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Plenum Press eBooks

Coherence in atomic collision physics : for Hans Kleinpoppen on his sixtieth birthday

H. J. Beyer, Karl Blum, R. Hippler, Hans Kleinpoppen

Published Jan 1, 1988• 0 citations
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Abstract

1 Electron Scattering from Heavy Atoms.- 2 Spin Polarization in Electron-Atom Scattering.- 3 Electron Scattering from Chiral Molecules.- 4 Applications of Lasers in Atomic Collision Physics.- 5 Excitation and Ionization in Atomic Collisions.- 6 Inner-shell Vacancy Creation: Perturbative Approximations and Beyond.- 7 Excitation in Ion-Atom Collisions.- 8 Coherence in Grazing Ion-Surface Collisions.- 9 The Two-Photon Decay of Atomic Hydrogen and Tests of Bell's Inequality.

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Collisions and half-collisions with lasers

N. K. Rahman, Carla Guidotti

Merging two subfields, collisions and spectroscopy, this book presents the latest research proposals, innovative experiments and fresh ideas. Topics considered include radiative collision induced electron continuum-continuum scattering; models of laser-induced chemical reactions; experimental studies of laser-induced ionizing collisions; laser photodissociation of Na/sub 2/ + ions produced by laser resonant ionization of Na vapor; steady-state electron-atom collision in a laser field; conditions for the observation of the predicted splitting of the laser assisted electron impact of the differential cross section of atoms; transitions between resonances; some proposals for experiments; above-threshold multiphoton ionization; observability of optical collisions in the frequency and the time domain; laser switched collisions - a diagrammatical approach; polarization of atomic fluorescence excited by molecular photodissociation; multiphoton selective excitation; on the role of chaotic dynamics with many basins of attraction; predissociation in a strong electromagnetic field; theory of double resonance; and coherent excitation of polyatomic molecules up to highly excited vibrational states by laser light.

•Jan 1, 1984•42 citations

The Story of Quantum Land

Pourya Zarshenas

Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned with the way in which electrons are arranged around the nucleus and the processes by which these arrangements change. This comprises ions, neutral atoms and, unless otherwise stated, it can be assumed that the term atom includes ions. The term atomic physics can be associated with nuclear power and nuclear weapons, due to the synonymous use of atomic and nuclear in Standard English. Physicists distinguish between atomic physics -which deals with the atom as a system consisting of a nucleus and electrons- and nuclear physics, which studies nuclear reactions and special properties of atomic nuclei. As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider context of atomic, molecular, and optical physics. Physics research groups are usually so classified. Atomic physics primarily considers atoms in isolation. Atomic models will consist of a single nucleus that may be surrounded by one or more bound electrons. It is not concerned with the formation of molecules (although much of the physics is identical), nor does it examine atoms in a solid state as condensed matter. It is concerned with processes such as ionization and excitation by photons or collisions with atomic particles. While modelling atoms in isolation may not seem realistic, if one considers atoms in a gas or plasma then the time-scales for atom-atom interactions are huge in comparison to the atomic processes that are generally considered. This means that the individual atoms can be treated as if each were in isolation, as the vast majority of the time they are. By this consideration atomic physics provides the underlying theory in plasma physics and atmospheric physics, even though both deal with very large numbers of atoms. Electrons form notional shells around the nucleus. These are normally in a ground state but can be excited by the absorption of energy from light (photons), magnetic fields, or interaction with a colliding particle (typically ions or other electrons). Electrons that populate a shell are said to be in a bound state. The energy necessary to remove an electron from its shell (taking it to infinity) is called the binding energy. Any quantity of energy absorbed by the electron in excess of this amount is converted to kinetic energy according to the conservation of energy. The atom is said to have undergone the process of ionization. If the electron absorbs a quantity of energy less than the binding energy, it will be transferred to an excited state. After a certain time, the electron in an excited state will "jump" (undergo a transition) to a lower state. In a neutral atom, the system will emit a photon of the difference in energy, since energy is conserved. If an inner electron has absorbed more than the binding energy (so that the atom ionizes), then a more outer electron may undergo a transition to fill the inner orbital. In this case, a visible photon or a characteristic x-ray is emitted, or a phenomenon known as the Auger effect may take place, where the released energy is transferred to another bound electron, causing it to go into the continuum. The Auger effect allows one to multiply ionize an atom with a single photon. There are rather strict selection rules as to the electronic configurations that can be reached by excitation by light — however there are no such rules for excitation by collision processes. One of the earliest steps towards atomic physics was the recognition that matter was composed of atoms. It forms a part of the texts written in 6th century BC to 2nd century BC such as those of Democritus or Vaisheshika Sutra written by Kanad. This theory was later developed in the modern sense of the basic unit of a chemical element by the British chemist and physicist John Dalton in the 18th century. At this stage, it wasn't clear what atoms were although they could be described and classified by their properties (in bulk). The invention of the periodic system of elements by Mendeleev was another great step forward. The true beginning of atomic physics is marked by the discovery of spectral lines and attempts to describe the phenomenon, most notably by Joseph von Fraunhofer. The study of these lines led to the Bohr atom model and to the birth of quantum mechanics. In seeking to explain atomic spectra an entirely new mathematical model of matter was revealed. As far as atoms and their electron shells were concerned, not only did this yield a better overall description, i.e. the atomic orbital model, but it also provided a new theoretical basis for chemistry (quantum chemistry) and spectroscopy. Since the Second World War, both theoretical and experimental fields have advanced at a rapid pace. This can be attributed to progress in computing technology, which has allowed larger and more sophisticated models of atomic structure and associated collision processes. Similar technological advances in accelerators, detectors, magnetic field generation and lasers have greatly assisted experimental work.

•Apr 11, 2022•0 citations

Atomic Collision Physics: Coherence and Correlation in Atomic Collisions . Papers from a workshop. H. Kleinpoppen and J. F. Williams, Eds. Plenum, New York, 1980. xiv, 706 pp., illus. $59.50. Physics of Atoms and Molecules.

Eugen Merzbacher

Science•Nov 7, 1980•0 citations

On Producing Long-Lived Spin Polarized Metastable Atoms—Feasibility of Storing Electric Energy

Horst Schmidt-Böcking, Gernot Gruber

We describe a method of producing long-lived multiply excited spin polarized atoms or ions, the decay of which is strongly delayed or even blocked by intra-ionic magnetic stabilization. Special configurations with huge internal magnetic fields capture only spin polarized electrons in collisions with spin aligned atomic hydrogen gas targets. It is expected that the spin aligned configuration yields an extremely high internal magnetic field which will effectively block spin flip transitions. By this the lifetime of inner shell vacancies is expected to strongly increase.

Atoms•Jul 18, 2022•2 citations

Atomic physics

Sheldon Datz, G. W. F. Drake, Thomas F. Gallagher +2 more

This Section contains examples of important areas in atomic physics, including articles on cold atoms collisions, accelerator-based atomic collisions, fundamental-type atomic collisions, high-precision atomic theory and the few-body problem, and ``exotic atoms.''

Reviews of Modern Physics•Mar 1, 1999•22 citations

Collision inside an atom: quantum ion-atom dynamics

Arijit Das, Yufeng Wang, Marcin Welter +6 more

Rydberg atoms occupy a central role in quantum science; their loosely bound outer electron gives rise to properties that enable quantum information processing1 or the formation of exotic molecular bonds2. Beyond these roles, they have been proposed as a neutral platform for the observation of quantum effects in collisions and reactions of the ionic core with neutral particles3, 4, a long-standing goal of ion-based chemistry and physics. However, all of the experimental results so far could be explained using a classical description of the internuclear motion5. Here we demonstrate cold collisions inside a Rydberg helium atom, achieved by merging helium Rydberg and ground-state helium beams and imaging individual scattering events. We resolve the fully quantum-coherent motion and observe matter-wave diffraction and tunnelling-driven shape resonances down to collision energies of 90 mK. In the case of identical helium nuclei, we demonstrate a new regime of identical-particle Mott interference6, where quantum statistics begin to govern the total scattering cross section. For distinct isotopes, we show the breakdown of the Born-Oppenheimer approximation and benchmark parameter-free, state-of-the-art theory. We directly measure the helium isotope ionization-energy difference to be 15.0 +/- 0.1 K. Our experiments establish Rydberg atoms as a platform for the direct observation of quantum dynamics with a general class of ions, atoms and molecules.

arXiv:2610.18345•Oct 13, 2026•0 citations
1 Electron Scattering from Heavy Atoms.- 2 Spin Polarization in Electron-Atom Scattering.- 3 Electron Scattering from Chiral Molecules.- 4 Applications of Lasers in Atomic Collision Physics.- 5 Excitation and Ionization in Atomic Collisions.- 6 Inner-shell Vacancy Creation: Perturbative Approximations and Beyond.- 7 Excitation in Ion-Atom Collisions.- 8 Coherence in Grazing Ion-Surface Collisions.- 9 The Two-Photon Decay of Atomic Hydrogen and Tests of Bell's Inequality.
Merging two subfields, collisions and spectroscopy, this book presents the latest research proposals, innovative experiments and fresh ideas. Topics considered include radiative collision induced electron continuum-continuum scattering; models of laser-induced chemical reactions; experimental studies of laser-induced ionizing collisions; laser photodissociation of Na/sub 2/ + ions produced by laser resonant ionization of Na vapor; steady-state electron-atom collision in a laser field; conditions for the observation of the predicted splitting of the laser assisted electron impact of the differential cross section of atoms; transitions between resonances; some proposals for experiments; above-threshold multiphoton ionization; observability of optical collisions in the frequency and the time domain; laser switched collisions - a diagrammatical approach; polarization of atomic fluorescence excited by molecular photodissociation; multiphoton selective excitation; on the role of chaotic dynamics with many basins of attraction; predissociation in a strong electromagnetic field; theory of double resonance; and coherent excitation of polyatomic molecules up to highly excited vibrational states by laser light.
Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned with the way in which electrons are arranged around the nucleus and the processes by which these arrangements change. This comprises ions, neutral atoms and, unless otherwise stated, it can be assumed that the term atom includes ions. The term atomic physics can be associated with nuclear power and nuclear weapons, due to the synonymous use of atomic and nuclear in Standard English. Physicists distinguish between atomic physics -which deals with the atom as a system consisting of a nucleus and electrons- and nuclear physics, which studies nuclear reactions and special properties of atomic nuclei. As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider context of atomic, molecular, and optical physics. Physics research groups are usually so classified. Atomic physics primarily considers atoms in isolation. Atomic models will consist of a single nucleus that may be surrounded by one or more bound electrons. It is not concerned with the formation of molecules (although much of the physics is identical), nor does it examine atoms in a solid state as condensed matter. It is concerned with processes such as ionization and excitation by photons or collisions with atomic particles. While modelling atoms in isolation may not seem realistic, if one considers atoms in a gas or plasma then the time-scales for atom-atom interactions are huge in comparison to the atomic processes that are generally considered. This means that the individual atoms can be treated as if each were in isolation, as the vast majority of the time they are. By this consideration atomic physics provides the underlying theory in plasma physics and atmospheric physics, even though both deal with very large numbers of atoms. Electrons form notional shells around the nucleus. These are normally in a ground state but can be excited by the absorption of energy from light (photons), magnetic fields, or interaction with a colliding particle (typically ions or other electrons). Electrons that populate a shell are said to be in a bound state. The energy necessary to remove an electron from its shell (taking it to infinity) is called the binding energy. Any quantity of energy absorbed by the electron in excess of this amount is converted to kinetic energy according to the conservation of energy. The atom is said to have undergone the process of ionization. If the electron absorbs a quantity of energy less than the binding energy, it will be transferred to an excited state. After a certain time, the electron in an excited state will "jump" (undergo a transition) to a lower state. In a neutral atom, the system will emit a photon of the difference in energy, since energy is conserved. If an inner electron has absorbed more than the binding energy (so that the atom ionizes), then a more outer electron may undergo a transition to fill the inner orbital. In this case, a visible photon or a characteristic x-ray is emitted, or a phenomenon known as the Auger effect may take place, where the released energy is transferred to another bound electron, causing it to go into the continuum. The Auger effect allows one to multiply ionize an atom with a single photon. There are rather strict selection rules as to the electronic configurations that can be reached by excitation by light — however there are no such rules for excitation by collision processes. One of the earliest steps towards atomic physics was the recognition that matter was composed of atoms. It forms a part of the texts written in 6th century BC to 2nd century BC such as those of Democritus or Vaisheshika Sutra written by Kanad. This theory was later developed in the modern sense of the basic unit of a chemical element by the British chemist and physicist John Dalton in the 18th century. At this stage, it wasn't clear what atoms were although they could be described and classified by their properties (in bulk). The invention of the periodic system of elements by Mendeleev was another great step forward. The true beginning of atomic physics is marked by the discovery of spectral lines and attempts to describe the phenomenon, most notably by Joseph von Fraunhofer. The study of these lines led to the Bohr atom model and to the birth of quantum mechanics. In seeking to explain atomic spectra an entirely new mathematical model of matter was revealed. As far as atoms and their electron shells were concerned, not only did this yield a better overall description, i.e. the atomic orbital model, but it also provided a new theoretical basis for chemistry (quantum chemistry) and spectroscopy. Since the Second World War, both theoretical and experimental fields have advanced at a rapid pace. This can be attributed to progress in computing technology, which has allowed larger and more sophisticated models of atomic structure and associated collision processes. Similar technological advances in accelerators, detectors, magnetic field generation and lasers have greatly assisted experimental work.
We describe a method of producing long-lived multiply excited spin polarized atoms or ions, the decay of which is strongly delayed or even blocked by intra-ionic magnetic stabilization. Special configurations with huge internal magnetic fields capture only spin polarized electrons in collisions with spin aligned atomic hydrogen gas targets. It is expected that the spin aligned configuration yields an extremely high internal magnetic field which will effectively block spin flip transitions. By this the lifetime of inner shell vacancies is expected to strongly increase.
Rydberg atoms occupy a central role in quantum science; their loosely bound outer electron gives rise to properties that enable quantum information processing1 or the formation of exotic molecular bonds2. Beyond these roles, they have been proposed as a neutral platform for the observation of quantum effects in collisions and reactions of the ionic core with neutral particles3, 4, a long-standing goal of ion-based chemistry and physics. However, all of the experimental results so far could be explained using a classical description of the internuclear motion5. Here we demonstrate cold collisions inside a Rydberg helium atom, achieved by merging helium Rydberg and ground-state helium beams and imaging individual scattering events. We resolve the fully quantum-coherent motion and observe matter-wave diffraction and tunnelling-driven shape resonances down to collision energies of 90 mK. In the case of identical helium nuclei, we demonstrate a new regime of identical-particle Mott interference6, where quantum statistics begin to govern the total scattering cross section. For distinct isotopes, we show the breakdown of the Born-Oppenheimer approximation and benchmark parameter-free, state-of-the-art theory. We directly measure the helium isotope ionization-energy difference to be 15.0 +/- 0.1 K. Our experiments establish Rydberg atoms as a platform for the direct observation of quantum dynamics with a general class of ions, atoms and molecules.