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Physical Review A

Radiative lifetime and transition probabilities in Cd~I and Cd~I~I (14 pages)

Sune R. Svanberg, Anders Persson, H. L. Xu

Published Jan 1, 2004• 0 citations
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The radiative transition probabilities in hydrogen have been calculated for all Stark transitions through n=25n=25n=25. In general, the total transition probability and lifetime of a particular state are a function of the parabolic quantum numbers n1{n}_{1}n1​, n2{n}_{2}n2​, and mmm. For m>0m>0m>0 and to within an error of the order of one percent the radiative lifetimes are functions only of nnn, mmm. The radiative lifetimes are presented graphically for all states from n=2n=2n=2 through n=25n=25n=25.
We experimentally and theoretically determine the magic wavelength of the (5s^{2})^{1}S_{0}-(5s5p)^{3}P_{0} clock transition of ^{111}Cd to be 419.88(14) and 420.1(7) nm. To perform Lamb-Dicke spectroscopy of the clock transition, we use narrow-line laser cooling on the ^{1}S_{0}-^{3}P_{1} transition to cool the atoms to 6 μK and load them into an optical lattice. Cadmium is an attractive candidate for optical lattice clocks because it has a small sensitivity to blackbody radiation and its efficient narrow-line cooling mitigates higher order light shifts. We calculate the blackbody shift, including the dynamic correction, to be fractionally 2.83(8)×10^{-16} at 300 K, an order of magnitude smaller than that of Sr and Yb. We also report calculations of the Cd ^{1}P_{1} lifetime and the ground state C_{6} coefficient.