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arXiv:2609.36051

Excitonic Stripe Order in the Two-Orbital Hubbard-Kanamori Model

Rafael Diogo Soares, Luke Staszewski, Chunhan Feng, Alexander Wietek

Published Sep 28, 2026• 0 citations
arXivHTMLPDF

Abstract

Excitonic condensation and stripe formation are two distinct manifestations of electronic correlations. While excitonic order naturally arises in multi-orbital systems, stripe order is a prominent feature of doped correlated-electron models. Here, we investigate an excitonic analogue of stripe order in the two--orbital Hubbard-Kanamori model on the square lattice, characterized by a spatial modulation of inter-orbital particle-hole coherence and, in the orbital-parity-symmetric limit, spontaneous breaking of a relative orbital $\mathbb{Z}_2$ symmetry. Using unrestricted real-space Hartree-Fock calculations complemented by random-phase-approximation instability analysis, we determine how the Kanamori interactions select different excitonic channels. The sign of Hund's exchange controls the spin character of the condensate: ferromagnetic Hund coupling favors triplet excitonic order, whereas antiferromagnetic Hund coupling stabilizes singlet excitonic order. Upon doping, commensurate excitonic density waves develop incommensurate textures, including excitonic stripes and, in the triplet sector, spiral excitonic density waves. We further show that crystal-field splitting strongly reorganizes the excitonic instability by modifying inter-orbital nesting and can stabilize triplet excitonic order even in the absence of pair hopping. Our results establish excitonic stripes as a distinct symmetry-broken state of multi-orbital correlated systems and identify microscopic routes for their stabilization.

DOI
10.48550/arxiv.2609.36051

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Excitonic condensation and stripe formation are two distinct manifestations of electronic correlations. While excitonic order naturally arises in multi-orbital systems, stripe order is a prominent feature of doped correlated-electron models. Here, we investigate an excitonic analogue of stripe order in the two--orbital Hubbard-Kanamori model on the square lattice, characterized by a spatial modulation of inter-orbital particle-hole coherence and, in the orbital-parity-symmetric limit, spontaneous breaking of a relative orbital Z2\mathbb{Z}_2Z2​ symmetry. Using unrestricted real-space Hartree-Fock calculations complemented by random-phase-approximation instability analysis, we determine how the Kanamori interactions select different excitonic channels. The sign of Hund's exchange controls the spin character of the condensate: ferromagnetic Hund coupling favors triplet excitonic order, whereas antiferromagnetic Hund coupling stabilizes singlet excitonic order. Upon doping, commensurate excitonic density waves develop incommensurate textures, including excitonic stripes and, in the triplet sector, spiral excitonic density waves. We further show that crystal-field splitting strongly reorganizes the excitonic instability by modifying inter-orbital nesting and can stabilize triplet excitonic order even in the absence of pair hopping. Our results establish excitonic stripes as a distinct symmetry-broken state of multi-orbital correlated systems and identify microscopic routes for their stabilization.
While excitonic instabilities in multiorbital systems recently have come under scrutiny in a variety of transition-metal compounds, understanding the emergence of these instabilities from strong electronic interactions has remained a challenge. Here, we present a sign-problem-free determinant quantum Monte Carlo study of excitonic density orders in a half-filled two-orbital Hubbard-Kanamori model with broken orbital degeneracy, which accounts for the role of Hund's coupling in transition-metal compounds. For strong inverted (negative) Hund's exchange, we find numerical evidence for the emergence of excitonic density order, with competition between anti-ferro-orbital order and $\mathbf{Q}=(\ensuremath{\pi},\ensuremath{\pi})$ excitonic density order as a function of orbital splitting and Hund's coupling. While inverted Hund's coupling stabilizes a spin-singlet excitonic density phase for weak orbital splitting, positive Hund's coupling favors a spin-triplet excitonic density phase.
Excitonic phases described by the quantum condensation of electron-hole pairs (or excitons) are studied in the two-orbital Hubbard model with the Hund's rule coupling J . Using the variational cluster approximation, we calculate the ground-state energy and order parameters, and show that the Hund's rule coupling always stabilizes the excitonic spin-density- wave state and destabilizes the excitonic charge-density-wave state. The pair coherence lengths calculated in the spin-singlet and spin-triplet states indicate that only the spin-triplet excitons are paired more tightly with increasing J . The single-particle spectrum and density of states are also calculated to clarify the characters of these excitonic density-wave states.
The electronic band structures of conventional band insulators generally remain unchanged under doping via chemical-potential shifts or increasing temperature. However, in Mott and Kondo insulators described by models such as the Hubbard and Kondo lattice models, distinct electronic modes with momentum-shifted magnetic dispersion relations have been shown to emerge from band edges into the gap. Here, by investigating the two-orbital Kanamori-Hubbard model, this study elucidates how and why the band structures of spin-1 antiferromagnetic insulators change with doping and temperature, revealing emergent spectral features characteristic of orbitally degenerate systems. The nature of the emergent electronic modes is clarified using weak-hopping effective theory, selection-rule analysis, and numerical calculations. In a typical parameter regime, the doping-induced modes in each orbital reflect distinct types of spin modes, while the temperature-induced modes primarily reflect the low-energy spin mode in both orbitals; in both cases, the emergent modes exhibit momentum-shifted spin-mode dispersion relations. The momentum regimes of these emergent modes can differ between orbitals if signs of the hopping parameters differ. For small inter-orbital repulsion, onsite spin-triplet pairs can form after doping, leading to a pair-breaking gap, while the temperature-induced electronic modes continue to reflect the low-energy spin mode without a pair-breaking gap. Moreover, the emergence and characteristics of electronic modes in nonequilibrium states by spin or charge perturbations are elucidated. These findings provide a comprehensive understanding of how the interplay among the spin, charge, and orbital degrees of freedom in large-spin antiferromagnetic insulators leads to emergent electronic modes, opening avenues for exploring unconventional quantum phenomena in strongly correlated systems.
Multiorbital Hubbard models with Hund coupling and crystal-field splitting exhibit an instability toward spin-triplet excitonic order in the parameter regime characterized by strong local spin fluctuations. Upon chemical doping, two distinct types of excitonic ferromagnetism have been reported. Using steady-state nonequilibrium dynamical mean-field theory, we demonstrate that photo-doped half-filled systems can host nonthermal counterparts of these excitonic phases and exhibit a rich phase diagram in the space of photo-doping and crystal field splitting. Photo-doping a spin-triplet excitonic insulator provides a route towards nonequilibrium control of magnetic order.
The electronic properties of excitonic insulators have been examined precisely in recent years. Pictures of exciton condensation may be applied to the spin-state transition observed in perovskite cobalt oxides. We examine the crystal-field and magnetic-field dependences of spatial spin structures on the basis of the density matrix renormalization group method using an effective model for the one-dimensional two-orbital Hubbard model in strong-coupling limit. We find an excitonic insulating (EI) phase and a spin-state ordering (SSO) phase in the intermediate region between low-spin and high-spin phases. In the EI phase, spin-triplet excitons are spatially fluctuating due to quantum effects, and an incommensurate spin correlation realizes. The analyses of a spin gap and degeneracy of entanglement spectra suggest the realization of the Haldane-like edge state in the EI phase. In the SSO phase, 3-fold or incommensurate SSO structures realize depending on the crystal-field splitting. These structures are stabilized as a result of the competition of exchange interactions between spin states.
We analyze the stability of excitonic ground states in the two-band Hubbard model with additional electron-phonon and Hund's rule couplings using a combination of mean-field and variational cluster approaches. We show that both the interband Coulomb interaction and the electron-phonon interaction will cooperatively stabilize a charge density wave (CDW) state which typifies an ``excitonic'' CDW if predominantly triggered by the effective interorbital electron-hole attraction or a ``phononic'' CDW if mostly caused by the coupling to the lattice degrees of freedom. By contrast, the Hund's rule coupling promotes an excitonic spin density wave. We determine the transition between excitonic charge and spin density waves and comment on a fixation of the phase of the excitonic order parameter that would prevent the formation of a superfluid condensate of excitons. The implications for exciton condensation in several material classes with strongly correlated electrons are discussed.