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Cambridge University Press eBooks

Macroscopic properties of materials from stimulated emission and absorption

W.S.C. Chang

Published Jan 20, 2005• 0 citations
Publisher

Abstract

All optical oscillators and amplifiers can be analyzed as an electromagnetic structure, such as a cavity or a transmission line, which contains an amplifying medium. The operating characteristics of lasers are governed by both the electromagnetic properties of the structures and the properties of the amplifying medium. Stimulated emission and absorption of radiation from energy states are the physical basis of amplification in all laser materials. In order to study lasers, it is necessary to understand the energy levels of the amplifying medium and the stimulated transitions involving them. Quantum mechanical analysis of the energy states and the stimulated emission and absorption is presented in most books on lasers. However, quantum mechanical analyses cover only the analysis of individual atoms. We need to relate the effects of the quantum mechanical interactions to the macroscopic properties of the materials so that properties of the lasers may be analyzed. Therefore, the macroscopic susceptibility of materials related to stimulated emission and absorption is the focus of discussion in this chapter. It is not the purpose of this book to teach quantum mechanics. There are already many excellent books on this topic. The readers are assumed to have a fundamental knowledge of quantum mechanics. However, it is necessary first to review some of the major steps in order to understand precisely the notation used and the meaning of the results. This is presented in Section 5.1.

DOI
10.1017/cbo9780511755712.006

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All optical oscillators and amplifiers can be analyzed as an electromagnetic structure, such as a cavity or a transmission line, which contains an amplifying medium. The operating characteristics of lasers are governed by both the electromagnetic properties of the structures and the properties of the amplifying medium. Stimulated emission and absorption of radiation from energy states are the physical basis of amplification in all laser materials. In order to study lasers, it is necessary to understand the energy levels of the amplifying medium and the stimulated transitions involving them. Quantum mechanical analysis of the energy states and the stimulated emission and absorption is presented in most books on lasers. However, quantum mechanical analyses cover only the analysis of individual atoms. We need to relate the effects of the quantum mechanical interactions to the macroscopic properties of the materials so that properties of the lasers may be analyzed. Therefore, the macroscopic susceptibility of materials related to stimulated emission and absorption is the focus of discussion in this chapter. It is not the purpose of this book to teach quantum mechanics. There are already many excellent books on this topic. The readers are assumed to have a fundamental knowledge of quantum mechanics. However, it is necessary first to review some of the major steps in order to understand precisely the notation used and the meaning of the results. This is presented in Section 5.1.
Introduction When an electromagnetic wave propagates through amedium stimulated emissions increase the intensity of the wave, while absorptions diminish it. The overall intensity will increase if the number of stimulated emissions can be made larger than the number of absorptions. If we can create such a situation then we have built an amplifier that operates through the mechanism of stimulated emission. This laser amplifier , in common with electronic amplifiers, has useful gain only over a particular frequency bandwidth. Its operating frequency range will be determined by the lineshape of the transition, and we expect the frequency width of its useful operating range to be of the same order as the width of the lineshape. It is very important to consider how this frequencywidth is related to the various mechanisms by which transitions between different energy states of a particle are smeared out over a range of frequencies. This line broadening affects in a fundamental way not only the frequency bandwidth of the amplifier, but also its gain. A laser amplifier can be turned into an oscillator by supplying an appropriate amount of positive feedback. The level of oscillation will stabilize because the amplifier saturates. Laser amplifiers fall into two categories, which saturate in different ways. A homogeneously broadened amplifier consists of a number of amplifying particles that are essentially equivalent, whereas an inhomogeneously broadened amplifier contains amplifying particles with a distribution of amplification characteristics. Homogeneous line broadening All energy states, except the lowest energy state of a particle (the ground state) cover a range of possible energies.
Methods of optical spectroscopy are widely used to study optical properties of materials. This area includes different methods of both linear and nonlinear optics. This chapter focuses on linear optical absorption and luminescence. It includes extended tutorial part addressing basics of the light emission and absorption mechanisms that will help students and young researchers to better understand the subject. The chapter presents a brief overview of basic physics that governs absorption and luminescence of light in materials. It then presents a classic picture of the optical absorption of materials. In order to make a next step and to get a quantum mechanical picture of light interaction with materials it is instructive to start with the interaction of an electromagnetic wave with an atom. There are three basic processes that are responsible for a formation of atomic spectra, i.e. spontaneous emission, stimulated emission, and absorption.
Thus far, we have developed the properties of the electromagnetic field at optical frequencies, based on Maxwell’s equations. These equations further give a classical macroscopic perspective on the coupling of the propagation media to the field, as presented in Chapter 2. The macroscopic properties of a medium are based on averaged microscopic properties. The microscopic energy structure of matter was presented in Chapter 3, covering gases, solids, and liquids by employing mostly quantum models. We now proceed to the next level of development, the dynamic description of the interaction between the optical field and the propagation medium as a function of the field frequency and propagation media variables (e.g., energy structure, temperature, and pressure). In this chapter, the classical electromagnetic field is coupled to discrete frequency oscillators via Newton’s equation of motion. This approach leads to the popular classical oscillator model, often presented in introductory books on lasers. The classical oscillator model is an incomplete theory and can be only a semiempirical model. In the next chapter, a more detailed and comprehensive approach, which also includes statistical and quantum mechanics, is used leading to robust semiclassical and quantum oscillator models. This chapter and the next are the basis for the applied models presented in Part II of this book. Classical electrodynamics is based on Maxwell’s equations, as given in Chapter 2, and the Lorentz force relation, as given below: . . . F = q[E + (v × B)]. (4.1) . . . These equations cover the classical description of the interaction of light and matter. The first term in Eq. 4.1 represents coupling of the electric field to the medium. As discussed in Chapter 2 (Section 2.2), the leading mechanism for this is the electric dipole moment. To see that this is the coupling mechanism in the first term, consider the potential function driving this force, F = −∇V(r) = −∇(−qr · E). The above expression contains the dipole moment, as defined in Chapter 2. The second term in Eq. 4.1 represents coupling of the magnetic field to the medium.
This chapter provides the basis for the discussion in the following chapters by summarizing the fundamental concepts and the quantum theory concerning the interaction between electrons and photons in a form that is convenient for theoretical analysis of semiconductor lasers [1-9]. First, quantization of electromagnetic fields of optical waves is outlined, and the concept of a photon is clarified. Quantum theory expressions for coherent states are also given. Then the quantum theory of electronphoton interactions and the general characteristics of optical transitions are explained. Fundamental mathematical expressions for absorption, spontaneous emission, and stimulated emission of photons are deduced, and the possibility of optical wave amplification in population-inverted states is shown.
This textbook provides an accessible introduction to laser physics, exploring three key questions: What is special about laser light? What is the physics underlying its generation? And how can laser light be manipulated and used? The material is presented in a manner that helps the reader develop an understanding of the underlying physics principles and processes without getting bogged down in mathematical details, but there is enough mathematics for the understanding to be quantitative. The book begins by describing the special properties of laser light and focuses on the physics of light-matter interaction to understand how it acquires them. It builds upon Maxwells equations for light and the classical electron oscillator model for the atoms, augmented with a quantum mechanical picture of atomic energy levels, to provide an accurate physical understanding of light-matter interaction. This approach bypasses the need for a course in quantum theory. Derivations of key equations are included not only to help readers follow the development of the subject, but also to illustrate that to approximate, simplify, and get analytic results is integral to understanding any complex phenomenon. Subjects such as nonlinear pulse propagation and nonlinear optics are discussed, but only at a level that should help readers to get started in these fields. The choice of topics has been limited to atomic/molecular lasers to allow for their coverage in one semester-long course. Problems, references and illustrations are included throughout the book, making it an ideal textbook for advanced undergraduate and graduate physics and engineering students. Students do not require prior knowledge of physics much beyond an undergraduate-level introduction to electromagnetic theory, including Maxwell’s equations, polarization in atomic media and electromagnetic wave propagation. Key features: · Provides a qualitative and quantitative understanding of, and appreciation for, the special properties of laser light · Explores quantum statistics of laser light · Presents an analytical approach to pulse formation
The analysis in Chapter 3 used a phenomenological form of the permittivity to describe active materials. A proper understanding of optical amplification requires a quantum-mechanical approach for describing the interaction of light with atoms of an active medium [1]. However, even a relatively simple atom such as hydrogen or helium allows so many energy transitions that its full description is intractable even with modern computing machinery [2, 3]. The only solution is to look for idealized models that contain the most essential features of a realistic system. The semiclassical two-level-atom model has proven to be quite successful in this respect [4]. Even though a real atom has infinitely many energy levels, two energy levels whose energy difference nearly matches the photon energy suffice to understand the interaction dynamics when the atom interacts with nearly monochromatic radiation. Moreover, if the optical field contains a sufficiently large number of photons (> 100), it can be treated classically using a set of optical Bloch equations. In this chapter, we learn the underlying physical concepts behind the optical Bloch equations. We apply these equations in subsequent chapters to actual optical amplifiers and show that they can be solved analytically under certain conditions to provide a realistic description of optical amplifiers. It is essential to have a thorough understanding of the concept of a quantum state [5]. To effectively use the modern machinery of quantum mechanics, physical states need to be represented as vectors in so-called Hilbert space [6].