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arXiv:2610.27994

Phase shifts and fluctuations from motional, relativistic, and dark-matter effects in ion-trap clocks

Alexander Bott, Fabio Di Pumpo, Enno Giese

quant-phphysics.atm-clusSubmitted Oct 20, 2026• Announced Oct 21, 2026• 0 citations
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Abstract

Ions possess both center-of-mass motion and internal states, rendering trapped-ion optical clocks susceptible to perturbations of both degrees of freedom, which results in systematic shifts and fluctuations with motional and relativistic origins. We develop a quantum theory that connects these effects to filter functions determined by the employed pulse sequences and show how the interrogation can be tailored to suppress or enhance specific perturbations. Our treatment includes laser frequency noise and motional effects such as recoil and Doppler shifts, micromotion and excess micromotion, as well as state-dependent trap imperfections and accelerations, e.g., caused by Stark shifts. We further account for relativistic effects including time dilation and the mass defect, and show how the same framework can be applied to hypothetical dark-matter signals. By considering ensemble-averaged phases and their variances, we characterize both systematic shifts and fluctuations, while asynchronous operation relative to the Paul-trap drive allows motional fluctuations to average down between runs. Our results provide a unified framework for characterizing and controlling the systematic and statistical contributions that determine the trueness and precision of trapped-ion optical clocks.

Comments
17 pages, 3 figures, 7 tables

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Ions possess both center-of-mass motion and internal states, rendering trapped-ion optical clocks susceptible to perturbations of both degrees of freedom, which results in systematic shifts and fluctuations with motional and relativistic origins. We develop a quantum theory that connects these effects to filter functions determined by the employed pulse sequences and show how the interrogation can be tailored to suppress or enhance specific perturbations. Our treatment includes laser frequency noise and motional effects such as recoil and Doppler shifts, micromotion and excess micromotion, as well as state-dependent trap imperfections and accelerations, e.g., caused by Stark shifts. We further account for relativistic effects including time dilation and the mass defect, and show how the same framework can be applied to hypothetical dark-matter signals. By considering ensemble-averaged phases and their variances, we characterize both systematic shifts and fluctuations, while asynchronous operation relative to the Paul-trap drive allows motional fluctuations to average down between runs. Our results provide a unified framework for characterizing and controlling the systematic and statistical contributions that determine the trueness and precision of trapped-ion optical clocks.
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We describe a framework for calculating the frequency shift and uncertainty of trapped-ion optical atomic clocks caused by background-gas collisions, and apply this framework to an 27Al+^{27}\mathrm{Al}^{+}27Al+ clock to enable a total fractional systematic uncertainty below ${10}^{\ensuremath{-}18}$. For this clock, with 38(19) nPa of room-temperature H2{\mathrm{H}}_{2}H2​ background gas, we find that collisional heating generates a non-thermal distribution of motional states with a mean time-dilation shift of order ${10}^{\ensuremath{-}16}$ at the end of a 150 ms probe, which is not detected by sideband thermometry energy measurements. However, the contribution of collisional heating to the spectroscopy signal is highly suppressed and we calculate the BGC shift to be $\ensuremath{-}0.6(2.4)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}19}$, where the shift is due to collisional heating time dilation and the uncertainty is dominated by the worst case $\ifmmode\pm\else\textpm\fi{}\ensuremath{\pi}/2$ bound used for collisional phase shift of the 27Al+^{27}\mathrm{Al}^{+}27Al+ superposition state. We experimentally validate the framework and determine the background-gas pressure in situ using measurements of the rate of collisions that cause reordering of mixed-species ion pairs.
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Optical clocks based on trapped ions can achieve systematic frequency uncertainties below 10${}^{\ensuremath{-}18}$, enabling relativistic geodesy and precise tests of fundamental physics. However, today's single-ion clocks require averaging times of over a week to resolve frequencies at this level, and no multi-ion clock has been implemented, due to difficulties in controlling ion motion. The authors present an ion-trap array that confines up to 100 clock ions with time-dilation shifts in the low-10${}^{\ensuremath{-}19}$ range, and measure the driven motion of individual ions within an ion crystal. These results point to the next generation of ion clocks, and the realization of clock schemes that have languished.