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arXiv:2609.26775

Optical Ion Clock with Engineered Immunity to Motion-Induced Frequency Shifts

Mark Lide, Wesley Hardin, Christian Sanner

physics.atom-phquant-phSubmitted Sep 22, 2026• Announced Sep 23, 2026
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Abstract

Spectroscopic frequency shifts due to residual motion of the probed atoms significantly contribute to the uncertainty budgets of state-of-the-art optical ion clocks. For clock transitions with second-order Doppler and quadratic Stark shifts of opposite signs, it is possible to configure electrodynamic ion confinement such that these two shift effects become anticorrelated causing zero net shift. Here, we introduce a spectroscopic interrogation protocol which leads, for systems with unknown and varying motional energy gain rates, to first-order auto-suppression of corresponding frequency shifts without requiring the opposite-sign configuration. We experimentally demonstrate the proposed method on a new ytterbium ion optical clock probing the 467 nm electric octupole (E3) transition, where the combined fractional uncertainty contribution from motion-induced frequency shifts is reduced from $1.3\times10^{-18}$ to $0.3\times10^{-18}$. An interleaved optical frequency ratio measurement against ytterbium's electric quadrupole transition (E2) at 435 nm delivers an E3/E2 frequency ratio of $0.932 \,829 \,404 \,530 \,965 \, 340 (39)$. Combined with previously published ratio data this leads to a limit for a potential fractional temporal variation of the fine-structure constant of $2.4 (2.7) \times 10^{-19}/$yr, in agreement with existing bounds.

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9 pages

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We experimentally investigate an optical frequency standard based on the (2)S1/2(F=0)→(2)F7/2(F=3) electric octupole (E3) transition of a single trapped (171)Yb+ ion. For the spectroscopy of this strongly forbidden transition, we utilize a Ramsey-type excitation scheme that provides immunity to probe-induced frequency shifts. The cancellation of these shifts is controlled by interleaved single-pulse Rabi spectroscopy, which reduces the related relative frequency uncertainty to 1.1×10(-18). To determine the frequency shift due to thermal radiation emitted by the ion's environment, we measure the static scalar differential polarizability of the E3 transition as 0.888(16)×10(-40) J m(2)/V(2) and a dynamic correction η(300 K)=-0.0015(7). This reduces the uncertainty due to thermal radiation to 1.8×10(-18). The residual motion of the ion yields the largest contribution (2.1×10(-18)) to the total systematic relative uncertainty of the clock of 3.2×10(-18).
Frequency standards based on optical transitions between electronic states of trapped ions have reached uncertainties below 10−18 [1]. The Stark shift caused by room-temperature blackbody radiation (BBR) causes the largest correction for most high-performance optical clock. The systematic uncertainty of 171Yb+ clocks based on the 2S1/2 (F = 0) → 2D3/2 (F = 2) electric quadrupole (E2) and 2S1/2 (F = 0) → 2F7/2 (F = 3) electric octupole (E3) transitions is currently limited to 28×10−18 and 1.5×10−18, respectively, by the fractional accuracy of the differential polarizability Δαdc of approximately 2% [2]. In the scope of this thesis, a dual species clock based on 171Yb+ and 88Sr+ ions was set up, operated and evaluated, to overcome this barrier. Since Δαdc is known with a smaller fractional uncertainty of 0.04% for the 2S1/2 → 2D5/2 E2 transition of 88Sr+ [3], this allows for a transfer of Δαdc from 88Sr+ to 171Yb+ following a method proposed in [4]. The optical intensity of a laser is calibrated with the Stark shift it causes on the 88Sr+ clock transition, allowing for the determination of Δαdc of the 171Yb+ clock transitions. This allows for a reduction of the fractional uncertainty of Δαdc for both 171Yb+ clock transitions below 0.4% and clock operation on the E2 and E3 transition with a fractional BBR shift uncertainty of 0.84×10−18 and 0.24×10−18 is enabled, respectively. However the value of Δαdc determined in this thesis does not agree with [2], a fractional offset of approximately 14% is observed. To investigate this discrepancy further, Δαdc is measured in the same manner as in [2] for the 88Sr+ clock transition. The same offset of approximately 14% is found, calling the accuracy of at least one of these methods into question. Finally, the first optical frequency ratio ℛ between the 88Sr+ clock transition and the 171Yb+ E3 transition is measured. The fractional uncertainty of ℛ is 23×10−18. ℛ in combination with the absolute frequency of the E3 transition allows for the determination of the 88Sr+ absolute frequency νSr+ with an uncertainty limited by the caesium references. The value of νSr+ falls outside of the recommended range, but is corroborated by measurements of the same quantity by other institutes [5, 6]. [1] M. Marshall et al., Phys. Rev. Lett. 135, 033201 (2025) [2] N. Huntemann et al., Phys. Rev. Lett. 116, 063001 (2016) [3] T. Lindvall et al., Phys. Rev. Lett. 135, 043402 (2025) [4] M. D. Barrett et al., Phys. Rev. A 100, 043418 (2019) [5] C. Marceau et al., Metrologia 62.4, 045001 (2025) [6] T. Lindvall et al., Phys. Rev. Appl. 24, 044082 (2025)
A multi-ion optical clock with 5×10−19\mathbf{5 \times 10^{-19}}5×10−19 uncertainty
Today's most accurate clocks are based on laser spectroscopy of electronic transitions in single trapped ions and feature fractional frequency uncertainties below 1×10−181\times10^{-18}1×10−18. Scaling these systems to multiple, simultaneously interrogated ions reduces measurement times, driving recent advances in multi-ion clocks. However, maintaining state-of-the-art systematic uncertainties while increasing the number of ions remains a central challenge. Here, we report on a multi-ion optical atomic clock with a fractional frequency uncertainty of 5.3×10−195.3\times10^{-19}5.3×10−19 and up to 10 \Sr ions. Ion-resolved state detection enables minimization of position-dependent shifts, with residual effects suppressed below the 10−2010^{-20}10−20-level. Clock operation with eight to ten ions reduces the measurement time by a factor of 4.8 compared to single-ion operation. A comparison with an established \Yb single-ion clock yields an unperturbed frequency ratio of 0.6926711632159660405(20)0.6926711632159660405(20)0.6926711632159660405(20), with a statistical uncertainty of 0.9×10−180.9\times10^{-18}0.9×10−18 and a combined uncertainty of 2.9×10−182.9\times 10^{-18}2.9×10−18. These results demonstrate robust multi-ion clock operation with reduced averaging time and state-of-the-art accuracy.
Abstract Optical clocks with ultralow uncertainty are strong candidates for the next redefinition of the SI second. The 171 Yb + single-ion clock is particularly attractive owing to its two clock transitions (E2 and E3) and its potential for low uncertainty. A major contribution to the uncertainty budget arises from the electric-quadrupole shift, caused by the interaction between the atomic quadrupole moment and the electric-field gradient at the trap center and strongly dependent on the orientation of the quantization axis. To evaluate this shift, a simplified orthogonal magnetic-field method was employed: three mutually orthogonal magnetic-field directions are generated together with an auxiliary non-orthogonal field. With a dual-condition locking scheme, we measure the E2 transition frequency differences between magnetic-field configurations, infer the electric-field gradient, and apply corrections for the associated quadratic Zeeman shifts. The uncertainty due to magnetic-field misalignment is quantified using a calibrated current-to-field model. The resulting electric-quadrupole shift correction for the 2 S 1/2 → 2 F 7/2 (E3) transition is 3.24 mHz, corresponding to a fractional uncertainty of 1.1×10 −18 in the absolute frequency measurement.
Optical clocks serve as the benchmark devices for the next-generation definition of the second and have significant applications in testing the theories beyong the standard models, dark matter research, and related fields.The ytterbium ion optical clock, featuring two clock transition lines, is among the most precise optical clocks with the lowest uncertainties.The National Institute of Metrology, China (NIM), initiated research on ytterbium ion optical clocks in 2021.Based on an end-cap ion trap, a vacuum system has been established.A 370 nm thirdharmonic fiber laser, along with 760 nm and 935 nm DFB lasers, ensures a stable operation of the optical system.To date, both the electric quadrupole and electric octupole clock transitions have been observed.A 2.8 Hz linewidth of the electric octupole transition has been achieved, with a stability of 1.7E-15 τ -1/2 after closed-loop locking.The uncertainties due to AC Starks shift from clock laser and second-order Doppler shifts are being evaluated, with an expected total uncertainty below 5E-18.
We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition (2)S(1/2)(F=0)→(2)F(7/2)(F=3) in a single trapped (171)Yb(+) ion. The extraordinary features of this transition result from the long natural lifetime and from the 4f(13)6s(2) configuration of the upper state. The electric-quadrupole moment of the (2)F(7/2) state is measured as -0.041(5)ea(0)(2), where e is the elementary charge and a(0) the Bohr radius. We also obtain information on the differential scalar and tensorial components of the static polarizability and of the probe-light-induced ac Stark shift of the octupole transition. With a real-time extrapolation scheme that eliminates this shift, the unperturbed transition frequency is realized with a fractional uncertainty of 7.1×10(-17). The frequency is measured as 642 121 496 772 645.15(52) Hz.