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arXiv:2609.20052

Semiclassical scaling of eigenstate thermalization in single-particle chaotic systems

Yaoqi Ye, Xiao Wang

quant-phcond-mat.stat-mechnlin.CDSubmitted Sep 17, 2026• Announced Sep 18, 2026• 0 citations
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Abstract

We study the off-diagonal matrix elements of real-space observables in time-reversal-invariant single-particle chaotic systems. By analyzing the semiclassical expression for the off-diagonal variance derived from Berry's conjecture, we show that the banded structure of the observable matrix emerges naturally. For local observables, we identify a characteristic bandwidth associated with a late-time timescale inversely proportional to the particle velocity. We further show that, for systems with steep-wall confinement, the predicted magnitude follows the entropy scaling of the eigenstate thermalization hypothesis (ETH), multiplied by an additional kinetic-energy-dependent factor that is independent of spatial dimension and is not captured by conventional many-body ETH. We illustrate these results through a case study of quantum billiards and verify the semiclassical scaling numerically in a generalized quarter-Sinai billiard. Our results elucidate the dynamical implications of Berry's conjecture and provide a comparison between single-particle eigenstate thermalization and many-body ETH.

Comments
6 pages, 3 figures; Supplemental Material: 3 pages, 1 figure

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We study the off-diagonal matrix elements of real-space observables in time-reversal-invariant single-particle chaotic systems. By analyzing the semiclassical expression for the off-diagonal variance derived from Berry's conjecture, we show that the banded structure of the observable matrix emerges naturally. For local observables, we identify a characteristic bandwidth associated with a late-time timescale inversely proportional to the particle velocity. We further show that, for systems with steep-wall confinement, the predicted magnitude follows the entropy scaling of the eigenstate thermalization hypothesis (ETH), multiplied by an additional kinetic-energy-dependent factor that is independent of spatial dimension and is not captured by conventional many-body ETH. We illustrate these results through a case study of quantum billiards and verify the semiclassical scaling numerically in a generalized quarter-Sinai billiard. Our results elucidate the dynamical implications of Berry's conjecture and provide a comparison between single-particle eigenstate thermalization and many-body ETH.
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We derive the eigenstate thermalization hypothesis (ETH) from a random matrix Hamiltonian by extending the model introduced by Deutsch (1991 Phys. Rev. A 43 2046). We approximate the coupling between a subsystem and a many-body environment by means of a random Gaussian matrix. We show that a common assumption in the analysis of quantum chaotic systems, namely the treatment of eigenstates as independent random vectors, leads to inconsistent results. However, a consistent approach to the ETH can be developed by introducing an interaction between random wave-functions that arises as a result of the orthonormality condition. This approach leads to a consistent form for off-diagonal matrix elements of observables. From there we obtain the scaling of time-averaged fluctuations of generic observables with system size for which we calculate an analytic form in terms of the inverse participation ratio. The analytic results are compared to exact diagonalizations of a quantum spin chain for different physical observables in multiple parameter regimes.
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We derive the eigenstate thermalization hypothesis (ETH) from a random matrix Hamiltonian by extending the model introduced by Deutsch (1991 Phys. Rev. A 43 2046). We approximate the coupling between a subsystem and a many-body environment by means of a random Gaussian matrix. We show that a common assumption in the analysis of quantum chaotic systems, namely the treatment of eigenstates as independent random vectors, leads to inconsistent results. However, a consistent approach to the ETH can be developed by introducing an interaction between random wave-functions that arises as a result of the orthonormality condition. This approach leads to a consistent form for off-diagonal matrix elements of observables. From there we obtain the scaling of time-averaged fluctuations of generic observables with system size for which we calculate an analytic form in terms of the inverse participation ratio. The analytic results are compared to exact diagonalizations of a quantum spin chain for different physical observables in multiple parameter regimes.
It is commonly believed that quantum isolated systems satisfying the eigenstate thermalization hypothesis (ETH) are diffusive. We show that this assumption is too restrictive since there are systems that are asymptotically in a thermal state yet exhibit anomalous, subdiffusive thermalization. We show that such systems satisfy a modified version of the ETH ansatz and derive a general connection between the scaling of the variance of the off-diagonal matrix elements of local operators, written in the eigenbasis of the Hamiltonian, and the dynamical exponent. We find that for subdiffusively thermalizing systems the variance scales more slowly with system size than expected for diffusive systems. We corroborate our findings by numerically studying the distribution of the coefficients of the eigenfunctions and the off-diagonal matrix elements of local operators of the random field Heisenberg chain, which has anomalous transport in its thermal phase. Surprisingly, this system also has non-Gaussian distributions of the eigenfunctions, thus, directly violating Berry's conjecture.