systems, and the form of operators representing the physical properties of a system, all of which were embodied by the quantum field. In this chapter we shall study the quantum dynamics of many-body systems, which can also be embodied by the quantum fields. We shall employ the fact that the quantum dynamics of a system, instead of being described in terms of the dynamics of the states or the evolution operator, i.e. as previously done through the Schrödinger equation, can instead be carried by the quantum fields. The quantum dynamics is therefore expressed in terms of the correlation functions or Green's functions of the quantum fields evaluated with respect to some state of the system. In particular we shall consider the general case of quantum dynamics for arbitrary non-equilibrium states. After introducing various types of Green's functions and relating them to measurable quantities, we will discuss the simplifications reigning for the special case of equilibrium states. Quantum dynamics Quantum dynamics can be described in different ways since quantum mechanics is a linear theory and the dynamics described by a unitary transformation of states. This will come in handy in the next chapter when we study a quantum theory in terms of its perturbative expansion using the so-called interaction picture. Here we first discuss the Schrödinger and Heisenberg pictures. The Schrödinger picture Having the Hamiltonian on the multi-particle space at hand we can consider the dynamics described in the multi-particle space.

Minhaeng Cho

Here, | ( )ψ t > is the Dirac ket state. The corresponding bra state is denoted as < ψ( ) |t . The time-dependent Schrödinger equation (2.1) is one of the most fundamental and important postulates in quantum mechanics.6-8 In this chapter, we introduce the concept of linear vector (wavefunction) and matrix (density operator) spaces to describe the quantum dynamics of matters interacting with external radiations.

Vasily Evgenevich Tarasov