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arXiv:2608.20136

Boltzmann counting in Hilbert space

Raúl O. Vallejos, Isadora Veeren, Frederico Brito, Fernando de Melo

quant-phcond-mat.stat-mechSubmitted Aug 20, 2026• Announced Aug 21, 2026• 0 citations
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Abstract

We introduce a geometric entropy for quantum preparations, defined as the logarithm of the Hilbert-space volume of pure states compatible with a given set of constraints. This construction extends Boltzmann's counting perspective to the quantum setting, where compatible states need not be orthogonal and the relevant notion of "number of states" is naturally replaced by a volume in state space. We analyze three classes of constraints: restriction to a subspace, fixed expectation values, and coarse-grained subsystem descriptions. For representative examples, including subspace projection, spin expectation values, partial trace, and an imperfect detector map, we obtain explicit scaling laws and closed-form expressions for the associated volumes. The resulting framework provides a geometric measure of quantum ignorance at the level of the preparation and complements entropy notions based on density matrices and coarse graining.

Comments
12 pages, 3 figures. Comments are welcome

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We introduce a geometric entropy for quantum preparations, defined as the logarithm of the Hilbert-space volume of pure states compatible with a given set of constraints. This construction extends Boltzmann's counting perspective to the quantum setting, where compatible states need not be orthogonal and the relevant notion of "number of states" is naturally replaced by a volume in state space. We analyze three classes of constraints: restriction to a subspace, fixed expectation values, and coarse-grained subsystem descriptions. For representative examples, including subspace projection, spin expectation values, partial trace, and an imperfect detector map, we obtain explicit scaling laws and closed-form expressions for the associated volumes. The resulting framework provides a geometric measure of quantum ignorance at the level of the preparation and complements entropy notions based on density matrices and coarse graining.
In this paper we introduce a canonical quantum coarse-graining and use negentropy to connect ignorance as measured by quantum information entropy and ignorance related to quantum coarse-graining. For our procedure, macro-states are the set of purifications {∣Γˉρ⟩}\{|\barΓ^ρ\rangle\}{∣Γˉρ⟩} associated with density operator ρρρ and micro-states are elements of {∣Γˉρ⟩}\{|\barΓ^ρ\rangle\}{∣Γˉρ⟩}. Unlike other quantum coarse-graining procedures, ours always gives a well-defined unique coarse-graining of phase space. Our coarse-graining is also unique in that the volumes of phase space associated with macro-states are computed from differential manifolds whose metric components are constructed from the Lie group symmetries that generate {∣Γˉρ⟩}\{|\barΓ^ρ\rangle\}{∣Γˉρ⟩}. We call these manifolds surfaces of ignorance, and their volumes quantify the lack of information in ρρρ as measured by quantum information entropies. To show that these volumes behave like information entropies, we compare them to the von Neumann and linear entropies for states whose symmetries are given by SO(3)SO(3)SO(3), SU(2)SU(2)SU(2), and SO(N)SO(N)SO(N). We also show that our procedure reproduces features of Boltzmann's original coarse-graining by showing that the majority of phase space consists of states near or at equilibrium. As a consequence of this coarse-graining, it is shown that an inherent flag variety structure underlies composite Hilbert spaces.
Entanglement for pure bipartite states is most commonly quantified in a state-by-state manner to each pure state of a bipartite system a scalar quantity, such as the von Neumann entropy of a reduced density matrix. This provides a precise local characterization of how entangled a given state is. At the same time, this local description naturally invites a set of complementary, more global questions about the structure of the space of pure states: How abundant are the states with a given amount of entanglement within the full state space? Do the manifolds of constant entanglement exhibit distinct geometric regimes? These questions shift the focus from assigning an entanglement value to a single state to understanding the global organization and geometry of entanglement across the entire manifold of pure states. In this work, we develop a geometric framework in which these questions become natural. We regard the projective Hilbert space of pure states, endowed with the Fubini-Study metric, as a Riemannian manifold and promote bipartite entanglement to a macroscopic functional on this manifold. Its level sets stratify the space of pure states into hypersurfaces of constant entanglement, and we define a geometric entanglement entropy as the log-volume of these hypersurfaces, weighted by the Fubini-Study gradient of entanglement. This quantity plays the role of a microcanonical entropy in entanglement space: it measures the degeneracy of a given entanglement value in the natural quantum geometry. The framework is illustrated first in the simplest case of a single spin-1/2 and then for bipartite entanglement of spin systems, including a two-qubit example where explicit calculations can be carried out, along with a sketch of the extension to spin chains.
We consider a closed macroscopic quantum system in a pure state ψψψ evolving unitarily with Hamiltonian HHH in a finite-dimensional Hilbert space H\mathscr{H}H. Following von Neumann, we assume a decomposition of H\mathscr{H}H into mutually orthogonal subspaces Hν\mathscr{H}_νHν​, where each ννν represents a macro state, and Hν\mathscr{H}_νHν​ contains the pure states compatible with ννν. We define the quantum Boltzmann entropy for a macro state ννν as SqB(ν)=kBlog⁡dim⁡HνS_\mathrm{qB}(ν) = k_{\mathrm{B}} \log \dim \mathscr{H}_νSqB​(ν)=kB​logdimHν​, where kBk_\mathrm{B}kB​ is the Boltzmann constant. Goldstein et al. [http://arxiv.org/abs/1903.11870] have suggested, as a version of the second law of thermodynamics, that SqBS_\mathrm{qB}SqB​ predominantly increases with time for realistic macroscopic systems. Here, we discuss precise versions of this statement and confirm them for several simple models of HHH and Hν\mathscr{H}_νHν​.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
In this paper, we construct the metric tensor and volume for the manifold of purifications associated with an arbitrary reduced density operator ρS. We also define a quantum coarse-graining (CG) to study the volume where macrostates are the manifolds of purifications, which we call surfaces of ignorance (SOI), and microstates are the purifications of ρS. In this context, the volume functions as a multiplicity of the macrostates that quantifies the amount of information missing from ρS. Using examples where the SOI are generated using representations of SU(2), SO(3), and SO(N), we show two features of the CG: (1) A system beginning in an atypical macrostate of smaller volume evolves to macrostates of greater volume until it reaches the equilibrium macrostate in a process in which the system and environment become strictly more entangled, and (2) the equilibrium macrostate takes up the vast majority of the coarse-grained space especially as the dimension of the total system becomes large. Here, the equilibrium macrostate corresponds to a maximum entanglement between the system and the environment. To demonstrate feature (1) for the examples considered, we show that the volume behaves like the von Neumann entropy in that it is zero for pure states, maximal for maximally mixed states, and is a concave function with respect to the purity of ρS. These two features are essential to typicality arguments regarding thermalization and Boltzmann's original CG.
We discuss the geometry of states of quantum systems in an n-dimensional Hilbert space in terms of an explicit parameterization of all such systems. The geometry of the space of pure as well as mixed states for n -state systems is discussed. The parameterization is particularly useful since it allows for the simple construction and isolation of various physically meaningful subspaces of the space of all density matrices. This is used to describe possible geometric phases, their calculation, and analyze entropy and purity (or linear entropy) functions. In particular we provide conditions under which nontrivial abelian and/or nonabelian geometric phases aris in these subspaces in terms of the given parameterization, an explicit example is given, and multidimensional ientopic surfaces are discused.