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Mathematical Foundations of Quantum Mechanics

Ugurbil, Mehmet, '13

Published Apr 9, 2013• 0 citations
OpenAlex

Abstract

Selected topics from the study of functional analysis are presented. Specifically, Hilbert space theory is analyzed to show the development of the mathematical base for quantum mechanics. The role of unbounded operators in physics versus the mathematically elegant bounded ones is discussed.

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Quantum theory and functional analysis were created and put into essentially their final form during similar periods ending around 1930. Each was also a key outcome of the major revolutions that both physics and mathematics as a whole underwent at the time. This paper studies their interaction in this light, emphasizing the leading roles played by Hilbert in preparing the ground and by von Neumann in bringing them together during the crucial year of 1927, when he gave the modern, abstract definition of a Hilbert space and applied this concept to quantum mechanics (consolidated in his famous monograph from 1932). Subsequently, I give a very brief overview of three areas of functional analysis that have had fruitful interactions with quantum theory since 1932, namely unbounded operators, operator algebras, and distributions. The paper closes with some musings about the role of functional analysis in actual physics.
Quantum mechanics and the theory of operators on Hilbert space have been deeply linked since their beginnings in the early twentieth century. States of a quantum system correspond to certain elements of the configuration space and observables correspond to certain operators on the space. This book is a brief, but self-contained, introduction to the mathematical methods of quantum mechanics, with a view towards applications to Schrodinger operators. Part 1 of the book is a concise introduction to the spectral theory of unbounded operators. Only those topics that will be needed for later applications are covered. The spectral theorem is a central topic in this approach and is introduced at an early stage. Part 2 starts with the free Schrodinger equation and computes the free resolvent and time evolution. Position, momentum, and angular momentum are discussed via algebraic methods. Various mathematical methods are developed, which are then used to compute the spectrum of the hydrogen atom. Further topics include the nondegeneracy of the ground state, spectra of atoms, and scattering theory. This book serves as a self-contained introduction to spectral theory of unbounded operators in Hilbert space with full proofs and minimal prerequisites: Only a solid knowledge of advanced calculus and a one-semester introduction to complex analysis are required. In particular, no functional analysis and no Lebesgue integration theory are assumed. It develops the mathematical tools necessary to prove some key results in nonrelativistic quantum mechanics. Mathematical Methods in Quantum Mechanics is intended for beginning graduate students in both mathematics and physics and provides a solid foundation for reading more advanced books and current research literature. This new edition has additions and improvements throughout the book to make the presentation more student friendly.
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Quantum mechanics is one of the principle pillars of modern physics. It also remains a topic of great interest to mathematicians. Since its discovery it has inspired and been inspired by many topics within modern mathematics, including functional analysis and operator algebras, Lie groups, Lie algebras and their representations, principle bundles, distribution theory, and much more. Written with beginning graduate students in mathematics in mind, this book provides a thorough treatment of (nonrelativistic) quantum mechanics in a style that is leisurely, without the usual theorem-proof grammar of pure mathematics, while remaining mathematically honest. The author takes the time to fully develop the required mathematics and employs a consistent mathematical presentation to clarify the often-confusing notation of physics texts. Along the way the reader encounters several topics requiring more advanced mathematics than found in many discussions of the subject, making for a fascinating course in how mathematics and physics interact.
Quantum mechanics is one of the principle pillars of modern physics. It also remains a topic of great interest to mathematicians. Since its discovery it has inspired and been inspired by many topics within modern mathematics, including functional analysis and operator algebras, Lie groups, Lie algebras and their representations, principle bundles, distribution theory, and much more. Written with beginning graduate students in mathematics in mind, this book provides a thorough treatment of (nonrelativistic) quantum mechanics in a style that is leisurely, without the usual theorem-proof grammar of pure mathematics, while remaining mathematically honest. The author takes the time to fully develop the required mathematics and employs a consistent mathematical presentation to clarify the often-confusing notation of physics texts. Along the way the reader encounters several topics requiring more advanced mathematics than found in many discussions of the subject, making for a fascinating course in how mathematics and physics interact.
In this chapter, we present the basic principles of the quantum mechanics of particle systems from a modern mathematical perspective. The proper study of quantum mechanics brings together several interesting mathematical ideas, ranging from group representations to the spectral theory of unbounded self-adjoint operators in Hilbert spaces and the theory of C * algebras. The facts from analysis of operators in Hilbert spaces and C * algebras needed in this chapter are presented in detail in the appendices at the end of the book. More on the mathematical foundations of quantum mechanics can be found in the books by L. Fadeev and O. Yakubovskii [FY], G. Mackey [M], and F. Strocchi [Str] listed in the bibliography. The birth of quantum theory The origins of quantum theory can be traced back to M. Planck's study, published in 1900, of so-called black-body radiation. It is well known that matter glows when heated, going from red-hot to white-hot as the temperature rises. The color (or frequency of radiation) of the radiating body is independent of its surface, and for a black body it is found to be a function of temperature alone. The behavior of the radiation energy as a function of temperature seemed quite different at high temperatures and low temperatures. In a desperate attempt to fit these different behaviors into a single law, Planck introduced the hypothesis that energy was not continuous, but came in discrete packets or quanta . At the beginning of the twentieth century, a number of experiments pointed to a breakdown of the laws of classical mechanics at very small (subatomic) scales.