Unlike special relativity, quantum mechanics was not the inspired product of one mind. It developed, in fits and starts, over a period of 25 years (1900–1925), and many cooks stirred the broth. Even now, a century later, quantum mechanics raises profound conceptual questions. Every competent physicist can “do” quantum mechanics, and the predictions it makes are in spectacularly good agreement with experimental results; there can be little doubt that quantum mechanics is “right.” On the other hand, as Richard Feynman once remarked, “nobody understands quantum mechanics.” I'll tell the story in two parts. First the history (how the essential pieces of the puzzle were assembled), and then the implications (what the finished picture has to say about our world). Photons Like relativity, quantum mechanics began with the study of light. In both cases, this historical association is misleading. Relativity, really, has nothing to do with light – to be sure, it involves that magic speed limit, c , and of course the most familiar thing that travels at speed c is light. So light is a convenient vehicle for introducing the subject. But it is perfectly possible to imagine a universe in which there is no such thing as light, and yet relativity might still be valid. Quantum mechanics, too, starts with light – in this case the “quantum” of light (the photon). But, as it turns out, this is just one rather specialized example of much more general principles – in fact, a rather bad example, because photons are by their nature relativistic (they travel at the speed of light), and it would be more natural to begin with the quantum mechanics of slow-moving objects, in analogy with Newtonian mechanics.
Unlike special relativity, quantum mechanics was not the inspired product of one mind. It developed, in fits and starts, over a period of 25 years (1900–1925), and many cooks stirred the broth. Even now, a century later, quantum mechanics raises profound conceptual questions. Every competent physicist can “do” quantum mechanics, and the predictions it makes are in spectacularly good agreement with experimental results; there can be little doubt that quantum mechanics is “right.” On the other hand, as Richard Feynman once remarked, “nobody understands quantum mechanics.” I'll tell the story in two parts. First the history (how the essential pieces of the puzzle were assembled), and then the implications (what the finished picture has to say about our world). Photons Like relativity, quantum mechanics began with the study of light. In both cases, this historical association is misleading. Relativity, really, has nothing to do with light – to be sure, it involves that magic speed limit, c , and of course the most familiar thing that travels at speed c is light. So light is a convenient vehicle for introducing the subject. But it is perfectly possible to imagine a universe in which there is no such thing as light, and yet relativity might still be valid. Quantum mechanics, too, starts with light – in this case the “quantum” of light (the photon). But, as it turns out, this is just one rather specialized example of much more general principles – in fact, a rather bad example, because photons are by their nature relativistic (they travel at the speed of light), and it would be more natural to begin with the quantum mechanics of slow-moving objects, in analogy with Newtonian mechanics.
The difficulties of the old quantum theory were largely dispelled by the development of quantum mechanics in the 1920s. First Heisenberg (1925) developed the rather abstract matrix mechanics and soon after Schro¨dinger (1926; see also Eckart, 1926) developed the physically more appealing wave mechanics. Subsequently he showed them to be mathematically equivalent. The physicists were greatly relieved; now they had once again a mathematical formalism that enabled the results of experiments to be calculated. It was possible to move forward. It is certainly a very elegant and indeed beautiful formalism, and does enable the results of many physical measurements to be calculated with great accuracy. It is used daily by atomic and nuclear physicists; there is no other way to make calculations. From the earliest days there has been intense debate about the interpretation of quantum mechanics, and it shows no signs of being settled; if anything it is becoming more intense over the years. As Penrose has remarked, no one understands quantum mechanics. Feynman (1967; see also Sykes, 1994) also admitted that ‘nobody understands quantum mechanics’, and Einstein once remarked: ‘I have thought a hundred times as much about the quantum problems as I have about general relativity theory’ (Pais, 1994, p. 57). It should therefore be evident that the most that can be done here is to try to show where the real difficulties lie, and how the failure to recognize that quantum mechanics is an essentially statistical theory has led to a series of confusing quantum paradoxes. It is just these paradoxes that have often been used to support theological speculations. It is useful to ask what ‘understanding quantum mechanics’ actually means. Certainly it means being able to calculate the results of many measurements. The same applies to Newton’s theory of gravitation, which we understand in the sense that we can use it as a basis of calculation, although we do not really understand the gravitational force itself. Very often, especially in modern physics, the mathematical formalism does not give us the sort of intuitive physical feeling for what is going on that we often obtain from classical mechanics. Perhaps we can never achieve more than this for quantum mechanics. In classical mechanics we can assume that a property that is measured objectively exists prior to the interaction of the measuring apparatus with the observed system. Quantum mechanics, however, ‘is incompatible with the proposition that measurement discovers some unknown but pre-existing property’ (Peres, 1997, p. 14). There is an important distinction between mysteries and absurdities. We may be forced to live with mysteries, but there is no reason why we should put up with absurdities such as the wave-particle duality, tunnelling through potential barriers, acausal events and the collapse of the wave function. These are the quantum paradoxes that will be discussed later on. They arise within the Copenhagen interpretation of quantum mechanics and are solved by other interpretations. These alternative interpretations enable us to make conjectures about what is going on, even though we cannot understand it in detail. This is acceptable and a stimulus to further research. It is certainly difficult enough to understand quantum mechanics, but there is no need to try to visualize logical absurdities in the effort to do so. Quantum mechanics is a mathematical formalism that makes it possible to calculate the results of some experiments. Anything more than this, such as questions about the interpretation of what is measured and whether it tells us what is actually going on in the system being studied, belongs to philosophy. Thus we are concerned here with what is essentially a philosophical debate; if it were just a matter of physics the debate would have been settled long ago. One of the difficulties is that it invokes the results of experiments and uses the language of quantum mechanics. Inevitably this language uses philosophical terms and then it is easy to give the impression that the philosophical propositions are in some way entailed by the physical results. These in turn can influence theological thinking. In order to be quite clear which arguments are justified and which are not, it is essential to separate the three levels of discourse: physical, philosophical and theological. Our task is to relate these together, and this immediately raises the traditional problems of the philosophy of science, including the relation of experiment to theory, and of theory to explanation. We begin by discussing experiments, distinguishing between those that are real and those that are imaginary.
The story of quantum mechanics is a fable of wonder and bewilderment. It has elements of science, philosophy, religion, and dare I say magic. It’ll turn your mind upside down, and sometimes it’ll make you question the existence of an all-powerful creator out there. Even though I find its concepts difficult to grasp, I’ve always been fascinated by it. Some of the concepts presented in this chapter are hard to understand; however don’t be troubled. Nobody has been able to fully describe what this all means, not even the titans of physics fully understand quantum mechanics. However that doesn’t mean we can’t be fascinated by it. The great physicist Richard Feynman once said: If somebody tells you he understands quantum mechanics, it means he doesn’t understand quantum mechanics. This chapter is my take on this fascinating fable and how the struggle of two titans of science shaped its past, present, and future.
What is usually called modern physics is based on two theories: relativity, which we have just nished discussing, and quantum mechanics (also called quantum theory). While some of the ideas of relativity, such as time dilation and length contraction, at rst seemed rather strange, we saw that they followed logically from the two postulates of relativity. We will see below that the ideas of quantum mechanics are also strange. Most physicists would agree that they are much stranger than relativity. In fact, we will see that there are no satisfactory explanations. To quote two Nobel Prize laureates, Murray Gell-Mann and Richard Feynman, “Nobody really understands quantum theory.” Despite this, it is one of the best-tested theories that we have. In some cases, the agreement between the theoretical prediction and experiment is better than 1 part in a million. There are many useful devices that are based on quantum mechanics. They include anything that uses microelectronics, such as a cell phone, DVD player, or computer, nuclear reactors, and medical imaging devices such as MRI and PET.
There are two ways to teach quantum mechanics. The first way – which for most physicists today is still the only way – follows the historical order in which the ideas were discovered. So, you start with classical mechanics and electrodynamics, solving lots of grueling differential equations at every step. Then, you learn about the “blackbody paradox” and various strange experimental results, and the great crisis these things posed for physics. Next, you learn a complicated patchwork of ideas that physicists invented between 1900 and 1926 to try to make the crisis go away. Then, if you're lucky, after years of study, you finally get around to the central conceptual point: that nature is described not by probabilities (which are always nonnegative), but by numbers called amplitudes that can be positive, negative, or even complex. Look, obviously the physicists had their reasons for teaching quantum mechanics that way, and it works great for a certain kind of student. But the “historical” approach also has disadvantages, which in the quantum information age are becoming increasingly apparent. For example, I’ve had experts in quantum field theory – people who've spent years calculating path integrals of mind-boggling complexity – ask me to explain the Bell inequality to them , or other simple conceptual things like Grover's algorithm. I felt as if Andrew Wiles had asked me to explain the Pythagorean Theorem.
The objective of this chapter is to go over a few of the basic concepts of quantum mechanics in preparation for a discussion of spectroscopy, which is in many ways the business end of quantum mechanics, at least for chemical scientists. We will also need a few quantum mechanical ideas from time to time in our study of thermodynamics and of kinetics. Why should we learn quantum mechanics at all? Atoms and molecules are small, and their constituent parts, electrons, protons and neutrons, are even smaller. Early in the twentieth century, we learned that small things don't obey the laws of classical mechanics. A different kind of mechanics, quantum mechanics, is required to understand chemistry on a fundamental level. In fact, we need different mechanical theories to treat extremes of both size and speed. Figure 2.1 summarizes the situation. There isn't a sharp cut-off between the various sectors of this diagram. Also note that some of the theories are more general than others. We could in principle use quantum mechanics or general relativity to predict the trajectories of tennis balls, but it just isn't worth the effort, given that classical mechanics works perfectly well in this range of masses and speeds. On the other hand, classical mechanics doesn't give very good results for things that are either extremely large, or small, or fast. Like it or not, to discuss phenomena on an atomic scale, we need quantum mechanics. Ordinary (non-relativistic) quantum mechanics is generally adequate, although electrons in heavy atoms sometimes reach relativistic speeds (approaching the speed of light, c ), requiring relativistic quantum mechanics.
The turn of the XXth century witnessed a revolution in physics comparable to Isaac Newton’s discovery of the universal laws of mechanics and of gravitation three centuries earlier. The world required to be described in novel terms, as the immutable, deterministic view of our familiar universe had given way to a new world picture, one which featured chance, flux, and an incessant upsurge of waves of matter. Such a worldview was so radically new and counterintuitive that it gave rise to strong debates, to the effect that Albert Einstein himself tried to oppose it on the grounds that “God does not play dice”. In spite of the intense debates that accompanied its emergence, quantum mechanics quickly proved an incredibly efficacious new tool to understand and to predict a wide array of new phenomena. It was so successful that in no time it broke free from the environment of research labs to become part of daily life, making it possible, for example, to understand why some materials were conductors, while others were insulators. Along with it, came, too, the discovery of transistors, on which much of modern electronics rests. It also led to understand how novel materials known as superconductors allow the transport of electricity with no loss, thus paving the way for new developments in the fields of medical imagery or energy distribution. Other aspects of the quantum theory led to the development of atomic clocks of astounding accuracy, which would be wrong by no more than fifteen seconds, had they been set at the beginning of the universe. A hundred years later, at the turn of the XXIst century, Quantum mechanics has lost none of its astounding power. Contemporary research has undertaken the task of exploring its less immediately perceptible aspects. Groundbreaking developments have ensued, such as the teleportation of grains of light or the possibility, once predicted by the great physicist Richard Feynman, to build, one day, novel computers which, unlike the ones we are familiar with today, will be able to process innumerable numbers of operations in parallel. The Wright Colloquium will be for us the occasion to explore, in the company of five internationallyknown specialists in the field, some of the fascinating aspects of quantum mechanics. We will appraise how efficiently quantum physics can describe our world, and confront its limitation when it is faced with the infinitely small (in relation to recent experiments carried out at the CERN) as with the incommensurably large scale of sidereal spaces. We will appreciate the extent to which quantum physics already has impacted our everyday lives, and evoke the way in which novel fields such as quantum computers and quantum information will entail profound changes in the future. The quantum adventure has only just begun! Monday 15 November 2010 - 18h30 Jochen Mannhart Center for Electronic Correlations and Magnetism, University of Augsburg, Germany Quantum Physics on the Scale of Daily Life Tuesday 16 November 2010 - 18h30 Wolfgang Ketterle Nobel Laureate 2001 (Physics), Department of Physics, Massachusetts Institute of Technology, Cambridge, U.S.A. When freezing cold is not cold enough New forms of matter close to absolute zero temperature Wednesday 17 November 2010 - 18h30 David Gross Nobel Laureate 2004 (Physics), Kavli Institute for Theoretical Physics, University of California, Santa-Barbara, U.S.A. Quantum Mechanics of the Very, Very Small and the Very, Very Large Thursday 18 November 2010 - 18h30 Alain Aspect CNRS senior scientist and Professor Institut d'Optique and Ecole Polytechnique Palaiseau, France. From Einstein’s intuition to quantum bits: a new quantum age? Vendredi 19 novembre 2010 - 18h30 Rainer Blatt Institute of Quantum Optics and Quantum Information, Austrian Academy of Sciences and University of Innsbruck, Austria The Quantum Way of Doing Computations