The radiative decay of metastable nsnp
3P0 atomic states is found to occur only by odd-parity multiphoton modes such as
E1M1 and
3E1, in the absence of hyperfine structure. A detailed calculation of the
E1M1 rates for several members of the Be sequence is presented, in the nonrelativistic approximation. Only the general properties of
3E1 decay are presented. Among other results, the
3E1 rate is found to be zero if any two photons have the same energy, and its spectrum, unlike the symmetrical two-photon spectra, is found to be irregular and asymmetric, being peaked somewhat below half the transition energy.
We have studied modification of the fluorescence spectra of a room-temperature atomic rubidium vapor in the region of 85 R b and 87 R b D 2 lines while changing the temporal rate of linear (triangular) scanning of laser radiation frequency. An increase in the ramping speed over a certain value ( ≈ 10 6 M H z / s ) results in essential modification of magnitudes of individual atomic transitions, different on rising and falling slopes, which characterize transition from a steady-state interaction regime to a transient one. Our experimental results are very consistent with the developed theoretical model. The obtained results can be used for determination of atomic system parameters such as ground-state relaxation rate. Possible follow-up actions for the addressed control of atomic level population are discussed.